全文获取类型
收费全文 | 282篇 |
免费 | 17篇 |
国内免费 | 7篇 |
专业分类
化学 | 113篇 |
晶体学 | 1篇 |
力学 | 1篇 |
数学 | 140篇 |
物理学 | 51篇 |
出版年
2022年 | 7篇 |
2021年 | 3篇 |
2020年 | 5篇 |
2019年 | 5篇 |
2018年 | 10篇 |
2017年 | 3篇 |
2016年 | 6篇 |
2015年 | 15篇 |
2014年 | 10篇 |
2013年 | 17篇 |
2012年 | 13篇 |
2011年 | 22篇 |
2010年 | 16篇 |
2009年 | 13篇 |
2008年 | 20篇 |
2007年 | 12篇 |
2006年 | 15篇 |
2005年 | 13篇 |
2004年 | 9篇 |
2003年 | 2篇 |
2002年 | 6篇 |
2001年 | 4篇 |
2000年 | 4篇 |
1998年 | 4篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 6篇 |
1994年 | 1篇 |
1993年 | 5篇 |
1992年 | 5篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 6篇 |
1984年 | 6篇 |
1983年 | 4篇 |
1981年 | 3篇 |
1980年 | 6篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 5篇 |
1976年 | 2篇 |
1974年 | 2篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1940年 | 2篇 |
1929年 | 1篇 |
排序方式: 共有306条查询结果,搜索用时 31 毫秒
1.
Cover Picture: Coordination Chemistry of N‐Heterocyclic Nitrenium‐Based Ligands (Chem. Eur. J. 19/2015)
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
2.
Single bacterial cells, each expressing a different library variant, were compartmentalized in aqueous droplets of water-in-oil (w/o) emulsions, thus maintaining a linkage between a plasmid-borne gene, the encoded enzyme variant, and the fluorescent product this enzyme may generate. Conversion into a double, water-in-oil-in-water (w/o/w) emulsion enabled the sorting of these compartments by FACS, as well as the isolation of living bacteria cells and their enzyme-coding genes. We demonstrate the directed evolution of new enzyme variants by screening >10(7) serum paraoxonase (PON1) mutants, to yield 100-fold improvements in thiolactonase activity. In vitro compartmentalization (IVC) of single cells, each carrying >10(4) enzyme molecules, in a volume of <10 femtoliter (fl), enabled detection and selection despite the fast, spontaneous hydrolysis of the substrate, the very low initial thiolactonase activity of PON1, and the use of difusable fluorescent products. 相似文献
3.
Shaul M. Aharoni 《先进技术聚合物》1995,6(6):373-382
The preparation of rigid aromatic, highly branched polyamides is described. Owing to the method of preparation and the chosen ratio of difunctional to trifunctional monomers, these entities are highly porous and not dendrimeric in nature. They better conform with the fractal model and are therefore called fractal polyamides (FPs). The effects of variations in the polymerization procedure, in total monomer concentration, in the ratio of amine to carboxyl groups and in the duration of the polycondensation reaction are investigated. Some characterization was performed and the results are presented and briefly discussed. 相似文献
4.
Ahmed M. Assaf 《组合设计杂志》1993,1(6):453-458
A (v, k. λ) covering design of order v, block size k, and index λ is a collection of k-element subsets, called blocks, of a set V such that every 2-subset of V occurs in at least λ blocks. The covering problem is to determine the minimum number of blocks, α(v, k, λ), in a covering design. It is well known that $ \alpha \left({\nu,\kappa,\lambda } \right) \ge \left\lceil {\frac{\nu}{\kappa}\left\lceil {\frac{{\nu - 1}}{{\kappa - 1}}\lambda} \right\rceil} \right\rceil = \phi \left({\nu,\kappa,\lambda} \right) $, where [χ] is the smallest integer satisfying χ ≤ χ. It is shown here that α (v, 5, λ) = ?(v, 5, λ) + ? where λ ≡ 0 (mod 4) and e= 1 if λ (v?1)≡ 0(mod 4) and λv (v?1)/4 ≡ ?1 (mod 5) and e= 0 otherwise With the possible exception of (v,λ) = (28, 4). © 1993 John Wiley & Sons, Inc. 相似文献
5.
6.
Shaul M. Aharoni Morton H. Litt 《Journal of polymer science. Part A, Polymer chemistry》1974,12(3):639-650
A polymer, poly(2,5-trimethylene benzimidazole), the first of a new family of nonsymmetrical polymers, was synthesized via an eight-step synthetic route. The polymer, obtained by melt polymerization, is amorphous and in its neutral form behaves as a moderate insulator. It forms 1 : 1 HCl adducts. When cast from formic acid solution, it forms 1 : 1 formic acid adducts. The acid adducts are semiconductors with resistivities in the 106–108 ohm-cm range. Space-charge effects are generated in the adducts as carrier mobility rises. 相似文献
7.
Shaul M. Aharoni Willis B. Hammond John S. Szobota Divakar Masilamani 《Journal of polymer science. Part A, Polymer chemistry》1984,22(10):2579-2599
Polyamides and related model compounds were prepared from carboxy acids and primary amines by reacting them with triphenylphosphite in an appropriate solvent at 100°C. The reactions proceeded in the absence of organic base but were accelerated by the addition of bases such as pyridine. Nevertheless, even the powerful combination of 13C and 31P NMR failed to indicate the presence of pyridinium phosphite in the reaction mixture. In the reaction of a primary amine and carboxyl groups a detectable amount of the diphenoxy aminophosphine intermediate was observed. The end products are the amides, phenol, and diphenyl phosphite. When primary amine was not present a slow formation of a phenyl ester of the carboxylic acid was evident. All the intermediate species and the end products were formed with or without added pyridine. A mixed anhydride of carboxylic acid and phosphite was never seen. The results in this article are fundamentally the same as those in the companion article (I) for which the data were obtained at 280°C in the absence of solvent and base. However, because the reaction went quickly to completion at 280°C, the diphenoxy aminophosphine intermediate was not observed. A mechanism for the amidation in which the diphenoxy aminophosphine is an initial reaction intermediate is proposed. This species reacts with the carboxylic acid through an intramolecular substitution to give an amide. This mechanism may be valid for the high-temperature reactions as well. Several minor unclear points are indicated. 相似文献
8.
9.
Assaf Rinot 《Mathematical Logic Quarterly》2019,65(2):200-204
We present a weak sufficient condition for the existence of Souslin trees at successor of regular cardinals. The result is optimal and simultaneously improves an old theorem of Gregory and a more recent theorem of the author. 相似文献
10.
Marianna Zaretsky Revital Etzyoni Joel Kaye Liora Sklair-Tavron Amir Aharoni 《Chemistry & biology》2013,20(2):202-211
- Download : Download high-res image (276KB)
- Download : Download full-size image