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Larionov S. V. Leonova T. G. Glinskaya L. A. Klevtsova R. F. Platonov V. E. Maksimov A. M. Fadeeva V. P. Batrachenko N. I. 《Russian Journal of Coordination Chemistry》2000,26(12):861-865
Compounds (CH3)2Sn(C12F9S)2 (I), (CH3)2Sn(C10F7S)2 (II), and (C2H5)2Sn(C10F7S)2 (III) were synthesized. Single crystals of Iwere grown and structurally characterized using X-ray diffraction analysis (1590 reflections, R = 0.0209). The crystals are orthorhombic, a = 40.848(8) Å, b = 6.058(1) Å, c = 11.183(2) Å, V = 2767(1) Å3, (calcd.) = 2.024 g/cm3, space group Pbcn, Z = 4. The structure is built from monomeric molecules. The coordination polyhedron of the Sn atom (the SnC2S2 core) is a distorted tetrahedron. Compounds I–III are volatile when heated in vacuo. Thermolysis of these compounds results in SnO2 (in air) or SnS2 (in argon). 相似文献
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S. V. Larionov T. G. Leonova N. I. Batrachenko I. V. Korol’kov V. S. Danilovich V. E. Platonov A. M. Maksimov V. P. Fadeeva 《Russian Journal of Inorganic Chemistry》2008,53(2):209-212
Silver(I) compounds with perfluorinated aromatic thiols (4-nonafluorodiphenylthiol C6F5C6F4SH (HL1), 2-heptafluoronaphthalenethiol C10F7SH (HL2), and pentafluorothiophenol C6F5SH (HL3), namely AgL1 (I), AgL2 (II), AgL3 (III), were prepared. The thermal properties of compounds I–III and the composition of thermolysis products were studied. By powder X-ray diffraction and electron microscopy, it was shown that thermolysis of compounds I–III under argon and thermolysis of compound III in air yield Ag nanoparticles. 相似文献
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S. V. Larionov T. G. Leonova L. A. Glinskaya R. F. Klevtsova N. I. Batrachenko I. V. Korol’kov V. S. Danilovich 《Russian Journal of Inorganic Chemistry》2012,57(3):378-385
The thermal decomposition of the chelate Cd(n-BuOCS2)2 (I) in EtOH and DMF, either in the absence or in the presence of Ph3P, yields finely disperse CdS particles. Mixed-ligand complex Cd(Ph3P)(n-BuOCS2)2 (II) has been synthesized. Cd(Ph3P)(n-BuOCS2)2 · Ph3P (III) single crystals have been grown. By X-ray crystallography, the crystal structure of III is built of [Cd(Ph3P)(n-BuOCS2)2] mononuclear complex molecules and uncoordinated Ph3P molecules, which reside inside channels formed by complex II molecules. The coordination polyhedron around a Cd atom is a tetragonal pyramid where the base is formed by the four S atoms
of the two bidentate chelating ligands n-BuOCS2− and the P atom of the Ph3P ligand is at the axial vertex. In the structure of III, there are supramolecular assemblies of two complex II molecules. 相似文献
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Monokristallreaktiv Scientific-Production Association. Translated from Zhurnal Strukturnoi Khimii, Vol. 32, No. 5, pp. 146–147, September–October, 1991 相似文献
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We show that the generalized holonomy groups of ungauged supergravity theories with 8 real supercharges must be contained in , where
is the generalized structure group. Here n=4ν is the number of preserved supersymmetries, so the allowed values are limited to n=0,4,8. In particular, solutions of ungauged supergravities in four, five and six dimensions are examined and found to explicitly follow this pattern. We also argue that the G-structure has to be a subgroup of this generalized holonomy group, which may provide a possible classification for supergravity vacua with respect to the number of supercharges. 相似文献
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