A spectroscopic study of cobalt(III) furyldioximates

Summary The electronic properties of a series of cobalt(III)trans-furyldioximato-complexes of the type [CoB(FH)₂X] (B=NH₃, X=Cl, Br, I or NO₂; B=pyridine (py) or thiocarbamide (thio), X=Cl or Br; B=imidazole (imid), X=Br), [Co(FH₂)(FH)Cl₂] and [Co(thio)₂(FH)₂]NO₃ were studied by i.r., u.v. and¹H and¹³C n.m.r. spectra The results were compared with those from the corresponding dimethylglyoximato-complexes. It was concluded that -conjugation over the equatorial plane in the furyldioximates is greater than in the dimethylglyoximates. There is some evidence of thetrans-influence of the anionic ligands in the ammines which are in the order NO ₂ ^– >Br^–>Cl^–.     

Crystal structure of an NPNA-repeat motif from the circumsporozoite protein of the malaria parasite Plasmodium falciparum

A crystal structure is reported of the peptide Ac-Ala-Asn-Pro-Asn-Ala-NH2, representing the immunodominant region of the major surface protein on the malaria parasite; the NPNA motif adopts a type-I beta-turn, which is stabilized by hydrogen bonding between the CO of Asn2 and the NH of Ala5 as well as between the O(delta) of Asn2 and the NH of Asn4.     

An axiomatic approach to egalitarianism in TU-games

A core concept is a solution concept on the class of balanced games that exclusively selects core allocations. We show that every continuous core concept that satisfies both the equal treatment property and a new property called independence of irrelevant core allocations (IIC) necessarily selects egalitarian allocations. IIC requires that, if the core concept selects a certain core allocation for a given game, and this allocation is still a core allocation for a new game with a core that is contained in the core of the first game, then the core concept also chooses this allocation as the solution to the new game. When we replace the continuity requirement by a weak version of additivity we obtain an axiomatization of the egalitarian solution concept that assigns to each balanced game the core allocation minimizing the Euclidean distance to the equal share allocation.     

Egalitarian solutions in the core

In this paper we define the Lorenz stable set, a subset of the core consisting of the allocations that are not Lorenz dominated by any other allocation of the core. We introduce the leximin stable allocation, which is derived from the application of the Rawlsian criterion on the core. We also define and axiomatize the egalitarian core, a set of core allocations for which no transfer from a rich player to a poor player is possible without violating the core restrictions. We find an inclusive relation of the leximin stable allocation and of the Lorenz stable set into the egalitarian core. Received: October 1999/Final version: July 2001     

Low temperature deposition of TiO2 layers from nanoparticle containing suspensions synthesized by microwave hydrothermal treatment

In this paper, we present a microwave-assisted, hydrothermal method for the synthesis of TiO₂ suspensions. These were obtained from Ti⁴⁺ aqueous precursor solutions using titanium-isopropoxide with EDTA and triethanolamine or tetraethylammonium hydroxide by applying a microwave treatment at temperatures between 100 and 140 °C. The influence of the ligands, pH, reaction temperature and time on the particle size and crystallinity was investigated and discussed. A selection of the TiO₂ suspensions was deposited on glass substrates using piezoelectric driven ink-jet printing. The rheological properties of the suspensions were evaluated against the relevant criteria for ink-jet printing and their jetting behavior was analyzed. The ink-jet printed layers were heated at temperatures between 150 and 500 °C to create transparent titanium oxide layers. The photocatalytic activity of the finally obtained layers was analyzed by following the decomposition of a methylene blue solution under UV illumination. The presence of preformed titania nanoparticles makes it possible to obtain photocatalytic active coatings at reduced heating temperatures. This can widen the application range of these functional layers to heat-sensitive substrates such as polymers. The influence of the heat treatment temperature on the film roughness, thickness and photocatalytic activity was also studied.     

Effect of friction in wedging of elastic solids

In this paper the contact problem for an elastic wedge of arbitrary angle is considered. It is assumed that the external load is applied to the medium through a rigid wedge and the coefficient of friction between the loading wedge and the elastic solid is constant. The problem is reduced to a singular integral equation of the second kind with the contact pressure as the unknown function. An effective numerical solution of the integral equation is described and the results of three examples are presented. The comparison of these results with those obtained from the frictionless wedge problem indicates that generally friction has the tendency of reducing the peak values of the stress intensity factors calculated at the wedge apex and at the end points of the contact area.This work was supported by NASA-Laugley under the Grant NGR 39-007-011 and by NSF under the Grant GK-42771X.     

RADICAL IONS 561,2 ONE-ELECTRON OXIDATION OF 1,2-DITHIETE DERIVATIVES

Abstract

Novel 1,2-dithiete derivatives R₂C₂S₂ with R = [sbnd]C(CH₃)₃ and [sbnd]C(CH₃)₂[sbnd]CH₂[sbnd]CH₂[sbnd]CH₂[sbnd]C(CH₃)₂[sbnd] are readily oxidized by the one-electron transfer system AlCl₃/H₂CCl₂ to their radical cations. The single line ESR spectra, on high amplification, exhibit ³³S satellites in natural abundance. Both the ESR data, i.e. rather large g values and ³³S hyperfine coupling constants as well as MNDO closed and open shell calculations for the parent molecule H₂C₂S₂ illustrate that spin and positive charge are predominantly located in the SS bridge of the four-membered ring.     

Monotonicity properties of the nucleolus on the domain of veto balanced games

This note shows that the nucleolus does not satisfy aggregate monotonicity and strong monotonicity, even on the class of veto balanced games, while it does satisfy complementary antimonotonicity on this class.     

The nucleolus and kernel of veto-rich transferable utility games

The process of computing the nucleolus of arbitrary transferable utility games is notoriously hard. A number of papers have appeared in which the nucleolus is computed by an algorithm in which either one or a huge number of huge linear programs have to be solved. We show that on the class of veto-rich games, the nucleolus is the unique kernel element. Veto-rich games are games in which one of the players is needed by coalitions in order to obtain a non-zero payoff. We then provide a fast algorithm which does not use linear programming techniques to compute the nucleolus of these games. Furthermore, we provide a few examples of economic situations which belong to the class of veto-rich games and which are treated in the literature.