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V. Ballarini G. Barucca E. Bennici C. F. Pirri C. Ricciardi E. Tresso F. Giorgis 《Physica E: Low-dimensional Systems and Nanostructures》2003,16(3-4):591
All amorphous silicon-nitride planar optical microcavities operating in the visible range have been grown by plasma enhanced chemical vapor deposition. The luminescence intensity of the N-rich silicon-nitride layer from a microcavity with 6 period distributed Bragg reflectors (DBRs) is two order of magnitude higher than that of the luminescent layer without the cavity. Moreover, a strong directionality of the microcavities emission can be observed. Such results can be ascribed to the anisotropic optical density of states induced in the Fabry–Perot structure. The quality factors of the resonators are strictly correlated to the number of periods of the DBRs. 相似文献
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Scuiller Elliot Dutournié Patrick Zbair Mohamed Bennici Simona 《Journal of Thermal Analysis and Calorimetry》2022,147(22):12409-12416
Journal of Thermal Analysis and Calorimetry - The determination of the thermo-physical properties (density, specific heat capacity, and thermal conductivity) of hygroscopic and reactive solid... 相似文献
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The acid properties of pure and modified silica surfaces were studied by 2-phenylethylamine (PEA) desorption in a thermogravimetric (TGA) apparatus, carrying out the experiments at different heating rates (5 < beta/(degrees C.min(-1)) < 30). The samples, containing about 13 wt % alumina, titania, and zirconia, were prepared by the sol-gel route from molecular precursors. The textural, structural, and surface properties of the materials were studied by complementary techniques (ICP, XRD, N(2) physisorption, SEM-EDS, and XPS). The chemical modification of the silica surface by enrichment with Al, Ti, or Zr, in amounts of about 90, 50, and 60% of that introduced in the preparation as determined by XPS, justified the increase of acidity of the modified silica surfaces compared with that of pure silica. The total number of strong acid sites was found to be in the order of SZ > SA > ST > S. Two different kinetic approaches were applied to the thermogravimetric data to kinetically interpret the PEA desorption from the different types of acid sites. The classical differential Kissinger model was found to be inadequate in representing the very complex situation of the acid surfaces. A more complex model is proposed by simultaneously taking into account PEA desorption from the different acid sites by a set of parallel and independent desorption reactions following Arrhenius's kinetic law. The fraction of each type of acid site on each surface and the relevant activation parameters were optimized through a computational procedure. Very good fitting of the experimental-calculated desorption profiles corroborated the validity of the model. For each surface, the acid-site energy distribution is presented and discussed in relationship to the surface composition of the oxides. 相似文献
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In this work we report about the characterization of the acidic and redox properties of four different commercial tungstated
zirconia catalysts with W loadings of about 12–13 mass%. The samples have been characterized in terms of their micro-structural
and surface properties by BET, X-ray diffraction, temperature programmed reduction, elemental chemical analysis and adsorption
microcalorimetry of NH3. Improved acidity has been detected upon addition of WO3 to zirconia and differences between the samples were pointed out thanks to the results obtained by the complementary physico-chemical
techniques used in this study. 相似文献
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H. Zhao S. Bennici J. Shen A. Auroux 《Journal of Thermal Analysis and Calorimetry》2010,99(3):843-847
The surface acidic properties of sulfated vanadia–titania catalysts prepared by various methods were investigated by adsorption
microcalorimetry, using ammonia as probe molecule. The acidic characteristics of the samples were shown to be strongly affected
by the preparation method, calcination temperature, and sulfur content. The samples prepared by sol–gel and mechanical grinding
exhibited higher acidity than co-precipitated samples. Moreover, increasing the calcination temperature of co-precipitated
samples resulted in a decrease in surface area from 402 to 57 m2 g−1 and sulfur content from around 4 to 0.2 mass%, but up to a certain point generated a stronger acidity. The optimal calcination
temperature appeared to be around 673 K. 相似文献
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Mekki-Berrada A Grondin D Bennici S Auroux A 《Physical chemistry chemical physics : PCCP》2012,14(12):4155-4161
The design of new amphoteric catalysts is of great interest for several industrial processes, especially those covering dehydration and dehydrogenation phenomena. Adsorption microcalorimetry was used to monitor the design of mixed oxides of zinc with Group 3 elements (aluminium, gallium, indium) with amphoteric character and enhanced specific surface area. Acid-base features were found to evolve non-linearly with the relative amounts of metal, and the strengths of the created acidic or basic sites were measured by adsorption microcalorimetry. A panel of bifunctional catalysts of various acid-base (amounts, strengths) and redox character was obtained. Besides, special interest was given to In-Zn mixed oxides for their enhanced basicity: this series of catalysts displays important basic features of high strength (q(diff) (SO? ads.) > 200 kJ mol(SO?)?1 in substantial amounts (1 - 2 μmol m(catalyst)?2), whose impact on efficiency or selectivity in catalytic dehydration/dehydrogenation can be valuable. 相似文献
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Simple Zeros of the Riemann Zeta-Function 总被引:1,自引:0,他引:1
Assuming the Riemann Hypothesis, Montgomery showed by meansof his pair correlation method that at least two-thirds of thezeros of Riemann's zeta-function are simple. Later he and Taylorimproved this to 67.25 percent and, more recently, Cheer andGoldston increased the percentage to 67.2753. Here we proveby a new method that if the Riemann and Generalized LindelöofHypotheses hold, then at least 70.3704 percent of the zerosare simple and at least 84.5679 percent are distinct. Our methoduses mean value estimates for various functions defined by Dirichletseries sampled at the zeros of the Riemann zeta-function. 1991Mathematics Subject Classification: 11M26. 相似文献