N_2和O_2纯转动拉曼光谱(PRRS)的温度特性

计算了N2 和O2 的PRRS ,讨论了其温度特性。提出通过测量N2 和O2 的PRRS计算大气温度的方法。     

关于体上分块矩阵的群逆

本文利用分块矩阵方法．研究了体上两个矩阵乘积的群逆的存在性及表示形式，给出了体上两个矩阵乘积群逆存在的充分必要条件和表示形式．并且在一定条件下．给出了体上分块矩阵的群逆存在性及表示形式．     

19F+27Al耗散反应中双核系统的转动与形变

测量了¹⁹F+²⁷Al耗散反应产物B,C,N,O,F和Ne的激发函数,入射束流的能量从110.25MeV到118.75MeV, 能量步长为250keV. 从产物的 能量自关联函数中提取了反应中所形成的中间双核系统的转动惯量, 与相粘模型计算的刚体转动惯量相比较, 结果表明形成的双核系统有大的形变.     

On congruence lattices of regular semigroups with Q-inverse transversals

Communicated by F. Pastijn     

草酰胺分子构型、稳定性、IR光谱及分子轨道的密度泛函与从头算研究

运用多种密度泛函理论 (DFT)和从头算 (abinitio)方法研究了草酰胺顺、反异构体的分子几何构型 ,结果表明Beck88交换函数与LYP非局域相关函数形成杂化的DFT方法B3LYP与MP2方法计算结果比较吻合。在此基础上选择B3LYP方法对草酰胺分子电子结构、红外光谱和前线分子轨道组成进行了系统研究 ;与实验事实对比分析了气态草酰胺分子中配位原子的反应活性     

小长径比垂直管气液两相流动特性分析

实验观察了小长径比垂直上流管内流型及特点,并对管入口处的压力波动特性和系统的压差波动特性进行了试验研究.结果表明:小长径比(L/D)垂直管内流型表现为泡状流、塞状流、乳沫状流、环状流和液束环状流;分别增加管线中的气量、液量,或者同时增加气液流量,均会造成垂直管入口处压力波动的均值和最大压力的增加;压力信号的概率密度(PDF)大部分呈双峰分布,也存在单峰和多峰分布;差压信号的概率密度符合正态分布,其功率谱密度同压力信号相比具有频率波动范围宽、幅值小的特点.     

溶液中CO…CO+体系相互作用的理论研究

在B3LYP/6-311+G水平上利用SCRF方法中的Onsager model模型考察了CO…CO+体系在两种介质(水和苯)中可能存在的相互作用复合物,发现由于H2O与CO+之间存在较强的相互作用,在水中仅能存在一种稳定结构,而在苯溶液中存在三种稳定的复合物.通过消除基函数引起的叠加误差(BSSE)和零点振动能(ZPVE)的校正,精确求算出三种复合物在两种介质中的相互作用能,表明溶剂的性质对复合物的稳定性有着重要的影响.     

Synchronizing Complex Networks by an Adaptive Adjustment Mechanism

We propose an adaptive adjustment mechanism for synchronizing complex networks, in particular for sociological or/and biological systems. We do not take it for granted that a dynamical system is put on isolated nodes and they are coupled with each other by one （or more） variable（s）, as employed in most previous models. As a replacement, we suppose that each node may have any finite number of possible states, and their evolutions with time are determined by their nearest-neighbouring （or even second-nearest-neighbouring, etc） nodes in an adaptive adjustment mechanism. It is found that synchronization can be achieved for almost all connected networks and that the scale-free property can evidently improve the synchronizing speed.     

YZr2OZr3:Er3+纳米晶anti-Stokes发光性质的研究

采用均相沉积法制备了不同Er³⁺离子浓度掺杂的Y₂O₃纳米晶, 应用XRD，SEM和PL光谱对该体系材料进行了表征.在Y₂O₃:Er³⁺纳米材料体系中, 观察和研究了Stokes及anti-Stokes PL谱强度与Er³⁺离子摩尔浓度变化的关系, 当Er³⁺离子浓度为2.0mol%时, anti-Stokes PL强度最强.粉末X 关键词： 氧化钇纳米晶 anti-Stokes PL 双光子吸收     

Synthesis,crystal structure and property of a novel azide-bridged one-dimensional chain copper(II) complex with a dinucleating macrocyclic polyamine

An azide-bridged polymeric cationic chain complex, [LCu₂(N₃)₂]n(ClO₄)_2n ·n(H₂O)**, where L=the dinucleating macrocyclic ligand bis-p-xylylBISDIEN, has been prepared and characterized by x-ray crystallography, u.v.-vis and i.r. spectra, and by magnetic measurements. The structure consists of cationic azide-bridged [LCu₂(N₃)₂]²⁺ (unit) chains, non-coordinated perchlorate anions and crystallized water molecules. The azide anion is bound to two copper atoms in neighboring units with an end-to-end bridging mode. In each unit, the copper atoms have a different coordination geometry; Cu(1) is a four-coordinated, distorted square-planar geometry, whereas Cu(2) is a five-coordinated, distorted square-pyramid. The electronic spectra of the title complex differ in anhydrous and in aqueous MeCN solutions, indicating that dissociation and solvation occur in aqueous solutions. The characteristic i.r. absorptions of azides and perchlorates are described. Magnetic moments vary from 2.05 (B.M.) at 300K to2.01 (B.M.) at 80K, which suggests that very weak interactions exist between the metals.