全文获取类型
收费全文 | 370篇 |
免费 | 34篇 |
国内免费 | 1篇 |
专业分类
化学 | 313篇 |
晶体学 | 3篇 |
力学 | 3篇 |
数学 | 48篇 |
物理学 | 38篇 |
出版年
2023年 | 4篇 |
2022年 | 8篇 |
2021年 | 8篇 |
2020年 | 8篇 |
2019年 | 8篇 |
2018年 | 9篇 |
2017年 | 5篇 |
2016年 | 20篇 |
2015年 | 15篇 |
2014年 | 21篇 |
2013年 | 21篇 |
2012年 | 45篇 |
2011年 | 37篇 |
2010年 | 17篇 |
2009年 | 15篇 |
2008年 | 22篇 |
2007年 | 29篇 |
2006年 | 13篇 |
2005年 | 14篇 |
2004年 | 19篇 |
2003年 | 25篇 |
2002年 | 6篇 |
2001年 | 1篇 |
1999年 | 1篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1994年 | 1篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1972年 | 2篇 |
1968年 | 1篇 |
1967年 | 2篇 |
1966年 | 4篇 |
排序方式: 共有405条查询结果,搜索用时 12 毫秒
1.
This study compares the use of form and function analogy object boxes to more traditional lecture and worksheet instruction during a 10th‐grade unit on human body systems. The study was conducted with two classes (N= 32) of mixed ability students at a high‐needs rural high school in central New York State. The study used a pretest/posttest design, in which the two classes alternated between conditions for the four systems (skeletal, digestive, immune, nervous). Both conditions involved students in quality instruction addressing the same concepts for the same amount of time. Additionally, all students participated in hands‐on labs. The experimental condition presented students with a set of objects analogous in form and function to parts of a human body system. Students matched objects with cards describing body system parts, mapped the analogies on a chart, generated alternative objects that could be used for the analogy, and finally, created new analogies for other body system parts. Students made significantly higher posttest and gain scores on material learned in the experimental condition, with a mean gain score average of 12.4 points out of 25, compared to 6.2 points in the control condition. Cohen's Effect Size was large, 1.36. 相似文献
2.
This Note deals with optimal control problems with only one control variable and one state constraint, of arbitrary order. We consider the case of finitely many boundary arcs and touch times. We obtain a no-gap theory of second-order conditions, allowing us to characterize second-order quadratic growth. To cite this article: J.F. Bonnans, A. Hermant, C. R. Acad. Sci. Paris, Ser. I 343 (2006). 相似文献
3.
Audrey A S G Lonni Ieda S Scarminio Lucas M C Silva Dalva T Ferreira 《Analytical sciences》2003,19(7):1013-1017
Phytochemical investigation of the aerial parts of three Baccharis species (Asteraceae family) was performed using HPLC and chemometric methods, with the objective of distinguishing between three morphologically very similar species: Baccharis genistelloides Persoon var. trimera (Less.) DC, B. milleflora (Less.) DC and B. articulata (Lam.) Persoon. With the help of Principal Component Analysis (PCA) and variance weights, it was possible to characterize the chromatographic profiles of the alcoholic extracts of the three species. Application of Soft Independent Modeling of Class Analogy (SIMCA) and K-Nearest Neighbor (KNN) methods on a training set of 74 extracts resulted in models that correctly classified all eight samples in an independent test set. 相似文献
4.
[reaction: see text] Allylically oxygenated vinyl alpha-triphenylstannanes such as 22 can be readily converted into vinyl iodides and thereafter stereodefined trisubstituted alkenes with retention of configuration. 相似文献
5.
The influence of floc structure and floc concentration on the drag acting on a floc is investigated theoretically. A two-layer model is adopted to describe floc structure, and a cell model is used to simulate a floc dispersion. The influences of the key parameters of the problem under consideration, including floc concentration, Reynolds number, the ratio (permeability of outer layer/permeability of inner layer), and the ratio (thickness of outer layer/thickness of inner layer), on the drag coefficient are discussed. We show that the more heterogeneous the floc structure is, the greater the drag and the more significant the deviation of curve of variation of drag coefficient against Reynolds number from a Stokes-law-like relation. The drag on a floc declines with the decrease in floc concentration, and, due to the convective flow of the fluid, the distortion of streamlines surrounding a floc becomes more serious and the deviation of the variation of the curve of drag against Reynolds number from a Stokes-law-like relation is more significant. 相似文献
6.
A discrete-time system of a tandem of queues with exogenous arrivals and departures at each stage is considered. A customer leaving queuek–1 departs the system with probability 1–
[k]
and continues to queuek with probability
[k]
. Exogenous arrivals to each stage are i.i.d. at each time slot. An approximate analysis of the occupancy and busy-period distributions of each stage based on a General Busy-period with batches and Memoryless (geometric) Idle period renewal Process (GBMIP) provides improved performance over two-state Markov approximations and gives exact results when there are no interstage departures.This research was supported in part by NSF grant NCR-8708282. 相似文献
7.
