Widely tunable, high-repetition-rate, dual signal-wave optical parametric oscillator by using two periodically poled crystals

This paper reports on a high-repetition-rate dual signal-wave (DSW) optical parametric oscillator (OPO) operating at the 1.5 μm band with tunable wavelength intervals from 2.5 nm to 69.1 nm. Two periodically poled crystals, a periodically poled lithium niobate (PPLN) with multiple gratings and a single grating MgO-doped PPLN (PPMgOLN), are cascaded in the same OPO cavity to generate dual signal-waves by using quasi-phase-matched (QPM) technique. The pump source was a Q-switched diode-pumped Nd:YVO₄ laser operating at 50 kHz. At an incident pump power of 3 W, an average output power of 169.6 mW at 1489.2 nm and 1558.3 nm has been achieved.     

Influence of the KTP crystal boundary temperature on conversion efficiency in high power green laser

The influence of the KTiOPO4 (KTP) crystal boundary temperature on conversion efficiency in high power green laser has been studied theoretically and experimentally. Temperature distribution inside the KTP crystal has been analyzed by solving the thermal conductivity equation. From the temperature distribution inside the KTP crystal, we have calculated the optimal phase-matching angles of the type-Ⅱ KTP crystal as a function of temperature. The second-harmonic conversion efficiency as a function of temperature has also been calculated. In the experiment, two KTP crystals with different phase-matching angles were used in the intrcavity-frequency-doubled resonator. When the boundary temperature of KTP-A (φ = 23.6°,θ = 90° under the condition of 27 ℃ temperature) was setting at 4 ℃, a maximum green light power of 104 W was generated at repetition rate of 20.7 kHz and pulse width of 132 nm with pumping current of laser diode of 18.3 A, leading to 10.2% optical-to-optical conversion efficiency. When KTP-B crystal (φ = 24.68°, θ = 90° under the condition of 80 ℃ temperature) was employed, an average output power of 110 W at 532 nm has been achieved with values of 11.5% and 2% for the optical-to-optical efficiency and the instability, respectively. The optimal boundary temperature of this KTP crystal has been found to be 48.8 ℃.     

Defluorination and Mineralization of Difluorophenols in Water by Anodic Contact Glow Discharge Electrolysis

Anodic contact glow discharge electrolysis (CGDE) is a DC-excited atmospheric pressure discharge, in which a steady non-thermal plasma is generated locally between the surface of an electrolytic solution and an anode in contact with it. The I–U characteristics of CGDE were investigated. The plasma temperatures were estimated to be in the range, 1373–2045 K. Hydroxyl radicals and hydrogen peroxide were the main oxidants generated by CGDE. The hydrogen peroxide concentration reached 31.2 mmol/L (mM) in a phosphate buffer solution without organic substrates. During CGDE, the DFPs and the corresponding total organic carbon (TOC) in water were consumed. Most of the fluorine atoms in the DFPs were converted to fluoride ions, and the fluoride concentration increased steadily. An analysis of the hydroxylation of DFPs suggested that the hydroxyl radicals generated by CGDE were the key species responsible for the degradation of DFPs, and the possible mechanistic routes of the mineralization of DFPs are proposed. The disappearance of DFPs and the TOC as well as the defluorination of the DFPs followed first-order kinetics. The rate of TOC disappearance was relatively constant: 1.00 ± 0.05 × 10^?2 min^?1. The order of disappearance of the DFPs was 2,6-DFP > 2,3-DFP > 2,5-DFP > 2,4-DFP > 3,4-DFP > 3,5-DFP. In contrast, the order of defluorination of the DFPs was 2,5-DFP > 2,3-DFP > 2,6-DFP > 2,4-DFP > 3,4-DFP > 3,5-DFP. Overall, the order of the reaction rates for each DFP was k_DFP > k_dF > k_TOC.     

104W内腔倍频全固态Nd∶YAG绿光激光器

报道了一台高功率内腔倍频全固态Nd∶YAG绿光激光器 ,针对KTP晶体热效应和激光热稳定腔 ,采取了对KTP晶体进行低温冷却的优化措施 ,以便减少KTP晶体的热效应导致的相位失配 ,同时兼顾了Nd∶YAG棒的热致双折射效应和KTP晶体热透镜效应 ,设计了热稳定谐振腔 ;实验中采用 80个 2 0W激光二极管阵列侧面抽运Nd∶YAG棒和Ⅱ类相位匹配KTP晶体 (在 2 7℃时相位匹配角为 =2 3.6° ;θ =90° ,尺寸为 7mm× 7mm× 10mm)内腔倍频技术 ,谐振腔腔长为 5 30mm ,KTP晶体的冷却温度为 4 .3℃ ,抽运电流为 18.3A时 ,实现平均功率达 10 4W、脉冲宽度为 130ns的 5 32nm激光输出 ;其重复频率为 2 0 .7kHz。光光转换效率为 10 .2 %。     

