全文获取类型
收费全文 | 82篇 |
免费 | 2篇 |
专业分类
化学 | 19篇 |
数学 | 5篇 |
物理学 | 60篇 |
出版年
2023年 | 2篇 |
2021年 | 1篇 |
2018年 | 1篇 |
2015年 | 2篇 |
2014年 | 4篇 |
2013年 | 2篇 |
2012年 | 2篇 |
2011年 | 6篇 |
2010年 | 6篇 |
2009年 | 12篇 |
2008年 | 7篇 |
2007年 | 3篇 |
2006年 | 8篇 |
2005年 | 1篇 |
2004年 | 4篇 |
2003年 | 4篇 |
2002年 | 1篇 |
2001年 | 3篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1998年 | 2篇 |
1996年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1984年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有84条查询结果,搜索用时 15 毫秒
1.
Detection of hepatocarcinoma in rats by integration of the fluorescence spectrum: Experimental model
J. C. Marcassa J. Ferreira S. Zucoloto O. de Castro e Silva Jr. L. G. Marcassa V. S. Bagnato 《Laser Physics》2006,16(5):827-832
The incorporation of spectroscopic techniques into diagnostic procedures may greatly improve the chances for precise diagnostics. One promising technique is fluorescence spectroscopy, which has recently been used to detect many different types of diseases. In this work, we use laser-induced tissue fluorescence to detect hepatocarcinoma in rats using excitation light at wavelengths of 443 and 532 nm. Hepatocarcinoma was induced chemically in Wistar rats. The collected fluorescence spectrum ranges from the excitation wavelength up to 850 nm. A mathematical procedure carried out on the spectrum determines a figure of merit value, which allows the detection of hepatocarcinoma. The figure of merit involves a procedure which evaluates the ratio between the backscattered excitation wavelength and the broad emission fluorescence band. We demonstrate that a normalization allowed by integration of the fluorescence spectra is a simple operation that may allow the detection of hepatocarcinoma. 相似文献
2.
L. G. Marcassa V. A. Nascimento L. L. Caliri A. Caires D. V. Magalhães V. S. Bagnato 《Laser Physics》2006,16(12):1722-1725
In this paper, we report observation of an enhancement of the ground state molecule Rb2 formation in a Rb magneto-optical trap due to a photoassociation laser. Such an enhancement effect is due to flux enhancement of atomic pairs at short internuclear distances. Our experimental observations consist in the measurement of the molecular formation rate constant due to a probe laser as a function of the trap laser intensity. The results are compared with a simple semi-classical model, showing good agreement. We conclude that the production of cold Rb2 may be enhanced using appropriate laser parameters; this may be useful for future experiments involving production and trapping of ultracold ground state molecules. 相似文献
3.
4.
5.
A protocol for the rapid NMR characterization of cobalamin (vitamin B(12)) analogues with 5'-hydroxy-alpha-ribofuranoside modification is reported. The structure of cyanocobalamin in DMSO-d(6) has been assigned using COSY, NOESY, HSQC, and HMBC NMR methods. The robust precision of (13)C NMR assignments in DMSO-d(6) allows for the rapid structural determination of 5'-hydroxy-alpha-ribofuranosyl cyanocobalamin derivatives with solely 1-D (13)C and DEPT NMR spectra and only 10 mg of derivatized cobalamin. Using this method, the (13)C NMR resonances of four cobalamin analogues were determined with the most significant variance of (13)C chemical shifts occurring in the alpha-ribofuranoside ring. In DMSO-d(6), cobalamin concentrations greater than 30 mM can be achieved for an improved signal-to-noise ratio. 相似文献
6.