Ong ES Len SM Lee AC Chui P Chooi KF 《Rapid communications in mass spectrometry : RCM》2004,18(21):2522-2530
Scutellariae radix or Scutellaria baicalensis is a medicinal plant that contains major flavonoids such as baicalein, baicalin, wogonin and wogonosides. The present work describes the development of an approach using proteomic analysis of mouse liver to study the effects of prolonged exposure to substances present in chemically standardized Scutellariae radix extracts. Histopathological examination of the mouse liver was compared with the proteome data. The botanical extracts were prepared using pressurized liquid extraction (PLE). A method without isotope labeling was developed, using proteolytic digestion with one- and two-dimensional liquid chromatography with tandem mass spectrometry, and was used to characterize the extent of differential protein expression in mouse liver in response to external factors such as extracts from Scutellariae radix. From the histopathological examination and proteome data, significant changes in the mouse livers were not observed for the low-dose group. The Scutellariae radix extracts at high dose were observed to cause damage at the bile duct and expression change of a number of proteins including some involved in catabolism of triglyceride-rich particles, carbohydrate metabolism, regulators of cell signaling processes, and enzymes involved in biotransformation. Thus, proteomic analysis of liver samples from mice treated with botanical extracts is a promising approach to provide information on any potential toxicity effects of the extracts. The present method also provides another means for comparing proteomes in biological samples such as liver lysates from mice subjected to different treatments. 相似文献
8.
Zeev Elkoshi Howard Reiss Audrey Dell Hammerich 《Journal of statistical physics》1985,41(3-4):685-708
A hole in a fluid is specified in a well-defined manner. The concentration of holes is a thermodynamic property of the fluid and we derive this concentration in three different ensembles for a one-dimensional fluid of hard rods. The thermodynamics of these rigorously defined holes is developed, and the properties of holes are explored. The ensemble in which the concentration of holes is maintained fixed exhibits dramatic properties. Finally, pair correlation functions for hard rods in the various ensembles are computed. Contrary to a frequently made assumption, the equilibrium number of holes is found to never be proportional to the probability of finding a single hole in the fluid. Constraining the concentration of holes as well as the density leads to dramatic structural effects prominently displayed by the pair correlation function. The ensemble in which the concentration of holes is fixed is an example of an internally constrained metastable system. 相似文献
9.
Dupont A Eastoe J Martin L Steytler DC Heenan RK Guittard F Taffin de Givenchy E 《Langmuir : the ACS journal of surfaces and colloids》2004,20(23):9960-9967
Hybrid fluorocarbon-hydrocarbon (F-H) sulfate surfactants are shown to be efficient stabilizers in water-in-CO2 (w/c) microemulsions. The chain structure and F-H ratio affect the regions of P-T phase stability and aggregation structure in these w/c phases. High-pressure near-infrared spectroscopy and small-angle neutron scattering measurements of microemulsified water provide evidence for the stabilization of w/c microemulsion droplets. The relative lengths of the two chains were found to influence the favored aggregation structure: for symmetric chain surfactants (F8H8, F7H7) spherical reverse micelles are present, but for asymmetric chain surfactants (F7H4, F8H4) extended cylinder aggregates form. These changes in aggregation are consistent with different surfactant packing parameters owing to the controlled variations in molecular structure. Furthermore, the general order of w/c phase transition pressures (F8H8 < F7H7 and F8H4 < F7H4) is in line with estimations of surfactant fractional free volume, as proposed by Johnston et al. (J. Phys. Chem. B 2004, 108, 1962-1966). Studies of adsorption at the poly(dimethylsiloxane)-water interface are shown to be valuable for assessing the CO2-philicity of new surfactants. All in all, the symmetric F8H8 and F7H7 analogues are seen to be the most efficient compounds from this class for applications in CO2. 相似文献
10.
A two-dimensional random motion of a point is dealt with. The point velocity (v cos ?,v sin ?) is subjected to two different kinds of perturbations, the first represented by a vector of independent standard Wiener processes and the second by a generalized type of Poisson process. The control function is ?, whilev is kept fixed. We assume given a configuration ofn+1 target sets,A 0,...,A n , in the plane, all of these sets being surrounded by an open and bounded setD. We denote by ? x (?(?)∈A i the probability thatX t , the location of the point, whereX 0=x∈D, will reach the setA i beforeX i reaches any other setA j ,i≠j, and before it leavesD. The problem dealt with here is to find an optimal control law ?*, ?*=?*(x),x∈D, such that the function $$V\left( {x;\theta } \right) = \sum\limits_{i = 0}^n {\lambda _i \mathbb{P}_x \left( {X_\tau \left( \theta \right) \in A_i } \right),}$$ where λ1,i=0,...,n, are given nonnegative numbers, will be maximized on a given class of admissible control laws. Sufficient conditions on optimal controls, of a dynamic programming type, are derived. These conditions require the existence of a smooth solution to a nonlinear partial integrodifferential equation, which is solved here by applying a finite-difference scheme. Two examples are dealt with numerically. 相似文献