全文获取类型
收费全文 | 180篇 |
免费 | 3篇 |
专业分类
化学 | 119篇 |
力学 | 4篇 |
数学 | 2篇 |
物理学 | 58篇 |
出版年
2020年 | 2篇 |
2016年 | 1篇 |
2014年 | 4篇 |
2013年 | 5篇 |
2012年 | 5篇 |
2011年 | 6篇 |
2010年 | 7篇 |
2009年 | 2篇 |
2008年 | 5篇 |
2007年 | 6篇 |
2006年 | 15篇 |
2005年 | 7篇 |
2004年 | 7篇 |
2003年 | 5篇 |
2002年 | 6篇 |
2001年 | 3篇 |
2000年 | 4篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1995年 | 4篇 |
1994年 | 2篇 |
1993年 | 7篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 4篇 |
1988年 | 6篇 |
1987年 | 5篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1982年 | 4篇 |
1981年 | 5篇 |
1980年 | 3篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1961年 | 2篇 |
1960年 | 1篇 |
1959年 | 2篇 |
1958年 | 5篇 |
1957年 | 1篇 |
1956年 | 7篇 |
1954年 | 4篇 |
1953年 | 1篇 |
1950年 | 1篇 |
1948年 | 1篇 |
1939年 | 1篇 |
1936年 | 1篇 |
1933年 | 1篇 |
1893年 | 1篇 |
排序方式: 共有183条查询结果,搜索用时 15 毫秒
1.
2.
A mean-field model of nonlinearly coupled oscillators with randomly distributed frequencies and subject to independent external white noises is analyzed in the thermodynamic limit. When the frequency distribution isbimodal, new results include subcritical spontaneous stationary synchronization of the oscillators, supercritical time-periodic synchronization, bistability, and hysteretic phenomena. Bifurcating synchronized states are asymptotically constructed near bifurcation values of the coupling strength, and theirnonlinear stability properties ascertained. 相似文献
3.
G. Hillrichs M. Dressel H. Hack R. Kunstmann W. Neu 《Applied physics. B, Lasers and optics》1992,54(3):208-215
Measurements of the transmission of XeCl excimer laser pulses (308 nm) through optical all-silica fibers are reported. The observed photodegradation effects during long time irradiation are dependent on the laser energy density and the laser repetition rate. Also the influence of the fiber drawing parameters and fiber geometry have been investigated. Absorption spectra of the fibers in the wavelength range from 200nm to 400nm before and after the irradiation with the excimer laser give some insight in the physical reasons for the changes in transmission properties. A spectral analysis of the fiber fluorescence has been performed.Presented at LASERION '91, June 12–14, 1991, München (Germany) 相似文献
4.
Richard Neu 《Fresenius' Journal of Analytical Chemistry》1954,143(1):30-38
Ohne ZusammenfassungII. Mitteilung: R. Neu 7. 相似文献
5.
6.
Richard Neu 《Fresenius' Journal of Analytical Chemistry》1956,151(5):328-332
Ohne ZusammenfassungVIII. Mitt. Über Tetraphenyl-diboroxyd.VII. Mitt. Vgl. Naturwissenschaften 43, 82 (1956).Verf. dankt Frl. Elisabeth Buhl für zuverlässige und eifrige Mitarbeit. 相似文献
7.
A rugged procedure utilizing reversed-phase liquid chromatography with positive-ion electrospray ionization mass spectrometry (LC-MS) along with tandem MS is described for the quantification and confirmation of N-methylpyrrolidinone (NMP) in methanolic extracts of riverine biofilm. The LC-MS method provided a 100-fold improvement in detection limits (2 ng g(-1) with a repeatability of 80-95% based on triplicate analyses) compared to a conventional LC-UV detection procedure and was applicable to quantitative analysis of biofilm samples with little or no clean up. Under low-energy collision induced dissociation (CID) conditions (17 V, laboratory frame of reference, with argon as the collision gas), two product-ions of the [M+H]+ ion were formed at m/z 69 [MH-CH3NH2]+ and m/z 58 [MH-CH3NCH]+ with relative abundances of 30% and 5%, respectively. These CID transitions were used to demonstrate that biofilm uptake of a photocatalytically-generated mixture of NMP was rapid once acclimation was achieved. 相似文献
8.
Surface modification of soft-glass capillaries for gas chromatography by treatment with water vapour
“Leaching” or “etching” by strong mineral acids seems to be a necessary pretreatment step for the most commonly used deactivation procedures of glass capillaries by reaction with either polyethylene glycol or silylation reagents. The acidic sites which are formed on the surface during this acid treatment cannot be completely removed by the subsequent deactivation process. This drawback can be overcome by performing the leaching with water vapour, resulting in an accumulation of cations at the surface and a decrease in the number of silanol groups. Capillaries of this type show excellent properties for the chromatography of strongly basic compounds. After the wash-out of the alkaline surface layer, the acidity of the support is suited for the chromatography of strongly basic as well as strongly acidic compounds. Due to a lack of reactive acidic sites, special deactivation procedures have to be applied to capillaries produced in this way. 相似文献
9.
Zusammenfassung In der vorliegenden Arbeit wird eine Methode zur Retentionsindex-Bestimmung beschrieben, die von einem kubischen Zusammenhang zwischen Bruttoretentionszeit-Differenzen der Referenzhomologen und der Kohlenstoffzahl ausgeht. Hieraus ergeben sich direkt die Nettoretentionszeiten. Der Fehler der Totzeitbestimmung entfällt bei dieser Methode. Mit den so gewonnenen Nettoretentionszeiten erhält man über einen kubischen Zusammenhang zwischen 1g ts=f(C) die Retentionsindices. Extrapolationen und Interpolationen sind über 300 Retentionsindexeinheiten mit einem mittleren Fehler von ±0,02 Retentionsindexeinheiten möglich. Das Verfahren bietet sich für eine automatische Berechnung der I-Werte mittels on-line-Datenverarbeitung an.
Cubic calculation of retention indices without determining the dead-time tm
Summary The method for the calculation of retention indices described here is based on a third order relationship between the logarithm of differences of unadjusted retention times of homologues and the carbon number. From this adjusted retention times are directly calculated. A determination of the dead-time is not necessary thus avoiding the errors connected with this factor. A cubic equation for the logarithm of the adjusted retention time lg ts as a function of carbon number Cn is used for the retention index calculation. Extrapolations and interpolations can be done over a range of 300 index units with an average deviation of ±0.02 i.u.. The method offers the possibility of an automated on-line calculation of retention indices by computer merely on the basis of unadjusted retention times.相似文献
10.
Richard Neu 《Fresenius' Journal of Analytical Chemistry》1956,153(3):183-186
Ohne ZusammenfassungVerfasser dankt Herrn Dr. H. Harms, Farbenfabriken Bayer, Leverkusen, für eine interessante Diskussion über die Verwendungsmöglichkeiten fester Diazoniumsalze, den Farbwerken Hoechst, A. G., Frankfurt (M)-Hoechst, für zur Verfügung gestellte Diazoniumsalze und Frl. Elisabeth Buhl für ihre Mitarbeit. 相似文献