The design of new solid-state proton-conducting materials is a great challenge for chemistry and materials science. Herein, a new anionic porphyrinylphosphonate-based MOF ( IPCE-1Ni ), which involves dimethylammonium (DMA) cations for charge compensation, is reported. As a result of its unique structure, IPCE-1Ni exhibits one of the highest value of the proton conductivity among reported proton-conducting MOF materials based on porphyrins (1.55×10−3 S cm−1 at 75 °C and 80 % relative humidity). 相似文献
The behavior of group-4 homologs Zr and Hf on extraction-chromatographic sorbents LN resin and TRU resin in mixtures of HF and HNO3 is considered. Distribution coefficients of the elements in the mixtures of 5·10−4 M–1 M HF and 0.01 M–5 M HNO3 are determined. Strong retention of both elements was found on LN resin in the range of concentrations c(HF) ≤ 0.01 M for all concentrations of HNO3. Retention tends to gradually disappear while increasing c(HF) to 0.5 M. On TRU resin retention is observed only in solutions with c(HNO3) ≥ 2 M and c(HF) ≤ 0.01 M. The possibility of separating Zr(IV) and Hf(IV) on LN resin is illustrated in two different acid mixtures, whereas their separation on TRU resin under the conditions studied in this work is difficult. The results obtained can be used to isolate analytes from multicomponent mixtures during analytical tasks, as well as to separate them from each other.
A highly selective and efficient oxidative carbocyclization/borylation of enallenols catalyzed by palladium immobilized on amino-functionalized siliceous mesocellular foam (Pd-AmP-MCF) was developed for diastereoselective cyclobutenol synthesis. The heterogeneous palladium catalyst can be recovered and recycled without any observed loss of activity or selectivity. The high diastereoselectivity of the reaction is proposed to originate from a directing effect of the enallenol hydroxyl group. Optically pure cyclobutenol synthesis was achieved by the heterogeneous strategy by using chiral enallenol obtained from kinetic resolution. 相似文献
We argue that it may be possible to consistently explain the quantum measurement by assuming that the wave function is in one-to-one correspondence with objective physical reality and has no probabilistic interpretation. In the context of such approach we consider the model of a harmonic oscillator linearly coupled to a heat bath and treat the oscillator as the system being measured. Three classes of initial pure states for the bath are considered. Exact expressions for the average values and variances of the oscillator coordinate and momentum as functions of time are considered for each class of pure states. It is shown that these quantities exhibit different asymptotic behavior for different classes of initial states of the bath. In particular, if each mode of the bath is initially in a coherent state, then for an arbitrary initial state of the oscillator the variances of the oscillator coordinate and momentum asymptotically approach the same values as for a coherent state of the free oscillator, while the averages of coordinate and momentum show a Brownian-like behavior. We argue that such behavior shows several features of the quantum measurement and supports our interpretation of the wave function. 相似文献
The reaction of trirutheniumdodecacarbonyl with various thioureas was found to give, depending upon the substituents and the reaction conditions, a large variety of tri-, tetra-, penta-, and hexanuclear ruthenium clusters. The ligand systems observed in the products are derived from the thioureas employed; the fragmentation of the thiourea molecules involve N-H, C-S, C-H, and C-N activation processes. 相似文献
A linear spectral estimation technique, the PDFT algorithm, is used as part of a nonlinear iterative reconstruction scheme to obtain improved radar images. The iterative PDFT algorithm is used to address the limited resolution problem inherent to imaging objects buried in soil and hidden under foliage. This is achieved by subsequent application of two properties of the PDFT algorithm: the energy parameter of the PDFT algorithm is used to determine the target shape, while the shape information in turn is used to obtain super-resolved images. We describe algorithms able to exploit both properties automatically and without manual intervention. Two methods are investigated in particular, one iteratively optimizing the constraints by monitoring the energy parameter, the other method computing energy values for all points, from which a weighted prior function is determined. In addition, we discuss variants of both algorithm which provide an optimized trade-off between computation time and performance. Additional attention is given to situations, where a known target is embedded in an unknown background. Imaging results are presented for both synthetic and measured data. 相似文献
Tetraphenylantimony(V) carboxylates have been used in the palladium-catalyzed C-phenylation reaction of methyl acrylate in the presence of (PhCO2)2 or t-BuOOH under mild conditions (50 °C). The peroxides promote a cascade participation of the organoantimony compound and result in the transfer of three phenyl groups. Organoantimony intermediates have been isolated from the reaction. 相似文献
Scattering of surface plasmon polaritons (SPP’s) by small ellipsoid particles placed near a dielectric–metal interface is theoretically considered. Using the Green’s function formalism and the dipole approximation, we consider the differential and total scattering cross-sections associated with the SPP-to-SPP scattering as well as with the SPP scattering into waves propagating away from the interface, analyzing the influence of system parameters. As an example, scattering cross-sections of differently shaped gold spheroid particles placed near an air–gold interface are evaluated at the light wavelength of 800 nm. It is shown that the differential and total cross-sections depend strongly upon the particle-to-surface distance, the ratio between the major and minor axes and their orientation with respect to both the interface and the direction of SPP incidence. Implications of the obtained results to the design of SPP micro-optical components are also discussed. 相似文献