全文获取类型
收费全文 | 2792篇 |
免费 | 105篇 |
国内免费 | 21篇 |
专业分类
化学 | 1993篇 |
晶体学 | 15篇 |
力学 | 44篇 |
数学 | 329篇 |
物理学 | 537篇 |
出版年
2023年 | 16篇 |
2022年 | 64篇 |
2021年 | 81篇 |
2020年 | 57篇 |
2019年 | 53篇 |
2018年 | 52篇 |
2017年 | 43篇 |
2016年 | 77篇 |
2015年 | 78篇 |
2014年 | 93篇 |
2013年 | 134篇 |
2012年 | 170篇 |
2011年 | 200篇 |
2010年 | 131篇 |
2009年 | 130篇 |
2008年 | 182篇 |
2007年 | 196篇 |
2006年 | 174篇 |
2005年 | 149篇 |
2004年 | 104篇 |
2003年 | 89篇 |
2002年 | 71篇 |
2001年 | 56篇 |
2000年 | 58篇 |
1999年 | 35篇 |
1998年 | 32篇 |
1997年 | 31篇 |
1996年 | 34篇 |
1995年 | 27篇 |
1994年 | 16篇 |
1993年 | 15篇 |
1992年 | 25篇 |
1991年 | 14篇 |
1990年 | 21篇 |
1989年 | 12篇 |
1988年 | 9篇 |
1987年 | 12篇 |
1986年 | 11篇 |
1985年 | 11篇 |
1984年 | 15篇 |
1983年 | 8篇 |
1982年 | 10篇 |
1981年 | 6篇 |
1980年 | 10篇 |
1979年 | 7篇 |
1978年 | 5篇 |
1975年 | 6篇 |
1974年 | 8篇 |
1934年 | 6篇 |
1930年 | 4篇 |
排序方式: 共有2918条查询结果,搜索用时 31 毫秒
1.
Functional Carbazole Liquid‐Crystal Block Codendrimers with Optical and Electronic Properties
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Ismael Gracia Beatriz Feringán Prof. José Luis Serrano Dr. Roberto Termine Dr. Attilio Golemme Dr. Ana Omenat Prof. Joaquín Barberá 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(3):1359-1369
The synthesis and characterisation of a family of block codendrimers consisting of highly versatile mesogenic and carbazole‐containing 2,2‐bis(hydroxymethyl)propionic acid (bis‐MPA) dendrons are reported. The liquid‐crystal behaviour was investigated by means of differential scanning calorimetry, polarised‐light optical microscopy and X‐ray diffraction. Depending on the chemical structure of the constituent dendrons, the codendrimers show lamellar or columnar mesophases. On the basis of the experimental results, models both at the molecular level and in the mesophase are proposed. The physical properties of the block codendrimers derived from the presence of the carbazole moiety in their structure were investigated: photoluminescence in solution and in the mesophase, electrochemical behaviour and hole transport. Electrodeposition of carbazole dendrons afforded a globular supramolecular conformation in which the mesogenic molecular side plays a key role. 相似文献
2.
3.
Karen Beatriz Méndez-Rodríguez Nicté Figueroa-Vega César Arturo Ilizaliturri-Hernandez Mónica Cardona-Alvarado Jaime Antonio Borjas-García Carlos Kornhauser Juan Manuel Malacara Rogelio Flores-Ramírez Francisco Javier Pérez-Vázquez 《Biomedical chromatography : BMC》2020,34(12):e4956
Metabolomics is a potential tool for the discovery of new biomarkers in the early diagnosis of diseases. An ultra-fast gas chromatography system equipped to an electronic nose detector (FGC eNose) was used to identify the metabolomic profile of Volatile Organic Compounds (VOCs) in type 2 diabetes (T2D) urine from Mexican population. A cross-sectional, comparative, and clinical study with translational approach was performed. We recruited twenty T2D patients and twenty-one healthy subjects. Urine samples were taken and analyzed by FGC eNose. Eighty-eight compounds were identified through Kovats's indexes. A natural variation of 30% between the metabolites, expressed by study groups, was observed in Principal Component 1 and 2 with a significant difference (p < 0.001). The model, performed through a Canonical Analysis of Principal coordinated (CAP), allowed a correct classification of 84.6% between healthy and T2D patients, with a 15.4% error. The metabolites 2-propenal, 2-propanol, butane- 2,3-dione and 2-methylpropanal, were increased in patients with T2D, and they were strongly correlated with discrimination between clinically healthy people and T2D patients. This study identified metabolites in urine through FGC eNose that can be used as biomarkers in the identification of T2D patients. However, more studies are needed for its implementation in clinical practice. 相似文献
4.
5.
Beatriz S. D'Ambrosio William J. Boone Shelly Sheats Harkness 《School science and mathematics》2004,104(1):5-15
This paper describes the mechanism used to gain insights into the state of the art of mathematics instruction in a large urban district in order to design meaningful professional development for the teachers in the district. Surveys of close to 2,000 elementary, middle school, and high school students were collected in order to assess the instructional practices used in mathematics classes across the district. Students were questioned about the frequency of use of various instructional practices that support the meaningful learning of mathematics. These included practices such as problem solving, use of calculators and computers, group work, homework, discussions, and projects, among others. Responses were analyzed and comparisons were drawn between elementary and middle school students' responses and between middle school and high school responses. Finally, fifth‐grade student responses were compared to those of their teachers. Student responses indicated that they had fewer inquiry‐based experiences, fewer student‐to‐student interactions, and fewer opportunities to defend their answers and justify their thinking as they moved from elementary to middle school to high school. In the elementary grades students reported an overemphasis on the use of memorization of facts and procedures and sparse use of calculators. Results were interpreted and specific directions for professional development, as reported in this paper, were drawn from these data. The paper illustrates how student surveys can inform the design of professional development experiences for the teachers in a district. 相似文献
6.
Rafael R. del Río Castillo 《Communications in Mathematical Physics》1991,142(2):421-431
In this work we study the behavior of embedded eigenvalues of Sturm-Liouville problems in the half axis under local perturbations. When the derivative of the spectral function is strictly positive, we prove that the embedded eigenvalues either disappear or remain fixed. In this case we show that local perturbations cannot add eigenvalues in the continuous spectrum. If the condition on the spectral function is removed then a local perturbation can add infinitely many eigenvalues. 相似文献
7.
8.
9.
Patricia Smichowski María Beatriz de la Calle Guntiñas Carmen Cámara 《Fresenius' Journal of Analytical Chemistry》1994,348(5-6):380-384
Summary A method is described for antimony preconcentration based on retention on a column of activated alumina. Recovery is 80% when no pH-control and 4 mol/l HCl as eluent are used. The preconcentration factor is 400. The method was applied to the determination of antimony in spiked tap and sea water. The analytical performance of the method is discussed. 相似文献
10.
We study bounds on averages of spectral functions corresponding to Sturm-Liouville operators on the half line for different boundary conditions. As a consequence constraints are obtained which imply existence of singular spectrum embedded in a.c. spectrum for sets of boundary conditions with positive measure and potentials vanishing in an interval [0,N]. These constraints are related to estimates on the measure of sets where the spectral density is positive. 相似文献