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Parthiban A. Lingam K. Arun Prasath Mangalaraj S. Muthukrishnan P. Surendiran M. 《Journal of Cluster Science》2021,32(5):1401-1409
Journal of Cluster Science - Single crystal electron paramagnetic resonance (EPR), powder X-ray diffraction (XRD), Fourier transform-infrared (FT-IR) and UV–Visible (UV–Vis)... 相似文献
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A series of N‐chloroacetyl‐2,6‐diarylpiperidin‐4‐ones (10–18) obtained from the corresponding 2,6‐diarylpiperidin‐4‐ones upon base‐catalyzed condensation with morpholine afforded N‐morpholinoacetyl‐2,6‐diarylpiperidin‐4‐ones (19–27). The synthesized compounds have been characterized by their elemental, analytical, and spectral data. 相似文献
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Satyasankar Jana Vivek Arjunan Vasantha Ludger Paul Stubbs Anbanandam Parthiban Julius G. Vancso 《Journal of polymer science. Part A, Polymer chemistry》2013,51(15):3260-3273
Vinylimidazole‐based asymmetric ion pair comonomers ( IPC s) which are free from nonpolymerizable counter ions have been synthesized, characterized and polymerized by free radical polymerization (FRP), atom transfer radical polymerization (ATRP), and reversible addition‐fragmentation chain transfer (RAFT) mediated polymerizations in solution and by dispersion polymerization in water. The asymmetric nature of IPC s is due to the fact that cationic component of these IPCs is derived from vinylimidazole (VIm) and anionic component is derived from either styrenesulfonate (SS) or 2‐acrylamido‐2‐methyl‐1‐propanesulfonate. Although under ATRP, conversions are either very low or negligible, FRP and RAFT produces polymers with high to moderate monomer conversions but with different solubility characteristics. This investigation provides insight to the polymerization behavior of each component of the asymmetric IPCs and also its effects on composition and solubility characteristics of the resulting polymers. The IPCs studied here are high temperature ionic liquid and thus the polymers synthesized from these IPCs are highly ionic in nature and possess very strong intermolecular interactions which makes some of these IPC based polymers completely insoluble in organic and aqueous solvents. This highly ionic interaction is exploited to synthesize ionically crosslinked PMMA. MMA on copolymerization with 5–6 mol % of IPC yielded copolymer which is insoluble in common organic solvents like THF, DMF, etc., unlike homo PMMA. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 3260–3273 相似文献
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Kaiprathu Anjali Velayudham Parthiban Teller Hanan Schechter Alex 《Journal of Solid State Electrochemistry》2022,26(9):1897-1917
Journal of Solid State Electrochemistry - Electrocatalytic nitrogen reduction reaction (E-NRR) to ammonia is becoming a major topic of interest in the field of large-scale energy storage from... 相似文献
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S. P. Meenakshisundaram S. Parthiban G. Madhurambal S.C. Mojumdar 《Journal of Thermal Analysis and Calorimetry》2008,94(1):21-25
The influence of a new organic additive, chelating agent 1,10-phenanthroline (Phen) (∼5.0·10−3 M L−1) on potassium hydrogen phthalate (KHP) single crystals at 30° is investigated. The crystals were grown from the aqueous solutions
of pH ∼4.5 at constant temperature by solvent evaporation technique. The chelating agent leads to an increase in metastable
zone width and assists the bulk growth process. The growth rate of crystals in the presence of Phen decreases considerably
with an increase in impurity concentration. Not much variation is observed in FTIR and cell parameter values, determined by
XRD analysis. It appears that the growth promoting effect (GPE) of Phen is caused by the adsorption of the organic additive
on the prism of KHP crystals. Differential scanning calorimetry (DSC) and TG-DTA studies reveal the purity of the sample and
no decomposition is observed up to the melting point. Scanning electron microscope (SEM) photographs exhibit the effectiveness
of the impurity in changing the surface morphology of KHP crystals. Contrary to expectations, Phen depresses the NLO efficiency
of KHP, suggesting that the molecular alignments in the presence of Phen results in cancellation effects disturbing the non-linearity. 相似文献
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S. Meenakshisundaram S. Parthiban U. R. Pisipaty G. Madhurambal S. C. Mojumdar 《Journal of Thermal Analysis and Calorimetry》2010,100(3):821-826
The influence of the highly fluorescent dopant, anthracene (over a concentration range from 5 × 10?4 to 1.2 × 10?2 mol dm?3) on the nonlinear optical properties and fluorescence intensity of potassium hydrogen phthalate (KHP) single crystals grown at 30 °C by a slow evaporation solution growth technique (SEST) has been investigated. Powder XRD and FTIR spectral analyses confirm the slight distortion of the structure of crystal because of doping. UV–Visible study shows that the transparency is not affected much by the dopant. The SEM investigation reveals that KHP suffers from crack development. Thermal analysis indicates that there is no decomposition of the crystal up to the melting point. It is interesting to observe that additions of small quantity anthracene to KHP results in the enhancement of fluorescence intensity. The fluorescence intensity dependence on dopant concentration is observed. Interestingly, second harmonic generation (SHG) efficiency of KHP is dramatically improved by doping with small quantities of anthracene. 相似文献
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Asawin Likhitsup Anbanandam Parthiban Christina L. L. Chai 《Journal of polymer science. Part A, Polymer chemistry》2008,46(1):102-116
A simple, one‐step procedure has been developed for the preparation of bifunctional initiators capable of polymerizing monomers suitable for atom‐transfer radical polymerization (ATRP) and ring‐opening polymerization (ROP). These bifunctional initiators were employed for making narrow disperse poly(styrene) macroinitiators, which were subsequently used for the ROP of various lactides to yield poly(styrene‐block‐lactide) copolymers. Thermogravimetric analysis (TGA) of these block copolymers are interesting in that it shows a two‐step degradation curve with the first step corresponding to the degradation of poly(lactide) segment and the second step associated with the poly(styrene) segment of the block copolymer. This nature of the block copolymer makes it possible to estimate the block copolymer content by TGA in addition to the 1H NMR spectroscopic analysis. Thus, this study for the first time highlights the possibility of making porous materials by thermal means which are otherwise obtained by base hydrolysis. The bifunctional initiators were prepared by the esterification of 3‐hydroxy, 4‐hydroxy, and 3,5‐dihydroxy benzyl alcohols with α‐bromoisobutyryl bromide and 2‐bromobutyryl bromide. A mixture of products was obtained, which were purified by column chromatography. The esterified benzyl alcohols were employed in the polymerization of styrene under copper (Cu)‐catalyzed ATRP conditions to yield macroinitiators with low polydispersity. These macroinitiators were subsequently used in the ROP of L ‐, DL ‐, and mixture of lactides. The formation of block copolymers was confirmed by gel permeation chromatography (GPC), spectroscopic and thermal characterizations. The molecular weight of the block copolymers was always higher than the macroinitiator, and the GPC chromatogram was symmetrical indicating the uniform initiation of ROP by the macroinitiators. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 102–116, 2008 相似文献
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