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Suvorova V. V. Panicheva L. P. Mamontova Yu. V. Belyatskii M. K. 《Russian Journal of Organic Chemistry》2003,39(7):957-962
Selective dehydrobromination of 1,2-dibromo-1-phenylethane to -bromostyrene was effected under conditions of phase-transfer catalysis in systems containing KOH, toluene, and tetraalkylammonium bromides. The high selectivity of the catalytic systems originates from stabilization by lipophilic cation of the phase-transfer catalyst of a E1cb-like transition state in the E2 mechanism. In the presence of a catalytic amount of lipophilic alcohols, phenylacetylene was obtained. Substrate activation by alcohol molecules is explained by enhancement of the acceptor power of halogen atoms due to solvation and by increased mobility of hydrogen atoms. 相似文献
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D. S. Shapenova M. K. Belyatskii L. P. Panicheva 《Russian Journal of Organic Chemistry》2010,46(7):1017-1020
Oxidation of 2-(aryloxymethyl)oxiranes with periodic acid gave a series of aryloxyacetaldehydes which reacted with cyclohexylamine
in THF, and subsequent reduction of Schiff bases thus obtained with sodium tetrahydridoborate resulted in the formation of
the corresponding secondary amines which were isolated and characterized as hydrochlorides. 相似文献
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