N_2和O_2纯转动拉曼光谱(PRRS)的温度特性

计算了N2 和O2 的PRRS ,讨论了其温度特性。提出通过测量N2 和O2 的PRRS计算大气温度的方法。     

TDI三聚体的合成研究

以一种碱金属羧酸盐K-1000作为甲苯二异氰酸酯(TDI)三聚反应的催化剂合成了以TDI三聚体为主要成分的多异氰酸酯固化剂。对合成工艺条件进行了探讨。结果表明,将反应温度控制在35℃,催化剂K-1000用量为0.06%时,用苯甲酰氯作为阻聚剂可得到性能基本稳定的TDI三聚体产品。     

(2-甲基丙烯酰氧乙基)三甲基氯化铵-丙烯酰胺反相微乳液共聚合研究

采用SPAN-OP复合乳化剂和K_2S_2O_8-Na_2SO_3氧化还原引发剂,进行(2-甲基丙烯酰氧乙基)三甲基氯化铵-丙烯酰胺的反相微乳液共聚合。测得单体的竞聚率r_(DM·MC)=1.11±0.16,r_(AM)=0.53±0.08。在单体总浓度为20—40％(wt),引发剂浓度为0.01—0.05％,乳化剂浓度为10—18％,聚合温度为299K的条件下,得到共聚反应动力学方程:R_p=k[M]~(1.07)[I]~(0.52)[E]~(0.90),文中对上述结果做了解释。     

New structural motifs in the aggregation of neutral gold(I) complexes: structures and luminescence from (alkyl isocyanide)AuCN

The preparation and X-ray crystal structures of (CyNC)Au(I)CN, (n-BuNC)Au(I)CN, and (i-PrNC)Au(I)CN.0.5CH(2)Cl(2) are reported and compared with those of (MeNC)Au(I)CN and (t-BuNC)Au(I)CN, which were previously described. These linear molecules are all organized through aurophilic interactions into three structural classes: simple chains ((CyNC)Au(I)CN and (t-BuNC)Au(I)CN), side-by-side chains in which two strands make Au...Au contact with each other ((n-BuNC)Au(I)CN), and nets in which multiple aurophilic interactions produce layers of gold(I) centers ((i-PrNC)Au(I)CN and (MeNC)Au(I)CN). All of these five solids dissolve to produce colorless, nonluminescent solutions with similar UV/vis spectra. However, each of the solids displays a unique luminescence with emission maxima occurring in the range 371-430 nm.     

Living ring-opening metathesis polymerization of norbornenes bay-functionalized perylene diimides

Ring-opening metathesis polymerization (ROMP)-derived poly(oxanorbornene imide)s bearing bay-linked mono - alkoxy -M1 and 1,7-di-alkoxy M2 functionalized perylene diimides (PDIs) were synthesized using Grubb's third ( G3 ) and Hoveyda-Grubbs second generation ( HG2 ) ruthenium-alkylidene metathesis initiators. The mono-alkoxy-derived PDI-based non-ladderphane polymer poly M1 displayed 67% to 77% of the trans olefin content in the polymer chain depending on the initiator used for the polymerization. When using the symmetrical 1,7-di-alkoxy-derived PDI-based polymer poly M2 having the ladderphane type-structure, this displayed a significant amount of cis and trans olefin contents in the polymer chains, irrespective of the type of initiators used for the polymerization. ROMP of both monomers M1 and M2 proceeded in a well-controlled manner with a linear dependence of molecular weight on the monomer/initiator ratio using G3 as initiator. Optical properties of the ladderphane-based poly M2 and non-ladderphane-based poly M1 were characterized in both solution and the film state. X-ray diffraction (XRD) analysis for all the polymers showed significant π-stacking in the thin film state with ordered molecular packing and closer values of d-spacing for both poly M1 and poly M2 . Film morphology examined by AFM elucidated homogenous smooth polymer surface for both polymers in general, but with some irregularities observed for poly M1 . In addition, CV analysis revealed both polymers could be good candidates as electron-accepting materials, with excellent film-forming ability, and thermal stability.     

