Study by ESI‐FTICRMS and ESI‐FTICRMSn of zinc and cadmium thiophenolate complexes used as precursors for the synthesis of II–VI nanosemiconductors

[M₄(SC₆H₅)₁₀][(CH₃)N]₂, [M₁₀L₄(SC₆H₅)₁₆][(CH₃)N]₄ and [Cd₁₇S₄(SC₆H₅)₂₈][(CH₃)N]₂(M = Cd or Zn, and L = S or Se) zinc and cadmium thiophenolates have been studied by electrospray ionization (ESI) Fourier transform ion cyclotron resonance (FTICR) mass spectrometry (ESI‐FTICRMS) and tandem ESI‐FTICRMS (ESI‐FTICRMSⁿ). ESI‐FTICRMS demonstrated its ability to characterize and study such compounds, which may be used as precursors of II–VI nanomaterials. The obtained mass spectrum has been found to be highly relevant of the investigated thiophenolate and the fragmentation behavior of some of the detected ions is indicative of its stability. More specifically, it has been demonstrated that ESI in‐source activation or fragmentation experiments conducted in the Fourier transform ion cyclotron resonance mass spectrometry (FTICRMS) cell induced the formation of a very stable entity, which corresponds to the general formula M₄L₄ (M = Zn or Cd and L = S or Se). The elimination of SC₆H₅^? and/or M(SC₆H₅)₂ moieties by various activation processes from the studied thiophenolates led systematically to this structure. Copyright © 2009 John Wiley & Sons, Ltd.     

Integrodifferential equations with applications to a plate equation with memory

In this paper we study local existence, uniqueness, and continuous dependence of an abstract integrodifferential equation. We also present a result on unique continuation and a blow‐up alternative for mild solutions of the integrodifferential equation. Finally, we apply our results to an interesting strongly damped plate equation with memory.     

Novel methods for the synthesis of 1,5,2-diazaphosphinines as potential inhibitors of HCV polymerase

Two new methods for the preparation of 1,5,2-diazaphosphinines are described. The first approach involves the reaction between an amidine and an alkynylphosphonate in basic media. The second route involves the reaction between an amidine and a dithioketene acetal phosphonate in basic media. The 1,5,2-diazaphosphinines targets were synthesised for a HCV polymerase inhibitor program.     

Belief and probability: A general theory of probability cores

This paper considers varieties of probabilism capable of distilling paradox-free qualitative doxastic notions (e.g., full belief, expectation, and plain belief) from a notion of probability taken as a primitive. We show that core systems, collections of nested propositions expressible in the underlying algebra, can play a crucial role in these derivations. We demonstrate how the notion of a probability core can be naturally generalized to high probability, giving rise to what we call a high probability core, a notion that when formulated in terms of classical monadic probability coincides with the notion of stability proposed by Hannes Leitgeb [32]. Our work continues by one of us in collaboration with Rohit Parikh [7]. In turn, the latter work was inspired by the seminal work of Bas van Fraassen [46]. We argue that the adoption of dyadic probability as a primitive (as articulated by van Fraassen [46]) admits a smoother connection with the standard theory of probability cores as well as a better model in which to situate doxastic notions like full belief. We also illustrate how the basic structure underlying a system of cores naturally leads to alternative probabilistic acceptance rules, like the so-called ratio rule initially proposed by Isaac Levi [34].Core systems in their various guises are ubiquitous in many areas of formal epistemology (e.g., belief revision, the semantics of conditionals, modal logic, etc.). We argue that core systems can also play a natural and important role in Bayesian epistemology and decision theory. In fact, the final part of the article shows that probabilistic core systems are naturally derivable from basic decision-theoretic axioms which incorporate only qualitative aspects of core systems; that the qualitative aspects of core systems alone can be naturally integrated in the articulation of coherence of primitive conditional probability; and that the guiding idea behind the primary qualitative features of a core system gives rise to the formulation of lexicographic decision rules.