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Abstract Multi‐commutation, which refers to the use of solenoid valves to construct the flow network, has been widely used for providing automation in flow injection analysis. In this paper, the coupling of multi‐commutation and multi‐optosensing is developed for the analysis of two pesticides in environmental water samples, fuberidazole and o‐phenylphenol. In optosensing, the use of the solid support allows the discrimination between the analytes and other compounds that, if measuring in solution, would interfere in the analysis; in addition, the sensitivity needed when facing environmental samples is obtained. The two analytes are separated by using C18 silica gel as solid support, taking into account their different kinetics of sorption/desorption when interacting with the solid support microbeads; the separation is performed in the same flow‐cell where the sensing detection is carried out (by using an additional amount of solid support in the cell itself above the irradiated microzone), so both separation and determination are integrated in the cell. The native fluorescence of fuberidazole and o‐phenylphenol was simultaneously measured at 314/356 and 250/345 nm, respectively. The detection limits obtained were 0.18 and 6.1 ng mL?1 for fuberidazole and o‐phenylphenol respectively, with a sampling frequency of about 12 samples per hour. A recovery study was performed in waters obtained for wells and rivers, with satisfactory results. 相似文献
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非线性涡黏性系数模型和代数应力模型联系了线性涡黏性系数湍流模型和完整的微分
雷诺应力模型.随着它们受到日益关注,其形式也越来越多样化.本篇综述的目的是对这些模
型加以总结并比较它们之间的共同点及不同之处,指出它们与完整微分雷诺应力模型之间的
关系,以及相对于线性涡黏性系数模型而言它们在预报流场上所具有的优势. 相似文献
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We present a computer model of diffusion limited aggregation with linear seed. The clusters with varying linear seed lengths are simulated, and their pattern structure, fractal dimension and multifractal spectrum are obtained. The simulation results show that the linear seed length has little effect on the pattern structure of the aggregation clusters if its length is comparatively shorter. With its increasing, the linear seed length has stronger effects on the pattern structure, while the dimension D f decreases. When the linear seed length is larger, the corresponding pattern structure is cross alike. The larger the linear seed length is, the more obvious the cross-like structure with more particles clustering at the two ends of the linear seed and along the vertical direction to the centre of the linear seed. Furthermore, the multifractal spectra curve becomes lower and the range of singularity narrower. The longer the length of a linear seed is, the less irregular and nonuniform the pattern becomes. 相似文献
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有优先权的光突发交换中光缓存的性能分析 总被引:6,自引:6,他引:0
分析了配置有限数量光纤时延线(FDLs)和优先权机制的光突发交换(pOBS)网络性能,建立了pOBS的网络模型和排队模型;并以模型为基础,比较了各级别数据包的排队等延时与FDLs单位、负荷强度比例的关系;比较了有和无FDLs时,包丢失率与FDLs单位、FDLs深度、系统负荷强度以及波长数的关系.研究发现;高优先级数据包的平均延时远小于其它数据包,负荷强度越大平均延时也越大,高优先级数据包的比例越大则低优先级数据包的延时越大且丢失率越高,加入有限数量和适当深度的FDLs、减小FDLs最小单位、增加波长数都能减小数据包的平均排队延时和丢失率. 相似文献
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In the present work, a novel approach is proposed for the simultaneous determination of three widely used pesticides (namely, fuberidazole (FBZ), carbaryl (CBL) and benomyl (BNM)). The proposed method is based on a single continuous-flow solid surface fluorimetric multi-optosensor implemented with the use of a minicolumn placed just before the flow-through cell and filled with C18 silica gel. The three pesticides are determined from an only injection (simultaneous determination): the minicolumn strongly retains two of them while the third develops a transitory signal when passing through the sensing solid microzone. Then, two alternate eluting solutions appropriately selected perform the sequential elution of the two pesticides from the minicolumn, achieving the detection zone and developing their transitory signals. The proposed optosensor works under optimal sensitivity conditions for all the three analytes because of the use of multi-wavelength fluorescence detection mode, so recording three different signals corresponding at three pairs of optima excitation/emission wavelengths. Using a sample volume of 2100 μl, the system was calibrated in the range 0.5-15, 40-800 and 50-1000 μg l−1 with detection limits of 0.09, 6 and 9 μg l−1 for FBZ, CBL and BNM, respectively. The R.S.D values (n=10) were lower than 2% in all cases. The proposed methodology was applied satisfactorily to water samples. Recovery percentages ranging from 97.8 to 101.1%, 97.9 to 103% and from 97 to 105% for FBZ, CBL and BNM, respectively, were obtained. 相似文献