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1.
Loredana Protesescu Joaquín Calbo Kristopher Williams William Tisdale Aron Walsh Mircea Dinc 《Chemical science》2021,12(17):6129
The development of synthetic routes to access stable, ultra-small (i.e. <5 nm) lead halide perovskite (LHP) quantum dots (QDs) is of fundamental and technological interest. The considerable challenges include the high solubility of the ionic LHPs in polar solvents and aggregation to form larger particles. Here, we demonstrate a simple and effective host–guest strategy for preparing ultra-small lead bromide perovskite QDs through the use of nano-sized MOFs that function as nucleating and host sites. Cr3O(OH)(H2O)2(terephthalate)3 (Cr-MIL-101), made of large mesopore-sized pseudo-spherical cages, allows fast and efficient diffusion of perovskite precursors within its pores, and promotes the formation of stable, ∼3 nm-wide lead bromide perovskite QDs. CsPbBr3, MAPbBr3 (MA+ = methylammonium), and (FA)PbBr3 (FA+ = formamidinium) QDs exhibit significantly blue-shifted emission maxima at 440 nm, 446 nm, and 450 nm, respectively, as expected for strongly confined perovskite QDs. Optical characterization and composite modelling confirm that the APbBr3 (A = Cs, MA, FA) QDs owe their stability within the MIL-101 nanocrystals to both short- and long-range interfacial interactions with the MOF pore walls.We demonstrate a simple and effective host–guest strategy for preparing ultra-small lead bromide perovskite QDs through the use of nano-sized MOFs that function as nucleating and host sites. 相似文献
2.
Two methods for implementing angular momentum decoupling approximations in quantum mechanical reactive scattering examined. Applications of both reactive and nonreactive H + H2 collisions indicate that for the most intense individual reactive transitions and for all degeneracy-averaged ones, these decoupling methods (especially the “proper” decoupling method) yield results in good agreement with those of fully-coupled calculations. However, for the less intense reactive transitions and all individual nonreactive transitions, very large errors can result from use of these approximate methods. 相似文献
3.
A time-independent coupled-channel method, using hyperspherical coordinates, has been developed for calculating quantum mechanical collision-induced dissociation probabilities for collinear atom-diatom systems in which the exchange reaction can also occur. The results for a model potential energy surface are compared with quasi-classical trajectory calculations and discussed. 相似文献
4.
R. M. Aron P. Galindo D. Garcí a M. Maestre 《Transactions of the American Mathematical Society》1996,348(2):543-559
A Banach space is known to be Arens regular if every continuous linear mapping from to is weakly compact. Let be an open subset of , and let denote the algebra of analytic functions on which are bounded on bounded subsets of lying at a positive distance from the boundary of We endow with the usual Fréchet topology. denotes the set of continuous homomorphisms . We study the relation between the Arens regularity of the space and the structure of .
5.
Behforouz M Haddad J Cai W Arnold MB Mohammadi F Sousa AC Horn MA 《The Journal of organic chemistry》1996,61(19):6552-6555
The novel 7-(N-formyl-, 7-(N-acetyl-, and 7-(N-isobutyrylamino)-2-methylquinoline-5,8-diones were synthesized in excellent overall yields in three steps via the nitration of the commercially available 8-hydroxy-2-methylquinoline followed by a reduction-acylation step and then oxidation. Acid hydrolysis of 7-(N-acetylamino)-2-methylquinoline-5,8-dione (14a) afforded the novel 7-aminoquinoline-5,8-dione 7 in excellent yields. Due to our efficient preparation of dione 14a, we now report a short and practical method for the total synthesis of the potent antitumor agent lavendamycin methyl ester (1b) with an excellent overall yield. 相似文献
6.
Calculations of quantum mechanical probabilities and rate constants for the collinear reaction Br + HCl(ν = 2,3,4) → BrH + Cl, Br + HCl(ν < ν) were performed using hyperspherical coordinates. Removal of vibrationally excited HCl proceeds mainly by reaction to a nearly degenerate HBr state. Processes for which a large change in the internal enery occurs have low probabilities. 相似文献
7.
