全文获取类型
收费全文 | 121篇 |
免费 | 2篇 |
专业分类
化学 | 95篇 |
晶体学 | 2篇 |
力学 | 1篇 |
数学 | 3篇 |
物理学 | 22篇 |
出版年
2021年 | 4篇 |
2020年 | 4篇 |
2019年 | 3篇 |
2017年 | 2篇 |
2016年 | 1篇 |
2015年 | 1篇 |
2014年 | 1篇 |
2013年 | 4篇 |
2012年 | 1篇 |
2011年 | 6篇 |
2010年 | 5篇 |
2009年 | 5篇 |
2008年 | 9篇 |
2007年 | 10篇 |
2006年 | 10篇 |
2005年 | 3篇 |
2004年 | 7篇 |
2003年 | 5篇 |
2002年 | 4篇 |
2001年 | 7篇 |
2000年 | 3篇 |
1999年 | 6篇 |
1998年 | 5篇 |
1997年 | 2篇 |
1996年 | 3篇 |
1988年 | 1篇 |
1984年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1973年 | 6篇 |
1972年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有123条查询结果,搜索用时 15 毫秒
1.
Hyunkook Park Machiko Tsukiji Kazuaki Wagatsuma SangChun Lee 《Analytical sciences》2007,23(9):1133-1136
The emission characteristics of several Cu lines emitted from a Ne-Ar mixed gas glow discharge plasma were investigated. The addition of small amounts of Ar to a Ne plasma increases the sputtering rate of a Cu sample because Ar ions, which work as the impinging ions for cathode sputtering, are predominantly produced through Penning ionization collisions between Ne metastables and Ar atoms. Ar addition also elevates the number density of electrons in the plasma. These changes occurring in the Ne-Ar mixed gas plasma result in enhanced emission intensities of the Cu lines. The Cu II 270.10-nm and the Cu II 224.70-nm lines yield different intensity dependence on the Ar partial pressure added. This phenomenon is because these Cu II lines are excited principally through different charge transfer processes: collisions with Ne ions for the Cu II 270.10-nm line and collisions with Ar ions for the Cu II 224.70-nm line. The shape of sputtered craters in the Ne-Ar glow discharge plasma was measured. The depth resolution was improved when Ar was added to a Ne plasma because the crater bottoms were flatter with larger Ar partial pressures. 相似文献
2.
In order to obtain the depth profile of a thin film, we investigated the emission characteristics of a voltage modulation glow discharge to optimize the modulation parameters (modulation voltage, offset voltage, and modulation frequency). In this study, a phase-sensitive detection method with a lock-in amplifier to the modulation technique led to a higher sensitivity and a larger signal-to-noise ratio in the emission analysis compared to the normal dc amplification method. Upon increasing the maximum voltage, the emission intensity of the Cu atomic line (CuI 239.34 nm) increased linearly at a modulation voltage of 400 V and an offset voltage of 300 V. On the other hand, the emission intensity was gradually reduced when a modulation frequency increased. It is advantageous for surface analysis that the voltage modulation technique gives a lower sputtering rate rather than the conventional dc discharge. 相似文献
3.
Oishi S Kamano T Niida A Odagaki Y Hamanaka N Yamamoto M Ajito K Tamamura H Otaka A Fujii N 《The Journal of organic chemistry》2002,67(17):6162-6173
Diastereoselective synthesis of new psi[(E)-CH=CMe]- and psi[(Z)-CH=CMe]-type alkene dipeptide isosteres corresponding to dipeptides having one N-methylamino acid, and application to bioactive peptides, are described. In a key reaction introducing the chiral alpha-alkyl group of the isosteres, organocopper-mediated alkylation of syn-beta-methylated gamma-mesyloxy-alpha,beta-enoate 26a afforded E- and Z-isomers of anti-S(N)2' products in a solvent-dependent manner. The resulting two isosteres, D-Phe-psi[(E)-CH=CMe]-L-Val 27a and D-Phe-psi[(Z)-CH=CMe]-L-Val 28b, which corresponded to trans- and cis-conformers of D-Phe-L-MeVal, respectively, were utilized in a structure-activity relationship study on cyclic RGD peptides 1 and 2, in company with a psi[(E)-CH=CH]-type alkene dipeptide isostere, D-Phe-psi[(E)-CH=CH]-L-Val. The cyclic isostere-containing pseudopeptides 3, 4, and 40 were synthesized and biological activity against integrin alpha(V)beta(3) and alpha(IIb)beta(3) receptors were also evaluated. 相似文献
4.
