全文获取类型
收费全文 | 488篇 |
免费 | 15篇 |
国内免费 | 1篇 |
专业分类
化学 | 344篇 |
晶体学 | 1篇 |
力学 | 4篇 |
数学 | 17篇 |
物理学 | 138篇 |
出版年
2022年 | 8篇 |
2021年 | 8篇 |
2020年 | 6篇 |
2019年 | 2篇 |
2018年 | 1篇 |
2016年 | 11篇 |
2015年 | 10篇 |
2014年 | 4篇 |
2013年 | 7篇 |
2012年 | 21篇 |
2011年 | 31篇 |
2010年 | 9篇 |
2009年 | 9篇 |
2008年 | 35篇 |
2007年 | 38篇 |
2006年 | 31篇 |
2005年 | 35篇 |
2004年 | 32篇 |
2003年 | 10篇 |
2002年 | 23篇 |
2001年 | 16篇 |
2000年 | 16篇 |
1999年 | 9篇 |
1998年 | 3篇 |
1997年 | 7篇 |
1996年 | 6篇 |
1995年 | 11篇 |
1994年 | 9篇 |
1993年 | 4篇 |
1992年 | 8篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1989年 | 5篇 |
1988年 | 8篇 |
1987年 | 4篇 |
1986年 | 5篇 |
1985年 | 7篇 |
1984年 | 12篇 |
1983年 | 4篇 |
1982年 | 2篇 |
1981年 | 5篇 |
1980年 | 6篇 |
1979年 | 6篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1975年 | 1篇 |
1974年 | 2篇 |
1973年 | 2篇 |
1969年 | 1篇 |
排序方式: 共有504条查询结果,搜索用时 31 毫秒
1.
Prof. Guido Barone Prof. Aldo La Ginestra 《Journal of Thermal Analysis and Calorimetry》1992,38(12):2563-2563
2.
Proteins obtained from agricultural sources represent a unique feedstock from which to prepare thermally processable polymers. In this study, thermally processed feather keratin films were composted with three-month-old compost inoculum in self-heating laboratory composters for 30 days and temperature and carbon dioxide development monitored. About 24% of the available carbon in the feather keratin polymer (FKP) was metabolized in this time and this may not be high enough for some applications. Degradation of the feather keratin polymers was observed within 10 days with concurrent molecular weight reduction measured using FT-IR. Visual inspection of the polymers also showed destruction of the films. A change in crystallinity was observed in DSC analysis and some degradation processes could be inferred from this as well. 相似文献
3.
The heats of dilution of nine ternary solutions of urea and polyols have been determined at 25°C. Excess enthalpies and their virial coefficients h
xy
have been evaluated and compared with the data reported in the literature for mono- and polyfunctional alcohols and other oxygenated nonelectrolytes. The group additivity approach of Savage and Wood was applied and the contributions to the enthalpy coefficients, due to the water mediated interactions between urea and the functional groups –CH2–, –OH, and –O– were determined. On the other hand, by using empirical combination rules among the cross- and self-enthalpic interaction coefficients it is possible to emphasize the large differences in the behavior (even in the presence of urea) of the polyols (and in particular of cyclitols) and of saccharides. 相似文献
4.
Oesophageal cancer treated by photodynamic therapy alone or followed by radiation therapy 总被引:1,自引:0,他引:1
F Calzavara L Tomio L Corti P L Zorat I Barone A Peracchia L Norberto R F D'Arcais F Berti 《Journal of photochemistry and photobiology. B, Biology》1990,6(1-2):167-174
Photodynamic therapy (PDT) with porphyrins and red light is receiving increasing attention in the management of malignant tumours. At present PDT is primarily indicated for the treatment of superficial or early-stage lesions. At the Department of Radiotherapy and the First Institute of Surgery in Padova (Italy) more than 150 cases of tumours of different types have been treated using this technique. This paper briefly describes 21 cases of superficial oesophageal cancer. A complete response was observed in 11 of 21 cases. Radiation therapy appeared to be very effective as a salvage treatment of non-response patients. 相似文献
5.
Adele Bolognese Gaetano Correale Antonio Lavecchia Vincenzo Barone 《Tetrahedron》2004,60(37):8189-8197
Reaction between quinolinquinone and thiazolidine in basic medium was investigated. 2-Arylthiazolidine-4-carboxylic acid ethyl esters undergo two different cleavages in basic medium, yielding the 1-aryl-2-azadiene and a thiolic species. In the presence of quinolinquinone, the isomeric 1-aryl-3-ethoxycarbonyl-pyridoisoquinolin-5,10-diones and 3-amino-3-ethoxycarbonyl-dihydrothienoquinolin-4,9-diones are formed by a hetero-Diels-Alder reaction and 1,4-Michael addition reaction, respectively. A mechanism for the formation of the reaction products is presented. 相似文献
6.
