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1.
Nováková Kateřina Hrdlička Vojtěch Navrátil Tomáš Vyskočil Vlastimil Barek Jiří 《Monatshefte für Chemie / Chemical Monthly》2015,146(5):761-769
Monatshefte für Chemie - Chemical Monthly - The voltammetric behavior of 5-nitroindazole was investigated at polished (p-AgSAE) and at mercury meniscus-modified (m-AgSAE) silver solid amalgam... 相似文献
2.
Formation of porous polymer morphology by microsyneresis during divinylbenzene polymerization
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Libuše Hanková Ladislav Holub Karel Jeřábek 《Journal of Polymer Science.Polymer Physics》2015,53(11):774-781
This article describes the investigation of the importance of various reaction conditions on microsyneretic pore formation during polymerization of divinylbenzene (DVB) under so‐called “solvothermal” conditions. To induce microsyneretic pore formation, the most important parameter is an unusually high dilution of monomers with a “good” porogen solvating the polymer chains. High dilution and solvation of the growing poly(DVB) chains promote the prolongation of the polymer chains rather than their interconnection by crosslinking. Consequently, when the polymer gel density reaches the point where syneresis starts, the polymer network is geometrically too extensive to be broken up into precipitating entities and, instead, porogen droplets are formed within the continuous polymer gel. The pore geometry created by microsyneresis offers high surface area in wide mesopores and hence, high capacity for supporting functional groups or reactions with much better accessibility than narrow pores between polymer microspheres produced by macrosyneresis in conventional styrenic polymer supports. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 774–781 相似文献
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5.
P. Kolář 《Czechoslovak Journal of Physics》1989,39(11):1317-1320
Conclusions The sets (3) and (4) of condensates have been compared using the QCD sum rules (2) with indefinite weight functions. A bad matching between both sets of condensates and experimental data has been obtained. The standard values (3) appear to be closer to data but some increase ofQ is necessary to improve the agreement. Only higher values ofm
0
2
could change the results of this analysis. It is interesting that negative values ofm
0
2
considerably improve the agreement with data; note that this quantity cannot be determined with a sufficient accuracy. We conclude that the QCD sum rules (2) cannot definitely determine a privileged set of condensates.Dedicated to Academician Václav Votruba on the occasion of his eightieth birthday. 相似文献
6.
Jiří Herec 《Czechoslovak Journal of Physics》2004,54(12):1473-1481
In this paper the quantum-statistical properties of light beams propagating in a directional nonlinear coupler are investigated.
This device is composed of a pair of linearly coupled nonlinear waveguides operating by means of degenerate parametric downconversion.
The possibility of generation of nonclassical states of light in single and compound modes, using the short-length approximation,
is discussed. Influence of linear and nonlinear mismatches for generation of nonclassical light is taken into account.
This work was supported by Project LN00A015, Research Project No. CEZ: J14/98 and the COST project OC P11.003 of the Czech
Ministry of Education. 相似文献
7.
Bed ich Ko ata V clav Kozmik Ji í Svoboda Vladimí ra Novotn P emysl Van k Milada Glogarov 《Liquid crystals》2003,30(5):603-610
Four series of new [1]benzothieno[3,2- b ][1]benzothiophene derivatives have been synthesized. In the non-chiral series a SmA phase occurs, while the chiral series exhibits a rather wide antiferroelectric SmC * A phase just below the SmA phase. The SmA-SmC * A phase transition has been studied using DSC and dielectric spectroscopy. In the SmC * A phase the spontaneous quantities have been measured. The tilt angle shows a typical temperature dependence and the values of spontaneous polarization are rather moderate. The length of the helical pitch increases on increasing the length of the non-chiral alkyl chain. 相似文献
8.
No analytic solutions of the Schrödinger equation are known for the quartic anharmonic oscillator. We show in this paper that there are closely related modified quartic oscillators with the potential depending on |x| for which analytic solutions for some states exist. These results can be extended to the higher order oscillators 相似文献
9.
Jiří Čtyroký 《Optical and Quantum Electronics》2006,38(1-3):45-62
The bi-directional mode expansion propagation algorithm (BEP) is known to be an accurate and efficient method for modelling field distribution in high-index contrast waveguide structures with strong back-reflections like Bragg gratings and photonic crystals. The main difficulty of this method is that for lossy structures, the propagation constants of modes are to be searched in the complex plane. To speed-up this procedure, a two-step algorithm for eigenmode calculation based on the expansion into the modes of an empty metallic waveguide has recently been proposed. Proper truncation rules possessing good convergence of the expansion method for both TE and TM modes have also been recently published. In this contribution, both these approaches are combined in the development of an extremely simple version of the two-dimensional BEP method that makes use of the field expansion into the eigenmodes of a parallel-plate waveguide. The method is strictly reciprocal and appeared to be computationally reliable also for strongly lossy structures. High numerical stability is ensured using the scattering matrix formalism, and an efficient method of calculating Bloch modes for symmetric as well as asymmetric periodic waveguide structures is adopted. A wide range of applicability of the method is demonstrated by a few examples. 相似文献
10.
We consider the 3D Navier–Stokes equation with generalized impermeability boundary conditions. As auxiliary results, we prove the local in time existence of a strong solution (‘strong’ in a limited sense) and a theorem on structure. Then, taking advantage of the boundary conditions, we formulate sufficient conditions for regularity up to the boundary of a weak solution by means of requirements on one of the eigenvalues of the rate of deformation tensor. Finally, we apply these general results to the case of an axially symmetric flow with zero angular velocity. 相似文献