Passive Boundary Layer Flow Control Using Porous Lamination

The flow over a porous laminated flat plate is investigated from a flow control perspective through experiments and computations. A square array of circular cylinders is used to model the porous lamination. We determine the velocities at the fluid–porous interface by solving the two-dimensional Navier–Stokes and the continuity equations using a staggered flow solver and using LDV in experiments. The control parameters for the porous region are porosity, \(\phi \) and Reynolds number, Re, based on the diameter of the circular cylinders used to model the porous lamination. Computations are conducted for \(0.4< \phi < 0.9\) and \(25< Re < 1000\), and the experiments are conducted for \(\phi = 0.65\) and 0.8 at \(Re \approx 391,\ 497\) and 803. The permeability of the porous lamination is observed to induce a slip velocity at the interface, effectively making it a slip wall. The slip velocity is seen to be increasing functions of \(\phi \) and Re. For higher porosities at higher Re, the slip velocity shows non-uniform and unsteady behavior and a breakdown Reynolds number is defined based on this characteristic. A map demarcating the two regimes of flow is drawn from the computational and experimental data. We observe that the boundary layer over the porous lamination is thinner than the Blasius boundary layer and the shear stress is higher at locations over the porous lamination. We note that the porous lamination helps maintain a favorable pressure gradient at the interface which delays separation. The suitable range of porosities for effective passive separation control is deduced from the results.     

Multiswitching compound–compound synchronisation of six chaotic systems

In this paper, multiswitching combination synchronisation (MSCS) scheme has been investigated in a class of three non-identical fractional-order chaotic systems. The fractional-order Lorenz and Chen systems are taken as the drive systems. The combination of multidrive systems is then synchronised with the fractional-order Lü chaotic system. In MSCS, the state variables of the two drive systems synchronise with different state variables of the response system, simultaneously. Based on the stability of fractional-order chaotic systems, the MSCS of three fractional-order non-identical systems has been investigated. For the synchronisation of three non-identical fractional-order chaotic systems, suitable controllers have been designed. Theoretical analysis and numerical results are presented to demonstrate the validity and feasibility of the applied method.     

A de Vries (SmC*) Phase in a Novel Series of Chiral Fluorinated Organosiloxane Liquid Crystals

The synthesis and characterization of a series of five chiral fluorinated low molar mass (bifurcated tail) organosiloxane materials is presented. The mesogenic moiety is similar to that in the TSiKN65F mesogen reported by Naciri et al., which displays a de Vries-type SmA* phase. The one parameter varied across the series reported herein is the length of the alkyl chain linking the mesogen's core to the bifurcated siloxane tail. One of the five materials displays a de Vries SmC* phase upon cooling from SmA*.     

Can the photon velocity be derived from the Klein-Gordon equation?

In their most recent article, Grado-Caffaro et al. have addressed the question of the ‘photon velocity’. They have expressed the photon velocity in terms of the wavefunctions of the Klein-Gordon equation (Grado-Caffaro and Grado-Caffaro [4]). In this note, we closely follow their work and explicitly obtain the photon velocity using the free solutions of the Klein-Gordon equation. It is shown that the plane wave solutions give rise to six possible values of the photon velocity. Two of these solutions are the most expected (v=±c). The remaining four solutions, the real pair ±0.786c and the imaginary pair ±1.272ic are difficult to comprehend.     

Synthesis,Kinetics, and Equilibrium Study of Highly Sensitive Colorimetric Chemosensor for Monitoring of Copper Ions based on Benzo[f]fluorescein Dye Derivatives

The colorimetric chemosensor 2‐((3,5‐dichloro‐2‐hydroxybenzylidene)amino)‐3′,6′‐dihydroxy‐6‐methyl‐4‐(p‐tolyl)spiro[benzo[f]isoindole‐1,9′‐xanthen]‐3(2H)‐one ( BFFSH ) derived from benzo[f]fluorescein dye was synthesized. NMR and IR spectroscopy as well as mass spectrometry were used to confirm the compound. BFFSH shows potential application for detecting metal ions in aqueous solution. It displays a colorimetric selectivity and sensitivity towards the aqueous solution of Cu²⁺ ions with a detection limit in the nano‐molar range (1.69 nM). In addition, the application of BFFSH was extended for the detection of Cu²⁺ ions in real water samples (tap and synthetic water) with a high recovery percentage. Additionally, the association constant (K_a) of BFFSH , which binds with Cu²⁺ ions based on 2:1 stoichiometry was calculated.     

The Lysozyme Inhibitor Thionine Acetate Is Also an Inhibitor of the Soluble Lytic Transglycosylase Slt35 from Escherichia coli

Lytic transglycosylases such as Slt35 from E. coli are enzymes involved in bacterial cell wall remodelling and recycling, which represent potential targets for novel antibacterial agents. Here, we investigated a series of known glycosidase inhibitors for their ability to inhibit Slt35. While glycosidase inhibitors such as 1-deoxynojirimycin, castanospermine, thiamet G and miglitol had no effect, the phenothiazinium dye thionine acetate was found to be a weak inhibitor. IC₅₀ values and binding constants for thionine acetate were similar for Slt35 and the hen egg white lysozyme. Molecular docking simulations suggest that thionine binds to the active site of both Slt35 and lysozyme, although it does not make direct interactions with the side-chain of the catalytic Asp and Glu residues as might be expected based on other inhibitors. Thionine acetate also increased the potency of the beta-lactam antibiotic ampicillin against a laboratory strain of E. coli.