Improta R Mele F Crescenzi O Benzi C Barone V 《Journal of the American Chemical Society》2002,124(26):7857-7865
The importance of vicinal and long-range interresidue effects in determining the stability of the collagen triple helix has been investigated by quantum mechanical (QM) and molecular mechanical (MM) computations on suitable model polypeptides, taking into account solvent effects by the polarizable continuum model (PCM). At the QM level, the PII conformation corresponds to an energy minimum for pentapeptide analogues incorporating the sequence Gly-Pro-Pro-Gly, irrespective of the down or up puckering of the pyrrolidine ring. However, our computations indicate that the alternation of down and up prolines characterizing collagen and collagen-like peptides is not due to an intrinsic preference of the Pro-Pro-Gly sequence. This result is confirmed by MM computations of longer polypeptides. Next, MM computations on model triple helices show that a better packing is obtained for specific values of backbone dihedrals, which, in turn, favor the alternation of down and up prolines along each chain. 相似文献
7.
G. Graziano G. Barone F. Catanzano A. Riccio 《Journal of Thermal Analysis and Calorimetry》1995,44(4):765-775
A general feature of temperature-induced reversible denaturation of small globular proteins is its all-or-none character. This strong cooperativity leads to think that protein molecules, possessing only two accessible thermodynamic states, the native and the denatured one, resemble ‘crystal molecules’ that melt at raising temperature. An analysis, grounded on mean field theory, allows to conclude that the two-state transition is a first-order phase transition. The implication of this conclusion are briefly discussed. 相似文献
8.
Guido Barone Giuseppina Castronuovo Vittorio Crescenzi Vittorio Elia Eugenio Rizzo 《Journal of solution chemistry》1978,7(3):179-192
In order to clarify some aspects of the hydrophobic interactions, the enthalpies of dilution of monoethylurea, 1,3-dimethylurea,
and 1,3-diethylurea have been determined calorimetrically at 25°C. The calorimetric data, expressed in terms of excess enthalpy,
permit the evaluation of the pair and triplet interaction coefficients. The analyses of these and of the analogous coefficientsg
xx andg
xxx, derived from osmotic data, indicate a driving force favorable to the interactions among the hydrated solute molecules. Nevertheless,
the positive values of theh
xx andh
xxx coefficients seem to suggest that the source of the effect is a rearrangement of the water molecules rather than a direct
association of the solute molecules. There are evidences of a strict correlation between the enthalpic and the entropic effects.
Preliminary data were presented at the International Conferences on Chemical Thermodynamics at Baden (1973) and Montpellier
(1975). The experimental part was carried out at the Istituto Chimico of the University of Trieste.
To whom correspondence should be addressed. 相似文献
9.
Barone V Bencini A Gatteschi D Totti F 《Chemistry (Weinheim an der Bergstrasse, Germany)》2002,8(21):5019-5027
Density functional theory (DFT) was applied to describe the magnetic and electron-transfer properties of dinuclear systems containing the [MnO2Mn]n+ core, with n=0,1,2,3,4. The calculation of the potential energy surfaces (PESs) of the mixed-valence species (n=1,3) allowed the classification of these systems according to the extent of valence localization as Class II compounds, in the Robin-Day classification scheme. The fundamental frequencies corresponding to the asymmetric breathing vibration were also computed. 相似文献
10.
G. Barone S. Capasso P. Del Vecchio C. De Sena D. Fessas C. Giancola G. Graziano P. Tramonti 《Journal of Thermal Analysis and Calorimetry》1995,45(6):1255-1264
In a previous paper, we report a preliminary DSC study on bovine (BSA) and human (HSA) serum albumins. However, at accurate HPLC analysis the commercial proteins show three peaks: Fraction V-I, probably globulins (as declared by the producers), Fraction V-II (about 15–18% of the product) and Fraction V-III that represents pure BSA or HSA. A hypothesis is that the Fraction II is a covalent dimer, or trimer or a mixture of both, generated during the scalf-life of the commercial product. Denaturation enthalpies of the purified Fraction V-III and Fraction V-II of BSA, have been determined calorimetrically, at changing thepH, and the results of both compared with those obtained on the untreated protein. Few calorimetric experiments have been also carried on a BSA monomer derivative with sulphidril group protected. Computer program have been developed for the deconvolution of exo- and endothermic effects and for the analysis of thermal denaturation profiles. 相似文献