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1.
Bentley KW 《Natural product reports》2005,22(2):249-268
This review covers beta-phenylethylamines and isoquinoline alkaloids derived from them, including further products of oxidation, condensation with formaldehyde and rearrangement, some of which do not contain as isoquinoline system, together with napthylisoquinoline alkaloids, which have a different biogenetic origin. The occurrence of the alkaloids with the structures of new bases, together with their reactions and syntheses, are reported. The literature from July 2003 to June 2004 is reviewed, with 145 references cited. 相似文献
2.
This theory proposes that electric conductivity, metallic or otherwise, ohmic or superconducting, is simply the result of electron density moving through atomic and molecular orbital overlaps in material bodies. The theory argues that electron density moves without resistance (is superconducting) while it is contained within extended quantum mechanical (QM) states which are constructed so that the electron wave function does not experience reflections at any interface. The theory states that ohmic conduction results when the electron wave function does experience reflections at QM interfaces, and requires the continuous external application of electromotive force (EMF) to overcome those reflections and maintain an electric current. 相似文献
3.
T. William Bentley Robert O. Jones Dae Ho Kang In Sun Koo 《Journal of Physical Organic Chemistry》2009,22(9):799-806
Rate constants for a wide range of binary aqueous mixtures and product selectivities (S) in ethanol–water (EW) and methanol–water (MW) mixtures, are reported at 25 °C for solvolyses of benzenesulfonyl chloride and the 4‐chloro‐derivative. S is defined as follows using molar concentrations: S = ([ester product]/[acid product]) × ([water solvent]/[alcohol solvent]). Additional selectivity data are reported for solvolyses of 4‐Z‐substituted sulfonyl chlorides (Z = OMe, Me, H, Cl and NO2) in 2,2,2‐trifluoroethanol–water. To explain these results and previously published data on kinetic solvent isotope effects (KSIEs) and on other solvolyses of 4‐nitro and 4‐methoxybenzenesulfonyl chloride, a mechanistic spectrum involving a change from third order to second order is proposed. The molecularity of these reactions is discussed, along with new term ‘SN3–SN2 spectrum’ and its connection with the better established term ‘SN2–SN1 spectrum’. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
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D. Rudolph R. Hoischen M. Hellström S. Pietri Zs. Podolyák P. H. Regan A. B. Garnsworthy S. J. Steer F. Becker P. Bednarczyk L. Cáceres P. Doornenbal J. Gerl M. Górska J. Grebosz I. Kojouharov N. Kurz W. Prokopowicz H. Schaffner H. J. Wollersheim L. -L. Andersson L. Atanasova D. L. Balabanski M. A. Bentley A. Blazhev C. Brandau J. R. Brown C. Fahlander E. K. Johansson A. Jungclaus 《The European Physical Journal A - Hadrons and Nuclei》2008,36(2):131-138
The fragmentation of a 550MeV/u primary beam of 58Ni on a 9Be target has been used to measure time- and energy-correlated γ decays following the implantation of event-by-event discriminated
secondary fragments into a 9Be stopper plate. A new isomeric γ decay with T
1/2 = 14(
) ns and E
γ = 646.2(2) keV is observed and attributed to the decay of the yrast 3/2- state in 53
27Co26 . This short-lived isomeric state has been populated by means of nuclear reactions during the stopping process of the secondary
fragments. The experimental findings are discussed in the framework of large-scale spherical shell model calculations in conjunction
with isospin symmetry-breaking residual interactions for the A = 53 , T
z = ±1/2 mirror nuclei 53Co and 53Fe . 相似文献
7.
Carolina L. da Silva José O. Del Ciampo Fábia C. Rossetti Maria V. L. B. Bentley Maria B. R. Pierre 《Photochemistry and photobiology》2013,89(5):1176-1184
We report the development of d , l lactic co‐glycolic acid) (PLGA)‐based nanoparticles (NPs) for topical delivery of protoporphyrin IX (PpIX), a photosensitizer (PS), in treatments like photodynamic therapy (PDT) of skin cancers. PpIX‐NPs were obtained in ~75.0% yield, encapsulation efficiency of 67.7%, drug content of 50.3 μg mg?1, average diameter of 290 nm maintained up to 30 days and a zeta potential of 32.3 mV. Sustained in vitro release of PpIX through artificial membranes following Higuchi kinetics was kept up to 10 days. In vitro retentions of PpIX both in stratum corneum (SC) and epidermis + dermis ([EP + D]) were higher from NPs (23.0 and 10.0 times, respectively) compared to control solutions at all times. Quantification of PpIX by extraction, after in vivo skin application of NPs‐PpIX on hairless mice, showed higher retention of the PS both in SC and in [EP + D] (3.0 and 2.0 times, respectively) compared to control solutions. Taken together, the results indicate that NPs are suitable for PpIX encapsulation showing minimal permeation through the skin and a localized effect, characteristics of a potential and promising delivery system for PDT‐associated treatments of skin cancers, photodiagnosis and their off‐label uses. 相似文献
8.
Bentley PA Flood RW Roberts SM Skidmore J Smith CB Smith JA 《Chemical communications (Cambridge, England)》2001,(17):1616-1617
Epoxidation of chalcone (1), using basic hydrogen peroxide, catalysed by polypeptides with defined primary structures demonstrates that the residues in the chain near to the N-terminus determine the stereochemical outcome of the reaction. 相似文献
9.
In studying the factors which contribute to the Lewis acidity of organoboron compounds we investigated approaches to the design of robust, novel Lewis acids purposed for metal-free catalysis. Based on a sterically encumbered catechol motif, a series of boronate esters are shown to demonstrate modest Lewis acidities for the conventional Gutmann-Beckett test as an inquisitive investigation. 相似文献
10.
Acyl nitrile oxides are readily generated and trapped in a nitrating mixture with N-methylmaleimide. 相似文献