In this paper we extend our density-functional theory calculations, with generalized gradient approximation and hybrid functionals, using Slater-type orbitals (STOs), to the determination of second-order molecular properties. The key to the entire methodology involves the fitting of all STO basis function products to an auxiliary STO basis, through the minimization of electron-repulsion integrals. The selected properties are (i) dipole polarizabilities, (ii) nuclear magnetic shielding constants, and (iii) nuclear spin-spin coupling constants. In all cases the one-electron integrals involving STOs were evaluated by quadrature. The implementation for (ii) involved some complexity because we used gauge-including atomic orbitals. The presence of two-electron integrals on the right-hand side of the coupled equations meant that the fitting procedure had to be implemented. For (iii) in the hybrid case, fitting procedures were again required for the exchange contributions. For each property we studied a number of small molecules. We first obtained an estimate of the basis set limit using Gaussian-type orbitals (GTOs). We then showed how it is possible to reproduce these values using a STO basis set. For (ii) a regular TZ2P quality STO basis was adequate; for (i) the addition of one set of diffuse functions (determined by Slater's rules) gave the required accuracy; for (iii) it was necessary to add a set of 1s functions, including one very tight function, to give the desired result. In summary, we show that it is possible to predict second-order molecular properties using STO basis sets with an accuracy comparable with large GTO basis sets. We did not encounter any major difficulties with either the selection of the bases or the implementation of the procedures. Although the energy code (especially in the hybrid case) may not be competitive with a regular GTO code, for properties we find that STOs are more attractive. 相似文献
8.
Dr. Aron J. Huckaba Dr. Aswani Yella Dr. Louis E. McNamara April E. Steen J. Scott Murphy Casey A. Carpenter George D. Puneky Prof. Nathan I. Hammer Prof. Mohammad Khaja Nazeeruddin Prof. Michael Grätzel Prof. Jared H. Delcamp 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(43):15536-15542
Desirable components for dye‐sensitzed solar cell (DSC) sensitizers and fluorescent imaging dyes include strong donating building blocks coupled with well‐balanced acceptor functionalities for absorption beyond the visible range. We have evaluated the effects of increasing acceptor strengths and incorporation of dye morphology controlling groups on molar absorptivity and absorption breadth with indolizine donor‐based dyes. Indolizine‐based D –A and D –π–A sensitizers incorporating bis‐rhodanine, tricyanofuran (TCF), and cyanoacrylic acid functionalities were analyzed for performance in DSC devices. The TCF derivatives were also evaluated as near‐infrared (NIR)‐emissive materials with the AH25 emissions extending past 1000 nm. 相似文献
9.
The lowest-energy state of a macroscopic system in which symmetry is spontaneously broken, is a very stable wavepacket centered around a spontaneously chosen, classical direction in symmetry space. However, for a Heisenberg ferromagnet the quantum groundstate is exactly the classical groundstate, there are no quantum fluctuations. This coincides with seven exceptional properties of the ferromagnet, including spontaneous time-reversal symmetry breaking, a reduced number of Nambu–Goldstone modes and the absence of a thin spectrum (Anderson tower of states). Recent discoveries of other non-relativistic systems with fewer Nambu–Goldstone modes suggest these specialties apply there as well. I establish precise criteria for the absence of quantum fluctuations and all the other features. In particular, it is not sufficient that the order parameter operator commutes with the Hamiltonian. It leads to a measurably larger coherence time of superpositions in small but macroscopic systems. 相似文献
10.
Gate-modulated low-temperature Raman spectra reveal that the electric field effect (EFE), pervasive in contemporary electronics, has marked impacts on long-wavelength optical phonons of graphene. The EFE in this two-dimensional honeycomb lattice of carbon atoms creates large density modulations of carriers with linear dispersion (known as Dirac fermions). Our EFE Raman spectra display the interactions of lattice vibrations with these unusual carriers. The changes of phonon frequency and linewidth demonstrate optically the particle-hole symmetry about the charge-neutral Dirac point. The linear dependence of the phonon frequency on the EFE-modulated Fermi energy is explained as the electron-phonon coupling of massless Dirac fermions. 相似文献