Usually, the large trap loss rates observed in MOTs at the low light intensity regime have been associated with hyperfine change collisions (HCC). We propose an alternative mechanism to explain the sudden raise up of trap loss rates at low intensity without relying on HCC. Using the Gallagher-Pritchard model [Phys. Rev. Lett. 63, 957 (1989)] together with an intensity dependent escape velocity, we were able to reproduce qualitatively well some existing experimental results, including recent observations by Nesnidal et al. [Phys. Rev. A 62, 030701(R) (2000)]. This result reopens the discussion in order to better understand the physical mechanisms and their actual contribution to the trap losses. 相似文献
7.
Photodithazine (PDZ) is an N-methyl-D-glucosamine derivative of chlorine e6 that is water soluble and has an intense absorption in the range of 650?C680 nm. PDZ photobleaching and photoproduct formation were induced by illumination with laser at two wavelengths: 514 nm (ion argon laser) as well as in 630 nm (dye laser). The time constants of PDZ photobleaching were: 18 min for 630 nm irradiation and 50 min for 514 nm irradiation, suggesting that degradation after irradiation with red light is faster than with green light. Photoproducts formation was evidenced by the appearance of a new absorption band at 668 nm with slight broaden of the Soret band, suggesting that there was no break of the macrocycle. The cytotoxicity of the photodegradated PDZ was investigated and showed to be lower in the dark and higher than non irradiated PDZ. These results may have important clinical implications for PDT such as the possibility to use the previously irradiated PDZ just before clinical application in order to get increased efficiency. 相似文献
8.
Gustavo Nicolodelli Cristina KurachiVanderlei Salvador Bagnato 《Applied Surface Science》2011,257(7):2419-2422
Femtosecond laser ablation of materials is turning to be an important tool for micromachining as well as for selective removal of biological tissues. In a great number of applications, laser ablation has to process through interfaces separating media of different properties. The investigation of the ablation behavior within materials and passing through interfaces is the main aim of this study. Especially, the analysis of the discontinuity in the ablation profile close to interfaces between distinct materials can reveal some of the phenomena involved in the formation of an ablated microcavity geometry. We have used a method that correlates the ablation cross sectional area with the local laser intensity. The effective intensity ablation properties were obtained from surface ablation data of distinct materials. The application of this method allows the prediction of the occurrence of a size discontinuity in the ablation geometry at the interface of distinct media, a fact which becomes important when planning applications in different media. 相似文献
9.
S. S. Rojas G. J. M. Frigo M. I. B. Bernardi A. N. de S. Rastelli A. C. Hernandes V. S. Bagnato 《Journal of Thermal Analysis and Calorimetry》2010,99(1):263-268
We have investigated the thermal and structural properties of different commercial dental resins: FiltekTM Z-350, Grandio®, Tetric Ceram®, and TPH Spectrum®. The purpose of the present study was to evaluate quantitatively the photo-polymerization behavior and the effect of filler contents on the kinetic cures of the dental resins by using Differential Scanning Calorimetry (DSC) and Fourier Transform Infrared Spectroscopy (FT-IR) techniques. We have successfully obtained the low and high glass transition T g values of the dental composite resins from DSC curves. It was also observed a good agreement between the both T g values, activation energies from thermal degradation, and the degree of conversion obtained for all samples. The results have shown that Tetric Ceram® dental resin presented the higher T g values, activation energy of 215 ± 6 KJ mol?1, and the higher degree of conversion (63%) when compared to the other resins studied herein. 相似文献
10.
Fabio D’Agostino Elvira Oliveri Emanuela Bagnato Francesca Falco Salvatore Mazzola Mario Sprovieri 《Analytica chimica acta》2014
The aim of this work was to develop a new method to determine the mercury (Hg) concentrations in phosphate rock using a dedicated analytical instrument (the DMA80 Tricell by Milestone) that employs an integrated sequence of thermal decomposition followed by catalyst conversion, amalgamation and atomic absorption spectrophotometry. However, this instrument underestimates Hg concentrations when phosphorite and apatite rocks are investigated with a classic thermal decomposition treatment that complies with US EPA method 7473. 相似文献