全文获取类型
收费全文 | 111篇 |
免费 | 2篇 |
国内免费 | 1篇 |
专业分类
化学 | 22篇 |
晶体学 | 1篇 |
力学 | 6篇 |
数学 | 21篇 |
物理学 | 64篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2021年 | 5篇 |
2020年 | 3篇 |
2019年 | 4篇 |
2018年 | 5篇 |
2017年 | 6篇 |
2016年 | 4篇 |
2015年 | 2篇 |
2014年 | 4篇 |
2013年 | 4篇 |
2012年 | 2篇 |
2011年 | 5篇 |
2010年 | 6篇 |
2009年 | 3篇 |
2008年 | 4篇 |
2007年 | 3篇 |
2006年 | 3篇 |
2005年 | 1篇 |
2004年 | 1篇 |
2002年 | 7篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1999年 | 5篇 |
1998年 | 3篇 |
1997年 | 1篇 |
1996年 | 4篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1975年 | 2篇 |
1973年 | 1篇 |
1967年 | 1篇 |
1966年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有114条查询结果,搜索用时 15 毫秒
1.
2.
3.
NMR spectroscopic studies reveal that binding of Na(+) by tris(2-methoxyphenyl)amine (3) brings two of these tripod ethers together about the metal ion; the related double-tripod-ether ionophore 1,2-bis[2-(bis(2-methoxyphenyl)amino)phenoxy]ethane (4), in which two triarylamines are covalently attached, binds LiI, LiBPh(4), NaI, NaBPh(4), and KB(4-ClPh)(4). Dynamic NMR puts lower limits on binding free energies of 4 for Na(+) (71.8 kJ mol(-)(1)) and K(+) (66.8 kJ mol(-)(1)) ions. X-ray studies of 3(2).NaBPh(4), 4.NaBPh(4), 4.NaB(4-ClPh)(4), and 4.KB(4-ClPh)(4).CH(3)NO(2) show eight-coordinate M(+) ions bound between crystallographically independent, homochiral triarylamine tripod ethers in structures reminiscent of alkali metal [2.2.2] cryptates. Complexes crystallize as follows: 3(2).NaBPh(4), monoclinic, P2(1)/c, Z = 4, a = 10.701(3) ?, b = 37.593(3) ?, c = 13.774(2) ?, and beta = 98.24(2) degrees; 4.NaBPh(4), triclinic, P&onemacr;, Z = 2, a = 12.157(1) ?, b = 14.811(1) ?, c = 15.860(2) ?, alpha = 105.400(8) degrees, beta = 91.594(9) degrees, and gamma = 95.354(8) degrees; 4.NaB(4-ClPh)(4), monoclinic, P2(1)/n, Z = 4, a = 13.652(5) ?, b = 18.75(1) ?, c = 22.805(5) ?, and beta = 92.21(5) degrees; 4.KB(4-ClPh)(4).CH(3)NO(2), monoclinic, Pn, Z = 2, a = 13.663(4) ?, b = 12.228(3) ?, c = 18.712(8) ?, and beta = 91.45(3) degrees. They show variable N-M-N angles; 3(2).NaBPh(4) is surprisingly bent ( angleN-Na-N = 154.5 degrees ), while the 4.M(+) complexes are normal: nearly linear for Na(+) ( angleN-Na-N = 178.6, 178.1 degrees ) and again bent with the larger K(+) ( angleN-K-N = 164.5 degrees ). Finally, free 4 is structurally similar to 3; it crystallizes in the triclinic space group P&onemacr;, with Z = 2, a = 8.068(1) ?, b = 14.599(2) ?, c = 16.475(3) ?, alpha = 115.43(1) degrees, beta = 92.51(1) degrees, and gamma = 90.40(1) degrees. 相似文献
4.
5.
6.
V. S. Reznik V. S. Bakulin Yu. S. Shvetsov B. E. Ivanov 《Russian Chemical Bulletin》1975,24(6):1290-1293
Conclusions Some esters of -(oxodihydro-N-pyrimidinyl)butyl- and -(oxodihydro-N-pyrimidinyi)pentylphosphonic acids, and also some diphenyl -(2,4-dioxo-6-methyl-1,2,3,4-tetrahydro-N-pyrimidinyl)alkyl phosphates, were synthesized.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1397–1401, June, 1975. 相似文献
7.
8.
Novakov I. A. Sheikin D. S. Ruchko E. A. Brunilina L. L. Vernigora A. A. Salykin N. A. Vostrikova O. V. Chapurkin V. V. Nawrozkij M. B. Kurkin D. V. Bakulin D. A. Vorontsov M. Yu. Sablina L. A. Kovalev N. S. Tyurenkov I. N. 《Russian Chemical Bulletin》2021,70(11):2220-2226
Russian Chemical Bulletin - Novel structural analogs of isothiobarbamine, which differ from the prototype scaffold by the substituent at position 2 of the pyrimidine heterocycle, were for the first... 相似文献
9.
A. M. Zyuzin M. A. Bakulin V. V. Radaikin N. V. Yantsen 《Physics of the Solid State》2017,59(2):268-273
Zero spin-wave mode in inhomogeneous magnetic films with orthorhombic anisotropy has been found to exhibit a change of its localization region in two of three typical angular dependences of resonance fields of high-intensity modes. It has been shown that the anisotropy fields on both sides of the film can be determined from the resonance fields of the zero and uppermost high-intensity spin-wave modes of spin-wave resonance spectra. 相似文献
10.