Etude par spectrométrie de masse de la fragmentation des cyclopentane-triols-1,2,3, des cyclopentane-tétrols et des cyclopentane-pentols

The mass spectra of the three cyclopentane-1,2,3-triols, six cyclopentane-tetrols and four cyclopentane-pentols stereoisomers have been studied. Complex processes, especially regarding the H₂O eliminations, were detected by extensive deuterium labelling.     

ETUDE DE LA FRAGMENTATION DE N-ARYL ET DE N-ALKYL AMINOCETONES EN SPECTROMETRIE DE MASSE

A Comparison of the chemical ionisation and elctron-impact mass spectra of alkyl and aryl aminoketones has bee carried out. This has revealed the particular stabilization of the N-aryl grops in all cases.     

Acetylenic and diacetylenic liquid-crystalline monomers: towards ordered conjugated polymers

Abstract

Acetylenic and diacetylenic mesomorphic monomers have been prepared in order to obtain long conjugated polymers able to give high non-linear optical hyperpolarizabilities. Here we report the synthesis of such monomers incorporating cholesteryl and methoxybiphenyl groups; their structural and thermal behaviour are described. The occurrence of mesophases in the acetylenic and diacetylenic derivatives is discussed as a function of the spacer length and of the size of the mesogen moiety. The diacetylenic derivatives containing the methoxybiphenyl groups do not exhibit any liquid-crystalline behaviour but are able to polymerize under U.V. radiation.     

How to improve transmissive optics in the very far infrared?

Conclusion We have presented the possibility to make optical coatings on quartz in the FIR and we have got a transmission coefficient as high as 97% at room temperature. It will rise probably close to 100% at liquid helium temperature where the quartz two-phonon difference processes are frozen. The use of polyethylene or TPX is also possible to make plates and lenses. The reflectivity losses are smaller because the refractive index is much smaller, but they cannot be further reduced by any coating because there is no transparent material with n1.2 in the FIR. These lenses are very useful in the FIR (except around 60 cm^–1 if they are made of polyethylene). TPX is quite transparent over the whole FIR range, and also in the visible with nearly the same refractive index as in the FIR. Alignments can be made with visible light, and still work in the FIR.     

Frequency spectra of CFC metals and correlated spectral density between bulk atoms

The Green's function generating coefficients method is applied to the calculation of frequency spectra and correlated spectral density for bulk atoms of copper and platinum. The mean square and mean correlated displacements are then deduced. The method is certainly a powerful tool allowing precise calculation of all quantities related to vibrational properties of solids.     

A Quasi-Newton Penalty Barrier Method for Convex Minimization Problems

We describe an infeasible interior point algorithm for convex minimization problems. The method uses quasi-Newton techniques for approximating the second derivatives and providing superlinear convergence. We propose a new feasibility control of the iterates by introducing shift variables and by penalizing them in the barrier problem. We prove global convergence under standard conditions on the problem data, without any assumption on the behavior of the algorithm.     

Photocatalytic properties of Ta-doped TiO2

Ionics - This work reports the effect of tantalum (0.1–1 at.% Ta) on the photocatalytic performance of TiO2 annealed at 1373 and 1673 K in air. It was shown that addition of...     

Anomalous Geomagnetic Signal Emphasized before the Mw8.2 Coastal Alaska Earthquake,Occurred on 29 July 2021

A very strong earthquake of magnitude Mw8.2 struck the coastal zone of Alaska (USA), on 29 July 2021. This earthquake was felt around the Gulf of Alaska, on a wide offshore area belonging to USA and Canada. In order to identify an anomalous geomagnetic signal before the onset of this earthquake, we retrospectively analyze the data collected on the interval 17 June–31 July 2021, via internet, at the two geomagnetic observatories, College (CMO)—Alaska and Newport (NEW)—USA, by using the polarization parameter (BPOL) and the strain effect related to geomagnetic signal identification. Thus, for both observation sites (CMO and NEW), the daily mean distribution of the BPOL and its standard deviation (STDEV) are carried out using an FFT band-pass filtering in the ULF range (0.001–0.0083 Hz). Further on, a statistical analysis based on a standardized random variable equation is applied to emphasize the following: (a) the anomalous signature related to Mw8.2 earthquake on the both time series BPOL*(CMO) and BPOL*(NEW); (b) the differentiation of the transient local anomalies associated with Mw8.2 earthquake from the internal and external parts of the geomagnetic field, taking the NEW observatory as reference. Finally, on the BPOL*(NEW-CMO) time series, carried out on the interval 7–31 July 2021, a very clear anomaly of maximum, greater than 1.2 STDEV, was detected on 22 July, with 7 days before the onset of the Mw8.2 earthquake.     

The number of elliptic curves over ℚ with conductorNwith conductorN

We prove that the number of elliptic curves E/ℚ with conductorN isO(N ^1/2+ε). More generally, we prove that the number of elliptic curves E/ℚ with good reduction outsideS isO(M ^1/2+ε), whereM is the product of the primes inS. Assuming various standard conjectures, we show that this bound can be improved toO(M ^c/loglogM ). Research partially supported by NSF DMS-9424642.