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1.
In this study, 1,3-disulfonic acid imidazolium hydrogen sulfate (DSIMHS) is used as an efficient and reusable ionic liquid for the green, mild, and efficient synthesis of xanthenes under solvent-free conditions. Simple and easy work-up, low cost, green process, short reaction times and excellent yields of the products are the advantages of this procedure. Further, the catalyst can be recycled and reused at least for four times without a noticeably decrease in its catalytic activity. 相似文献
2.
Sheykhi-Estalkhjani Ammar Mahmoodi Nosrat O. Yahyazadeh Asieh Pasandideh Nadamani Meysam 《Research on Chemical Intermediates》2020,46(8):3835-3852
Research on Chemical Intermediates - Some new DAMN-based Schiff base 6a–6g were synthesized via a condensation reaction of the corresponding azo dyes with... 相似文献
3.
A variety of β-hydroxyphosphonates were produced in high yields by ring opening reaction of different types of epoxides with di/trialkyl phosphite esters catalyzed by Al(OTf)3. The reactions proceeded with complete chemo- and regioselectivity to give the title compounds. This method is new, simple and efficient for the one-pot synthesis of β-hydroxyphosphonates via direct C-P bond formation. 相似文献
4.
Mohammad Kazem Rofouei Asieh Ahmadalinezhad Mehdi Taghdiri 《Journal of inclusion phenomena and macrocyclic chemistry》2007,58(3-4):377-382
The interaction of 1,13-bis(8-quinolyl)-1,4,7,10,13-pentaoxatridecane (Kryptofix5) with alkali-metal cations (Li+, Na+, K+) in aprotic medium (acetonitrile) has been investigated. Conductance measurements demonstrated that 1:1 metal cation:ligand
stoichiometries are found with these cations in this solvent. 7Li and 23Na NMR experiments were carried out by titration of the metal cation solutions with Kryptofix5 solution in CD3CN + CH3CN at 298 K. Thermodynamic parameters of complexation for this ligand and alkali-metal cations in acetonitrile at 278–308 K
were derived from titration conductometry. The highest stability is found for sodium complex. The complexation sequence, based
on the value of log K at 278–308 K was found to be Na+ > K+ > Li+. 相似文献
5.
A series of novel azo disperse dyes were synthesized by coupling reaction of 4-benzyloxyphenol with diazotized p-substituted aniline derivatives as diazo components.These compounds were characterized by spectroscopic techniques and elemental analysis. Ionization constants,pK_a,for these dyes were determined using electronic spectroscopic method. 相似文献
6.
An Expedient Synthesis of Novel Derivatives of Pyrido[2,3‐d]pyrimidines Using Magnetically Supported ZrO2 Nanocatalyst
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Leila Kheirkhah Manouchehr Mamaghani Nosrat Ollah Mahmoodi Asieh Yahyazadeh Abdollah Fallah Shojaei Yaseman Rostamli 《中国化学会会志》2016,63(5):410-416
An efficient synthesis of pyrido[2,3‐d]pyrimidine derivatives via one‐pot multicomponent reactions of 6‐amino‐2‐(alkylthio)pyrimidin‐4(3H)‐one, 3‐cyanoacetylindole and arylaldehydes using [Fe3O4@ZrO2] as magnetically recyclable nanocatalyst is reported. This protocol furnished the desired products in good to excellent yields (70–93 %) and lower reaction times. The catalyst could be easily and efficiently separated from the final product solution by an external magnet and be reused in 5 consecutive runs without any significant activity decrease. 相似文献
7.
Basic Ionic Liquid as Catalyst and Reaction Media for the One‐pot Three‐component Regioselective Synthesis of Various Thiazol‐2‐imine Derivatives
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Jafar Abbasi Shiran Asieh Yahyazadeh Bohari M. Yamin Manouchehr Mamaghani Jalal Albadi 《Journal of heterocyclic chemistry》2016,53(4):1009-1016
Thiazol‐2‐imine derivatives were synthesized in an easy and efficient route from the regioselective one‐pot three‐component reaction of aryl amine, alkylisothiocyanate, and various α‐haloketones in [omim][OH] basic ionic liquid. Recyclable reaction media, catalyst free, and short reaction times are the main advantages of this protocol. This method produces the products at room temperature in excellent yields (68–96%). Furthermore, the target compound 6b was determined by X‐ray crystallographic analysis. 相似文献
8.
Ammar Sheykhi-Estalkhjani Nosrat O. Mahmoodi Asieh Yahyazadeh Meysam Pasandideh Nadamani Hossein Taherpour Nahzomi 《Tetrahedron》2019,75(6):749-756
A facile two-directional synthesis of new pyrimido[5,4-d]pyrimidine-2,8-dione was reported via an efficient reaction of premade bis-aldehydes and 1-(2-amino-1,2-dicyanovinyl)-3-phenylurea in the presence of triethylamine as the base and Cu (II) as catalyst. As there is controversy about the formation of two types of products, that is, purine or pyrimidine ring containing compounds in the reaction of diaminomaleonitrile with isocyanates and aldehydes, the computational model chemistry has been employed to obtain new insight about this reaction and determining the dominant pathway of the process. Using DFT model, two alternative pathways have been explored and geometrical isomerization of central double bond has been considered. Accordingly, the evaluated energy barriers affirm the formation of six-membered pyrimidine ring as the major product in the presence of CuCl2 as the catalyst and MeOH as solvent. 相似文献
9.
The first ultrasound-promoted multicomponent synthesis of pyridazinones and phthalazinones from arenes, cyclic anhydrides and ArNHNH2 in the presence of an efficient recyclable catalyst, [bmim]Br/AlCl3, in high yield and short reaction time is reported. 相似文献
10.
We develop a stability and convergence theory for a Discontinuous Galerkin formulation (DG) of a highly indefinite Helmholtz problem in . We prove that the DG-method admits a unique solution under much weaker conditions than for conventional Galerkin methods. It is shown that for the case of hp-DGFEM the optimal convergence order estimate can be obtained under the conditions that is sufficiently small and the polynomial degree p is at least O(log k). (© 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献