全文获取类型
收费全文 | 383篇 |
免费 | 6篇 |
国内免费 | 4篇 |
专业分类
化学 | 220篇 |
晶体学 | 1篇 |
力学 | 9篇 |
数学 | 46篇 |
物理学 | 117篇 |
出版年
2023年 | 1篇 |
2022年 | 3篇 |
2021年 | 5篇 |
2020年 | 7篇 |
2019年 | 6篇 |
2018年 | 5篇 |
2017年 | 3篇 |
2016年 | 10篇 |
2015年 | 7篇 |
2014年 | 11篇 |
2013年 | 18篇 |
2012年 | 20篇 |
2011年 | 22篇 |
2010年 | 15篇 |
2009年 | 16篇 |
2008年 | 30篇 |
2007年 | 10篇 |
2006年 | 20篇 |
2005年 | 14篇 |
2004年 | 13篇 |
2003年 | 6篇 |
2002年 | 8篇 |
2001年 | 11篇 |
2000年 | 23篇 |
1999年 | 7篇 |
1998年 | 9篇 |
1997年 | 5篇 |
1996年 | 9篇 |
1995年 | 4篇 |
1994年 | 10篇 |
1993年 | 9篇 |
1992年 | 8篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 6篇 |
1986年 | 3篇 |
1985年 | 7篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 2篇 |
1980年 | 3篇 |
1977年 | 1篇 |
1976年 | 2篇 |
排序方式: 共有393条查询结果,搜索用时 31 毫秒
1.
We study the connection between universal central extensions in the categories of precrossed and crossed modules. They are compared with several kinds of universal central extensions in the categories of groups, epimorphisms of groups, groups with operators and modules over a group. We study the relationship between the homologies defined in these categories. Applications to relative algebraic K-theory are also obtained. 相似文献
2.
A set of invariants describing the limit regimes of braking disk-type wound composite flywheels is suggested. The limit regime is determined by using a linear failure criterion. It is shown that, for generating short-time impulses of very high power, a set of small identical flywheels is more effective than one large flywheel with an equivalent mass. Particular examples illustrating the theory considered are discussed. 相似文献
3.
Juan Arias de Reyna 《Monatshefte für Mathematik》1988,106(2):95-97
We give another proof of Seymour and Zaslavsky's theorem: For every familyf
1,f
2,...,f
n of continous functions defined on [0, 1], there exists a finite setF[0, 1] such that the average sum off
k
overF coincides with the integral off
k
for everyk=1, 2,...,n. 相似文献
4.
A. González Arias C. Torres C. de
Francisco J. M. Muñoz P. Hernández
Gómez O. Alejos O. Montero J. I. Iñiguez 《Journal of Thermal Analysis and Calorimetry》2006,86(1):195-198
The article discusses theory and experiment about the measurement of
defect concentration in Ti-substituted yttrium iron garnet by means of thermogravimetry
techniques. The two possible cases arising from oxygen interchange with atmosphere,
oxygen vacancies and interstitial cations, may be analyzed quantitatively
from the derived expressions. The possibility of another type of defects being
present in the samples, not associated to oxygen evolution, is not excluded.
Measurements were carried out in air and CO2 for different
Ti contents. The substitution tends to increase slightly the defect parameter
θ in YIG, while a CO2 reducing atmosphere is
much more effective than the Ti substitution for increasing θ. Calculations
for a given single-phased sample sintered in air show two possibilities: a
deficit of one oxygen atom for every 2.5 unit cells of 96 atoms, or one excess
cation for every 3.5 cells. Other samples show very similar results. The accuracy
involved in the measurements is about 2–3%. 相似文献
5.
Qintong Huang Ningyue Chen Lichen Liu Karen S. Arias Sara Iborra Xianfeng Yi Chao Ma Weichi Liang Anmin Zheng Chuanqi Zhang Jibo Hu Zilin Cai Yi Liu Jiuxing Jiang Avelino Corma 《Chemical science》2020,11(44):12221
Aluminosilicate boggsite (Si/Al-BOG) has been hydrothermally synthesized without adding organic structure-directing agents (OSDAs) in the synthesis gel using the borosilicogermanium ITQ-47 (Si/B-ITQ-47) zeolite as seeds. The introduction of the costly and environmentally less benign phosphazene organic structure-directing agent is not required to grow the zeolite. Physicochemical characterization experiments show that Si/Al-BOG has good crystallinity, high surface area, tetrahedral Al3+ species, and acid sites. In order to test the catalytic performance of the zeolite, the synthesis of l,l-lactide from l-lactic acid was performed. Si/Al-BOG exhibits 88.2% conversion of l-lactic acid and 83.8% l,l-lactide selectivity, which are better than those of other zeolites studied up to now.Aluminosilicate boggsite (Si/Al-BOG) has been hydrothermally synthesized without adding organic structure-directing agents (OSDAs) in the synthesis gel using the borosilicogermanium ITQ-47 (Si/B-ITQ-47) zeolite as seeds. 相似文献
6.
