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1.
The angular variations of the five-fold differential cross section obtained by using different wave functions of helium are
compared with experimental data. It is found that in the coplanar geometry two kinematical arrangements, (i) equal energy
sharing between the two ejected electrons with one of them ejected along the momentum transfer direction and the other along
varying direction and (ii) the Bethe ridge condition with fixed sum of ejected electron energies and varying angle between
them, are very sensitive to e-e correlations contained in the target wave function. This comparison has been used to show
that open-shell class of wave functions better incorporate e-e correlations than the closed-shell class. 相似文献
2.
In this paper, nonlinear systems having multiple equilibrium points and low order dynamics are investigated. Roll motions of ships are studied by means of modern nonlinear techniques to exemplify the behavior of such nonlinear systems in the case when they are under the influence of external sinusoidal disturbances with unknown amplitudes. The main objective is to analyze the performance of this system at different operating conditions, including those giving rise to chaos, and to design a controller with an overparameterized structure to stabilize the system at the origin. A nonlinear recursive backstepping controller is proposed and the transient performance is investigated. Lyapunov-based techniques are used to force systematic following of a reference model while introducing a nonlinear parameter estimator to guarantee adaptivity. Robustness problems as well as ways to tune the controller parameters are examined. Simulation results are submitted for the uncontrolled and controlled cases, verifying the effectiveness of the proposed controller. Finally, a discussion and conclusions are given with possible future extensions. 相似文献
3.
Let R be a ring and d : R → R a derivation of R. In the present paper we investigate commutativity of R satisfying any one of the properties (i)d([x,y]) = [x,y], (ii)d(x o y) = xoy, (iii)d(x) o d(y) = 0, or (iv)d(x) o d(y) = x o y, for all x, y in some apropriate subset of R. 相似文献
4.
Hung‐Chuan Cheng Li‐Tang Wang Ashraf Taha Khalil Yao‐To Chang Yu‐Chi Lin Ya‐Ching Shen 《中国化学会会志》2004,51(2):431-435
Phytochemical investigation of the stem bark of Calophyllum inophyllum resulted in the isolation of a new dipyrenoxanthone, calophinone ( 1 ), together with four related xanthones ( 2–5 ). Identification of the isolated compounds was achieved through intensive studies of their spectral data, especially 2D NMR. 相似文献
5.
Nizakat Bib Misal Khan Amal Badshah Muhammad Ashraf Chaudry 《Radiation Physics and Chemistry》2005,73(6):362-364
Minimally processed cauliflower samples were irradiated, stored at 5 °C for 2 weeks and analyzed for sensory, physicochemical and microbiological qualities at 0th, 7th and 14th days. The data showed highest mean values of 7.93 and 7.57 for appearance and flavor, respectively, for 1.0 kGy treated samples. The D10 values of contaminating microorganisms on cauliflower were 0.20 (Escherischia coli) and 0.24 kGy (Salmonella paratyphae A.) and the resulting 5D10 value was 1.2 kGy. The study revealed that a dose of 1.5 kGy is enough for retention of quality and reduction of microbial load to 5D10 values in cauliflower during 2 weeks storage at refrigerated temperature. 相似文献
6.
Phytochemical investigation of the methanol extract of Euchresta formosana resulted in the isolation of thirty-four compounds. Compounds 1, 3-12, 15, 27, 29 and 32-24 were isolated from this species for the first time. These compounds were identified by spectral analyses and tested for antiplatelet aggregation and anti-HIV activities. Among these compounds, tectorigenin (1), 3',4',5-trihydroxyisoflavone (3), and euchretin F (19) were the most effective antiplatelet aggregation compounds; they inhibited both AA- (arachidonic acid) and collagen-induced platelet aggregation. Meanwhile, flemiphyllin (B), quercetin (13), euchretin M (23), and formosanatin C (26) inhibited HIV replication in H9 lymphocyte cells. 相似文献
7.
Summary An intense fluorescence,5D7F, of the europium(III) ion was observed at room temperature in DMSO and DMF solutions of the europium(III) chelate with salicylidene-valinate Schiff base, as a result of an intramolecular energy-transfer from the ligand to the metal ion. The metal chelate has been characterized and appears to possess an octahedral configuration. These results offer an interesting opportunity to probe the active sites of pyridoxal enzymes. 相似文献
8.
A new series of CoII, NiII and CuII complexes derived from N-picolinamido-N-benzoylthiocarbamide has been prepared in which the Schiff base ligand is tridentate and/or bidentate, containing a potential ONS donor. The complexes have been characterized by elemental analyses, 1H-n.m.r., magnetic susceptibility, i.r., u.v., e.p.r. and thermal analyses. Stereochemistries are proposed for the complexes on the basis of the spectral and magnetic studies. The i.r. data indicate that the carbonyl oxygen of the benzoyl moiety constituents chelating backbone in most complexes. 相似文献
9.
Ya‐Ching Shen Yun‐Sheng Lin Shaw‐Man Hsu Ashraf Taha Khalil Shih‐Sheng Wang Ching‐Te Chien Yao‐Haur Kuo Chang‐Hung Chou 《Helvetica chimica acta》2007,90(7):1319-1329
The phytochemical investigation of the more polar fractions from the leaves and twigs of Taxus sumatrana (Taxaceae) afforded five new taxane diterpene esters, tasumatrols P–T ( 1 – 5 ) possessing an 11(15→1),11(10→9)‐diabeotaxane skeleton. Compounds 1, 4 , and 5 contain an α‐hydroxy group at C(14), while 3 has no OH group at either C(13) or C(14). Compound 2 is a natural 4,5‐acetonide derivative, while 4 has an unusual spiro‐connected 2‐hydroxy‐2‐phenyl‐1,3‐dioxolane ring. Ten known taxoids, were also isolated in the course of the chromatographic fractionation. Five additional new O‐acetyl derivatives 3a, 4a, 4b, 5a , and 5b were prepared from the taxanes 3 – 5 . The structures of all new compounds were established on the basis of their spectroscopic analyses. Compound 1 showed mild cytotoxic activity against human Hela and Daoy tumor cells. 相似文献
10.