Nutritional Analysis of Red-Purple and White-Fleshed Pitaya (Hylocereus) Species

Pitaya is one of the most preferred and produced tropical fruit species recently introduced to the Mediterrranean region in Turkey. Due to its nutritional fruits with high economic value, the popularity of pitaya increases steadily in Turkey as an alternative crop. No detailed nutritional analysis has been undertaken in Turkey so far on fruits of the pitaya species. In this study, we determined and compared some nutritional parameters in fruit flesh of two pitaya (dragon fruit) species (Hylocereus polyrhizus: Siyam and Hylocereus undatus: Vietnam Jaina) grown in the Adana province located in the eastern Mediterranean region in Turkey. The individual sugars, antioxidant activity, total phenolic content, phenolic compounds and volatiles were determined for the first time in Turkey on two pitaya species. The results showed that total phenol content and antioxidant capacity are notably higher in red-fleshed fruits than white-fleshed ones and the predominant phenolic compound in fruits of both species was quercetin. The total sugar content and most of the phenolic compounds in fruits of two pitaya species were similar. A total of 51 volatile compounds were detected by using two Solid Phase Micro Extraction (SPME) fibers, coupled with Gas Chromatography Mass Spectrometry (GC-MS) techniques, and more volatile compounds were presented in the white-fleshed species. Total phenolic content (TPC) of the red-fleshed and white-fleshed pitaya species were 16.66 and 17.11 mg GAE/100 g FW (fresh weight). This study provides a first look at the biochemical comparison of red-fleshed and white-fleshed pitaya species introduced and cultivated in Turkey. The results also showed, for the first time, the biochemical content and the potential health benefit of Hylocereus grown in different agroecological conditions, providing important information for pitaya researchers and application perspective.     

二烯丙基二甲基氯化铵—丙烯酰胺反相乳液聚合的动力学特征研究

采用油酸失水山梨醇酯（ＳＰＡＮ）－壬基酚聚氧化乙烯醚（ＯＰ）复合乳化剂与Ｋ２Ｓ２Ｏ８－Ｎａ２ＳＯ３氧化还原引发剂，进行二烯丙基二甲基氯化铵－丙烯酰胺反相乳液共聚合，测得单体的竞聚率为γＤＡＤＭＡＣ＝０．１４±０．１１，γＡＭ＝５．０５±０．６６；在单体浓度为２５─４５％，引发剂浓度０．０６—０．１％，乳化剂浓度为５—９％，聚合温度３０３Ｋ条件下，得到了共聚反应动力学方程：Ｒｐ＝ｋ［Ｍ］０．６８［Ｉ］１．３１［Ｅ］０．７３，文中对上述结果做了解释．     

不确定信息处理及在归纳学习中的应用

信息的不确定性是由于模糊性、随机性、不完全性、不精确性等因素造成的,不确定性信息在现实世界中广泛存在.关于这方面的研究主要集中在模糊性这种不确定性上.我们课题组在此领域的研究已经持续20余年,概括起来讲,早期的研究兴趣在于模糊(非可加)测度与积分的理论建立,主要研究了传统的可加测度与积分理论到非可加情况的推广;尔后的兴趣转向为如何用数值方法确定非可加测度;近期的研究兴趣在于从已有数据中获取模糊控制规则以及具有模糊表示的归纳学习问题.近10年的研究曾得到了多项基金项目资助,出版专著3部,发表学术论文100余篇,30余篇被SCI收录,20余篇被EI收录,省级以上奖励3项.以下是我们近期研究工作的一个总结,主要包括模糊决策树归纳;基于模糊信息的决策表简化;产生模糊规则的扩张矩阵算法;模糊归纳学习在其他领域中的应用;基于示例学习的模糊控制等.     

How Do Cultural Classes Emerge from Assimilation and Distinction? An Extension of the Cucker-Smale Flocking Model

When cultural tastes are not neutral but hierarchically matched to social status, people assimilate themselves to higher status by consuming cultural goods while distinguishing themselves from lower status by developing new tastes. Extending the Cucker-Smale model for mutual influence among agents, we examine when and how many cultural classes emerge from continuous distributions of tastes and what conditions those classes satisfy, through the assimilation-distinction mechanism. We simulate the models with different initial distributions of tastes (uniform, normal, and chi-square), given various ranges of 2 parameters: (a) the strength and (b) the range of distinction relative to assimilation. Tastes are flocking and cultural classes emerge when the range of assimilation is much larger than that of distinction. The number of classes increases with the strength of distinction, whereas the distance between classes equals the range of distinction. Some properties of emergent classes are mathematically proved. First, in a two-class system, the stronger distinction, the larger the upper class. Second, in a three-class system, the middle class is necessarily larger than the lower class and likely larger than the upper class. Third, a 3-class system cannot emerge if distinction is weaker than assimilation. These properties are universal and do not depend on the initial distribution of cultural tastes. This independence predicts homogeneous cultural classes emerging across different social conditions. Also, the cultural middle class as the largest group may explain why subjective class consciousness is often higher than objective position. Unless assimilating efforts can reach an infinite range, there emerges a cultural outcast at the lowest end of the cultural hierarchy.     

中国紫胶树脂基本组成的研究

定量测定了紫胶树脂基本成分的含量；分离得到了紫胶树脂 状脂肪酸和环状萜烯酸的代表物－－紫胶桐酸和壳脑酸。研究发现国产紫胶中软树脂含量高于印度紫胶。结果证明国产紫胶与印度胶在组成和树脂分子构成方面基本一致。