Garcia Ruano JL Alcudia A del Prado M Barros D Maestro MC Fernandez I 《The Journal of organic chemistry》2000,65(10):2856-2862
The addition of the lithium anions derived from (R)- and (S)-methyl and -ethyl p-tolyl sulfoxides to (S)-N-benzylidene-p-toluenesulfinamide provides an easy access route to enantiomerically pure beta-(N-sulfinyl)amino sulfoxides. Stereoselectivity can be achieved when the configurations at the sulfur atoms of the two reagents are opposite (matched pair), thus resulting in only one diastereoisomer, even for the case in which two new chiral centers are created. The N-sulfinyl group primarily controls the configuration of the carbon bonded to the nitrogen, whereas the configuration of the alpha-sulfinyl carbanion seems to be responsible for the level of asymmetric induction, as well as for the configuration of the new stereogenic C-SO carbon in the reactions with ethyl p-tolyl sulfoxides. An efficient method for transforming the obtained beta-(N-sulfinyl)amino sulfoxides into optically pure beta-amino alcohols, based on the stereoselective non-oxidative Pummerer reaction, is also reported. 相似文献
7.
Neira-Carrillo A Yazdani-Pedram M Retuert J Diaz-Dosque M Gallois S Arias JL 《Journal of colloid and interface science》2005,286(1):134-141
The biopolymer chitosan was chemically modified by grafting polyacrylamide or polyacrylic acid in a homogeneous aqueous phase using potassium persulfate (KPS) as redox initiator system in the presence of N,N-methylene-bis-acrylamide as a crosslinking agent. The influence of the grafted chitosan on calcium salts crystallization in vitro was studied using the sitting-drop method. By using polyacrylamide grafted chitosan as substrate, rosette-like CaSO4 crystals were observed. This was originated by the presence of sulfate coming from the initiator KPS. By comparing crystallization on pure chitosan and on grafted chitosan, a dramatic influence of the grafted polymer on the crystalline habit of both salts was observed. Substrates prepared by combining sulfate with chitosan or sulfate with polyacrylamide did not produce similar CaSO4 morphologies. Moreover, small spheres or donut-shaped CaCO3 crystals on polyacrylic acid grafted chitosan were generated. The particular morphology of CaCO3 crystals depends also on other synthetic parameters such as the molecular weight of the chitosan sample and the KPS concentration. 相似文献
8.
The framework of the paper is that of the full Fock space
and the Banach algebraF
which can be viewed as non-commutative analogues of the Hardy spacesH
2 andH
respectively.An inner-outer factorization for any element in
as well as characterization of invertible elements inF
are obtained. We also give a complete characterization of invariant subspaces for the left creation operatorsS
1
,..., S
n
of
. This enables us to show that every weakly (strongly) closed unital subalgebra of {(S
1
,..., S
n
) F
} is reflexive, extending in this way the classical result of Sarason [S]. Some properties of inner and outer functions and many examples are also considered.The first author was supported in part by NSF DMS 93-21369 1991Mathematics Subject Classification. Primary 47D25, Secondary 32A35, 47A67. 相似文献
9.
10.
A. González Arias A. del Cueto J. M. Muñoz C. de Francisco L. Torres A. G. Flores M. Zazo J. Iñiguez 《Applied Physics A: Materials Science & Processing》1996,63(5):453-459
Silica may dissolve up to about 0.05 wt% in an iron excess NiZnCo spinel matrix, affecting noticeably the magnetic properties at low and high values of the applied field. The initial permeability is reduced by about 50% with the addition of only 0.1 % SiO2, while the coercivity almost triples, without noticeable changes in porosity or grain distribution. The vacancy and Fe2+ content of the sintered material also show a considerable change. The energy associated to the transformation Fe3+ Fe2+ for the samples without SiO2 was found to be 0.41–0.42 eV, while for the samples with SiO2 additions it decreased to 0.26 eV. The changes in magnetic properties are thought to be caused, more than because of the mentioned changes in ion distribution, by the stresses and defects created in the lattice due to the very small size of the Si4+ ion, which substitutes Fe3+ ions in tetrahedral sites. The transition Fe3+ Fe2+ seems to take place exclusively in the octahedral sites. 相似文献