Development of electrochemical performances of carbon black obtained by the surface organosilicon-modified method

Carbon black (CB) was simply modified by tert-butylchlorodimethylsilane (TBDMCl) to form the–C–OSiR and–C–OOSiR structures on the surface of CB. The formation of–C–OSiR and–C–OOSiR structures on CB was verified by FTIR and XRD measurements. The modified carbon black (MCB) has relative high electrochemical performance, which was determined by electrochemical studies. The first charging capacity of MCB is at 343 mAh g^–1 and the conductivity of MCB is at 148.1 Sm^–1 which is similar to that of CB 155.2 Sm^–1. These results indicate that application of the obtained MCB will be promising for lithium anode materials. Meanwhile, these results can also suggest solving the overproduction problem of CB in China.     

Synthesis of an ordered porous carbon with the dual nitrogen-doped interfaces and its ORR catalysis performance

Both nitrogen-doping feature and pore structure are critical factors for developing nitrogen-doped carbons based catalysts with a high performance toward oxygen reduction reaction(ORR).Herein,a simple one-step CVD of acetylene and acetonitrile vapor method using silanized SBA-15 as a template has been developed to synthesize an ordered porous carbon(OPC) with dual nitrogen-doped interfaces.The optimized sample as prepared with the CVD of 4 h at 750℃ contains two types of ordered mesopores that one type is the ordered cylindrical pores inheriting from the pores of SBA-15 and has a pore width of4.0~5.0 nm,the other type is the ordered quasi-hexagonal pores with a width of 3.0~4.0 nm produced by etching the pore walls of SBA-15.These two types of pores whose pore walls are built by the nitrogen doped carbon layers resulted by the CVD and thus it actually makes the dual nitrogen-doped interfaced OPC(DN-OPC).Meanwhile,DN-OPC contains a few of micropores and a large SSA of 1430 m~2/g.This dualordered pores and dual nitrogen-doped interfaces cannot only facilitate mass transport but also utilize the active sites of DN-OPC for ORR.Therefore,as metal-free ORR catalyst,DN-OPC exhibits a good activity close to commercial Pt/C catalyst,and an excellent durability and methanol tolerance.     

High-power simultaneous dual-wavelength emission of an end-pumped Nd:YAG laser using the quasi-three-level and the four-level transition

An efficient continuous-wave (CW) simultaneous dual-wavelength lasing (SDWL) of an LD end-pumped Nd:YAG laser utilizing a quasi-three-level transition at 946 nm and a four-level transition at 1064 nm is reported. A theoretical model has been introduced to determine the threshold conditions for SDWL. The temperature distributions of a Nd:YAG crystal under different pump powers have been analyzed. In the experiments, a CW SDWL output power of 5.12 W at a temperature of 273 K has been achieved with a pump power of 17 W, giving a slope efficiency of 16.36%.     

Mid-infrared tunable dual-wavelength generation based on a quasi-phase-matched optical parametric oscillator

We report an efficient optical parametric oscillator (OPO) of dual idler wave output based on periodically poled MgO:LiNbO₃ with a periodically-phase-reversed grating structure, which is pumped by a Q-switched 1.064 μm laser with a repetition rate of 50 kHz. 0.98 W of dual idler-waves at 3.824 μm and 3.731 μm is achieved at room temperature, leading to a 12.9% conversion efficiency. The crystal temperature tuning provides output tunability of the dual idler wavelengths. In addition, the sum frequency generation of the dual signal waves is simultaneously observed in the OPO cavity.     

Theoretical study of the electro-optic effect of aperiodically poled lithium niobate in a Q-switched dual-wavelength laser

The electro-optic effect of aperiodically poled lithium niobate (APLN) has been theoretically investigated and proposed to use as a Q-switch in a simultaneous dual-wavelength laser. Our analysis shows that the polarization planes of the z-polarized (or y-polarized) dual-wavelength beams can be simultaneously rotated by 90° through a well-constructed APLN with an external electric field applied along the y-axis, which enables Q-switch function in a dual-wavelength laser cavity. Using a Nd:YVO₄ laser operating at 1.0643 μm and 1.3419 μm as an example, we present a design method of APLN by using the so-called simulated annealing algorithm. The influence of the domain errors in fabricating an APLN device is also studied. The results show that the device is not susceptible to the fabrication errors.     

Tunable quasi-phase-matched optical parametric generator by translating a segmented crystal

A simple way to realize a fast tunable quasi-phase-matched optical parametric generation without crystal rotation, temperature changing or multi-grating periodically poled crystal translation is presented. The key is to translate a segmented crystal which is stacked by a lithium niobate crystal with three teeth and a single grating periodically poled crystal. The signal wavelength is tunable near 1.55 μm with the signal power of 90 mW.