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1.
ZverovichIE ZverovichOI 《高校应用数学学报(英文版)》2004,19(2):125-132
Two new hereditary classes of P5-free graphs where the stability number can be found in polynomial time are proposed. They generalize several known results. 相似文献
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Bestimmung des Oxydationszustandes in Vanadiumkomplexen mit Hilfe von V—K-Röntgenabsorptionsspektren
Determination of the Oxydation State in Vanadium Complexes using V—K-Absorption Spectra The compounds resulting from the reaction of oxovanadium(IV) sulfate with 8-quinolinols in air were characterized by magnetic moments and V—K-absorption spectra. 8-quinolinol and its Mannich derivates (“CMAB-oxine”, “CMAP-oxine”) form vanadium(V) complexes. The oxovanadium(IV) compound of 7-methyl-8-quinolinol initially formed is not very stable in solution and tends to oxydation. Only the oxovanadium(IV) complex of 2-methyl-8-quinolinol has a good stability corresponding to that of β-diketone compounds. 相似文献
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Stephan Schaumüller Doris Cristurean Stephan Haudum George S. Pappas Markus Himmelsbach Matthias Bechmann Oliver Brüggemann Ian Teasdale 《Journal of polymer science. Part A, Polymer chemistry》2021,59(24):3161-3166
We report a facile post-polymerization modification route to functionalized aromatic polyimides via Diels-Alder cycloaddition. Aromatic polyimides are important, versatile high-performance polymers; however, their structural diversity is restricted by the requirements of the step-growth polymerization. We prepared polyimides with alkynes in their main-chain as macromolecular dienophiles and quantitatively grafted tetraphenylcyclopentadienone based dienes. The resulting solution-processable, wholly aromatic polyimides show a considerable increase in surface area due to the induced conformational changes and bulky, rigid, and contorted molecular structures. The orthogonality of the reaction is exploited to insert functional groups, namely bromine and sulfonates, along the polymer backbone. In a further extension, the phenylene segments undergo cyclodehydrogenation to form nanographene segments within the polymer chains. The Diels-Alder cycloaddition onto polyimides is therefore demonstrated to be an effective, widely applicable route to tunable high-performance polymers with value-added functionality and thus considerable potential in a wide range of advanced materials. 相似文献
4.
Double-quantum filtered MAS NMR spectra of an isolated homonuclear spin-1/2 pair are considered, at and away from rotational resonance conditions. The pulse sequence used is the solid-state NMR equivalent of double-quantum filtered COSY, known from solution-state NMR. The 119Sn spin pair in [(chex3Sn)2S] is characterized by a difference in isotropic chemical shielding smaller than the two chemical shielding anisotropies and by direct dipolar and isotropic J-coupling constants of similar magnitudes. At rotational resonance, one-dimensional double-quantum filtered 119Sn lineshapes yield the relative orientation of the two 119Sn chemical shielding tensors. Good double-quantum filtration efficiencies are found at and away from rotational resonance conditions, despite the presence of large chemical shielding anisotropies. Numerical simulations illustrate the interplay of the direct dipolar and J-coupling pathways and identify the latter as the main pathway even at rotational resonance conditions. 相似文献
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6.
Iben Ellegaard Bechmann 《Analytica chimica acta》1996,320(2-3):155-164
A flow injection analysis (FIA) system for determination of formaldehyde in frozen fish products is described. The system provides a rapid and selective determination of formaldehyde in aqueous fish extracts by the combination of a deproteinization procedure and a stopped-flow enzymatic approach in a FIA system. The FIA system is furnished with a gel-filtration chromatography column for on-line removal of the proteins from the extract before the enzymatic analysis is performed. Compared with the standard methods for determination of formaldehyde in fish products the present method is much faster and less affected by interferences. The limit of detection for the proposed method is 2.5 mg/l of formaldehyde. The sampling frequency is about 10 determinations per hour. 相似文献
7.
Zverovich I E 《高校应用数学学报(英文版)》2004,19(3):239-244
§1 IntroductionLet G be a graph with vertex-set V(G) ={ v1 ,v2 ,...,vn} .A labeling of G is a bijectionL:V(G)→{ 1,2 ,...,n} ,where L (vi) is the label of a vertex vi.A labeled graph is anordered pair (G,L) consisting of a graph G and its labeling L.Definition1.An increasing nonconsecutive path in a labeled graph(G,L) is a path(u1 ,u2 ,...,uk) in G such thatL(ui) + 1相似文献
8.
I. E. Bechmann S. Stürup L. V. Kristensen 《Analytical and bioanalytical chemistry》2000,368(7):708-714
The contents of V, Cr, Co, Ni, Cu, Ga, Rb, Cd, Ba, and Pb in the soft tissue of blue mussel (Mytilus edulis) were determined by a high resolution inductively coupled plasma mass spectrometry (HR-ICPMS) method. Sample digestions were performed in closed microwave vessels using nitric acid and hydrogen peroxide. Using HR-ICPMS it is possible to resolve the analytical peaks from otherwise interfering polyatomic ions with a mass resolution setting of 4000 (Cr, Ni, Cu). The proposed method was validated using a mussel tissue reference material (NIST SRM 2974). The proposed method was applied to real samples of blue mussel from seven sites in the inlet “Limfjorden”, Denmark, and the levels of trace elements found were compared with the levels found in an earlier study. For the mussel samples large inter-regional differences in trace element concentrations in the tissues were recorded. The mussels from the different sites could be separated using principal component analysis (PCA). Comparison with the levels of trace elements in mussels found in 1982 showed that the trace elemental contamination has increased during the last 15 years. From the data obtained, mussel tissue appears to be good bio-indicator for identification of coastal areas exposed to metallic contaminants. 相似文献
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Bechmann IE 《Talanta》1997,44(4):585-591
A flow injection analysis (FIA) system furnished with a gel-filtration chromatographic column and with photodiode-array detection was used for the generation of second-order data. The system presented is a model system in which the analytes are blue dextran, potassium hexacyanoferrate(III) and heparin. It is shown that the rank of the involved sample data matrices corresponds to the number of chemical components present in the sample. The PARAFAC (parallel factor analysis) algorithm combined with multiple linear regression and tri-PLS (tri-linear partial least-squares regression), which allows unknown substances to be present in the sample, are implemented for FIA systems and it is illustrated how these three-way algorithms can handle spectral interferents. The prediction ability of the two methods for pure two-component samples and also the predictions ability in the presence of unknown interferents are satisfactory. However, the predictions obtained by tri-PLS are slightly better than those obtained using PARAFAC regression algorithm. 相似文献
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A. Friedrich K. Grunewald S. Klinnert W. Bechmann 《Journal of Thermal Analysis and Calorimetry》1996,46(6):1589-1597
Soil substrates of sewage farms (inflow of sewage areas) and of closed sewage farms were investigated by means of thermogravimetry and differential thermal analysis. The results were compared with those obtained for control samples from outside the sewage farms.The organic matter of actively used sewage areas (inflow) contains a remarkable amount of easily oxidizable compounds brought to the inflows by suspended matter.Beside these compounds, macromolecular organic substances predominate in the composition of the organic matter and are responsible for an immense heat release in the high temperature range of the thermal studies.In the substrates of closed sewage farm inflows or of other sewage farm areas which do not belong to the inflows, the amounts of volatile and easily oxidizable compounds decrease rapidly. The substrates hardly differ in their reaction temperatures from control samples. The influence of single macromolecules on the exothermic oxidation is reduced with increasing humification. 相似文献