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1.
Attila Kovács 《International journal of quantum chemistry》2020,120(1):e26051
Lanthanide dinitrogen complexes, Ln(N2) x (x = 1-8), were investigated by Density Functional Theory computations using the B3LYP exchange-correlation functional in conjunction with quasirelativistic pseudopotentials for Ln. After a recent study on the lanthanum complexes (A. Kovács, Structural Chemistry 2018 , 29, 1825), the present study aimed to probe the changes upon variously filled 4f subshells of Ln on the structures, stabilities, and bonding properties in related complexes of Nd, Ho, and Lu. The bonding properties were assessed on the basis of natural atomic charges, Ln valence orbital populations, and analysis of bonding molecular orbitals. 相似文献
2.
András Gy. Németh Renáta Szabó Dr. Attila Domján Prof. György M. Keserű Dr. Péter Ábrányi-Balogh 《ChemistryOpen》2021,10(1):16-27
The development of a new three-component chromatography-free reaction of isocyanides, amines and elemental sulfur allowed us the straightforward synthesis of thioureas in water. Considering a large pool of organic and inorganic bases, we first optimized the preparation of aqueous polysulfide solution from elemental sulfur. Using polysulfide solution, we were able to omit the otherwise mandatory chromatography, and to isolate the crystalline products directly from the reaction mixture by a simple filtration, retaining the sulfur in the solution phase. A wide range of thioureas synthesized in this way confirmed the reasonable substrate and functional group tolerance of our protocol. 相似文献
3.
Leo Liebermann 《Fresenius' Journal of Analytical Chemistry》1883,22(1):232-233
Ohne Zusammenfassung 相似文献
4.
Julien Ferrari Christian Terreaux Tibor Kurtn Attila Szikszai‐Kiss Sndor Antus JeromeD. Msonthi Kurt Hostettmann 《Helvetica chimica acta》2003,86(8):2768-2778
Investigation of the methanol extract of the roots of Gnidia involucrata (Thymelaeaceae) led to the isolation and characterization of two new 3,8″‐biflavonoid diastereoisomers, named GB‐4 ( 6a ) and GB‐4a ( 6b ). Their absolute configurations were determined in mixture by on‐line LC/CD measurements, which also allowed the revision of absolute configurations of the biflavanoids GB‐1 and GB‐2, and the configurational assignment of GB‐3. 相似文献
5.
Stefano De Leo 《International Journal of Theoretical Physics》1996,35(9):1821-1837
We derive an appropriate definition of transpose for quaternionic matrices and give a new panoramic review of the quaternionic groups. We aim to analyze possible quaternionic groups for GUTs. 相似文献
6.
7.
B. Savo P. Romano A. Nigro R. Di Leo 《Physica C: Superconductivity and its Applications》2002,370(4):275-280
The flat voltage noise component of current biased, high-transparency Nb/AlOx/Nb superconducting tunnel junctions has been investigated at frequencies up to 70 kHz. Several aspects of the analyzed phenomena suggest the presence of current noise effects induced by the discreteness of the charge carriers. At subgap voltages, where excess currents occur, a behavior coherent with a multiple Andreev reflection-assisted transport through the tunnel barrier has been found. However, the measured charge values exceed any theoretical prediction. 相似文献
8.
Monica-Gabriela Cojocaru Leo B. Jonker 《Proceedings of the American Mathematical Society》2004,132(1):183-193
We prove existence and uniqueness of integral curves to the (discontinuous) vector field that results when a Lipschitz continuous vector field on a Hilbert space of any dimension is projected on a non-empty, closed and convex subset.
9.
An approach called Schramm–Loewner evolution (SLE) provides a new method for dealing with a wide variety of scale-invariant problems in two dimensions. This approach is based upon an older method called Loewner Evolution (LE), which connects analytic and geometrical constructions in the complex plane. In this paper, the bases of LE and SLE are described and some simple applications are discussed in relatively non-technical form. A bibliography of the subject is presented. 相似文献
10.