Yûetsu Danzaki Kunio Takada Kazuaki Wagatsuma Masaoki Oku 《Analytical and bioanalytical chemistry》1998,361(5):410-418
A practical method to estimate spectral interferences and to select optimum analytical lines in ICP-AES is suggested. Depending on the matrix composition and the amounts of the analyte, the analytical lines suffering from little interferences and the limit of determination can be determined from calculation using spectral interference coefficients. For this calculation, the spectral interference coefficients, which are defined as apparent mass of the analyte equivalent to the spectral interference from unit mass of the interferent, are obtained experimentally for 639 emission lines of 68 elements. There is a good correlation between the coefficients obtained on two spectrometers having different resolutions. 相似文献
5.
Kazuaki Wagatsuma 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1996,37(3):231-239
The relative intensities of silver emission lines from Grimm glow discharge plasmas were investigated in the wavelength range from 160 to 600 nm when using different plasma gases. It was characteristic of the plasma excitation that the spectral patterns were strongly dependent on the nature of the plasma gas employed. Intense emission lines of silver ion were observed when argonhelium mixed gases were employed as the plasma gas. Selective excitation of the ionic lines could be principally attributed to the charge transfer collisions between silver atoms and helium ions. 相似文献
6.
Stabilization of the spark-discharge point on a sample surface by laser irradiation for steel analysis. 总被引:1,自引:0,他引:1
A combined technique with laser irradiation is suggested to control spark discharge for analytical use, having a unique feature that firing points of the spark discharge can be fixed by laser irradiation. Because the spark discharge easily initiates at particular surface sites, such as non-metallic inclusions, called selective discharge, the concentration of some elements sometimes deviates from their average one in spark discharge optical emission spectrometry. Therefore, stabilization of firing points on a sample surface could improve the analytical precision. 相似文献
7.
Oishi S Kamano T Niida A Odagaki Y Tamamura H Otaka A Hamanaka N Fujii N 《Organic letters》2002,4(7):1051-1054
[reaction: see text] Acyclic psi[(E)-CH=CMe]- and psi[(Z)-CH=CMe]-type dipeptide isosteres were efficiently synthesized. In a key reaction, alpha-alkylation of gamma-mesyloxy-beta-methyl-alpha,beta-unsaturated esters with organocyanocuprates in diethyl ether or tetrahydrofuran preferentially afforded the psi[(E)-CH=CMe]- or psi[(Z)-CH=CMe]-isomer, respectively, via anti-S(N)2' mechanism. 相似文献
8.
Masaoki Oku Toetsu Shishido Takeshi Shinohara Qiang Sun Yoshiyuki Kawazoe Kazuo Nakajima Kazuaki Wagatsuma 《Journal of solid state chemistry》2004,177(2):457-460
The solid solutions of ScBRh3-ScRh3 and CeBRh3-CeRh3 are synthesized by the arc melting method, where RBRh3 and RRh3 (R=rare earth element) have perovskite and AuCu3 type structures, respectively. The binding energy of Sc 2p3/2 for ScBxRh3 increases with the boron concentration. The Knight shift of 45Sc observed by nuclear magnetic resonance spectroscopy decreases with increase of boron concentration. The decrement of the Knight shift corresponds the Sc 4s electron density at the Fermi level. The intensity ratio of f2: f1: f0 of Ce 3d XPS spectrum changes with boron concentration of CeBxRh3. It is concluded that in both cases of ScBxRh3 and CeBxRh3 the charge on the atoms on A-site changes with the concentration of the atoms on B-site, where the atoms are not directly bound. 相似文献
9.
A high-powered, microwave-induced nitrogen–oxygen plasma (N2–O2–MIP) generated by using an Okamoto cavity at atmospheric pressure was investigated when the observation height, the flow rate of carrier gas, and the oxygen content were varied as the experimental parameters. The emission characteristics of the plasma were evaluated with regard to the excitation temperature and the intensity ratio of atomic line to ionic line. The excitation temperature of the N2–O2–MIP was in the range of 5100–5700 K when the oxygen content was varied from 0 to 30% at the observation height of 7 mm and the carrier gas flow rate of 0.6 l/min. The intensity ratio of atomic line to ionic line was elevated with an increase in the oxygen content. 相似文献
10.
Tetsuji Kametani Kazuo Kigasawa Mineharu Hüragi Nagatoshi Wagatsuma Setsu Saitoh Hideo Sugi 《Journal of heterocyclic chemistry》1973,10(3):313-315
Acid treatment of the alkylated products of (Va, Vb, and VIII) of piperidinols IVa and IVb, and tetrahydropyridine VII with β-bromoethylbenzene, afforded 1,2,3,4,5,6-hexahydro-8-hydroxy-2,6-methano-6,1 1-dimethyl-3-phenethyl-3-benzazocine (la) in good yield. Piperidinols Va and Vb were also obtained from the reaction of N-(3-methyl-3-pentenyl)-β-phenethylamine (IIb) with methyl 3-(4-methoxyphenyl)-2,3-epoxypropionate. 相似文献