Semicarbazones and thiosemicarbazones,XII: Crystal structure of salicylaldehyde semicarbazone

Summary The crystal and molecular structure of salicylaldehyde semicarbazone was obtained by single crystal X-ray diffraction. The O atom of the semicarbazone fragment isanti to the N atom of the hydrazinic group. The distribution of bond lengths in the semicarbazone fragment indicates delocalization of the -electrons. The crystal structure is stabilized by intra- and intermolecular hydrogen bonds.

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Semicarbazone und Thiosemicarbazone, 12. Mitt.: Die Kristallstruktur des Salicylaldehyd-Semicarbazons

Zusammenfassung Die Kristallstruktur und die molekulare Struktur des Salicylaldehyd-Semicarbazons wurde über Einkristall-Röntgenstreuung ermittelt. Das O-Atom des Semicarbazonteils stehtanti zum N-Atom der Hydrazin-Gruppierung. Die Bindungslängen in der Semicarbazoneinheit zeigen eine Delokalisierung der -Elektronen an. Die Geometrie der Verbindung wird durch stabilisierende intra- und intermolekulare Wasserstoffbrückenbindungen bestimmt.

     

Spectrophotometric resolution of ternary mixtures of amaranth,Carmoisine and Ponceau 4R by the derivative ratio spectrum-zero crossing method

A method for the simultaneous determination of Amaranth, Ponceau 4R and Carmoisine dyes in ternary mixtures is proposed, with no separation step; this is based on the simultaneous use of the first derivative of ratio spectra and measurements at zero-crossing wavelengths. The calibration graphs are linear up to 32 mg/L of Amaranth, Carmoisine and Ponceau 4R. The mean recovery is 102.1, 95.3 and 102.6 %, respectively. The method was applied to several food products.     

A STUDY OF THE PRIMARY ELECTROVISCOUS EFFECT IN PYREX GLASS SUSPENSIONS.

An experimental investigation on the electrokinetic phenomenon known as primary electroviscous effect is described for suspensions of Pyrex glass, a highly charged and well known material. By means of an automatic method, the viscosity of the suspensions is measured for different volume fractions of solids, at various electrolyte concentrations and pH values. These measurements allow the estimation of the electroviscous coefficient, p. The electrophoretic mobility was determined for the same systems and zeta potential calculated from these experimental data in order to carry out the comparison between the measured values of p and different theoretical predictions. A qualitative agreement between theory and experiment was found in many cases, but the rigorous theories seem to systemmatically underestimate the experimental p values. The reasons for this disagreement are discussed in addition to the general trends of the electrokinetic behaviour of Pyrex glass.     

Development of a capillary zone electrophoretic method to determine six antidepressants in their pharmaceutical preparations. Experimental design for evaluating the ruggedness of method

A capillary zone electrophoresis method is proposed for the separation of six of the antidepressants most used for the treatment of mental illness (clomipramine, paroxetine, fluoxetine, citalopram, fluvoxamine, and trazodone). Optimum conditions for their separation were investigated. A background electrolyte solution consisting of 50 mM phosphate buffer adjusted to pH 2.0, hydrodynamic injection, and 25 kV as separation voltage were used. Relative standard deviations (RSD) were <0.38% and <2.93% for migration time and corrected peak area (n = 24), respectively. Detection limits obtained for the six antidepressants ranged from 0.03 to 0.11 mg L(-1). Stability of the solutions, linear concentration range, accuracy, and precision were examined during validation of the method. A ruggedness test of this method was performed using the fractional factorial model of Plackett-Burman, requiring in our case design of a matrix of 15 experiments, in which the influence of seven factors at three different levels was tested on different electrophoretic results: efficiency; resolution; and corrected peak area. Statistical evaluation of electrophoretic results was achieved by Youden and Steiner's method. The described method is rapid, sensitive, and rugged and it was tested for the pharmaceutical formulation analysis, giving recoveries between 95.6 and 99.1% with respect to the nominal content.     

Generalized heat kernel coefficients

In hadronic collisions, the mini-jet cross section is formally divergent in the limit . We argue that this divergence is tamed by some effective colour correlation length scale of the hadron. A toy model of the hadronic structure is introduced, that allows an estimate of the screening effects, and especially their energy dependence.     

Meson-baryon s-wave resonances with strangeness -3

Starting from a consistent SU(6) extension of the Weinberg-Tomozawa (WT) meson-baryon chiral Lagrangian ( Phys. Rev. D 74, 034025 (2006)), we study the s-wave meson-baryon resonances in the strangeness S = - 3 and negative-parity sectors. Those resonances are generated by solving the Bethe-Salpeter equation with the WT interaction used as kernel. The considered mesons are those of the 35-SU(6)-plet, which includes the pseudoscalar (PS) octet of pions and the vector (V) nonet of the rho-meson. For baryons we consider the 56-SU(6)-plet, made of the 1/2⁺ octet of the nucleon and the 3/2⁺ decuplet of the Delta. Quantum numbers I(J ^P) = 0(3/2^-) are suggested for the experimental resonances Ω ^*(2250)^- and Ω ^*(2380)^-. Among other, resonances with I = 1 are found, which minimal quark content is sssˉl', being s the strange quark and l, l' any of the the light up or down quarks. A clear signal for such a pentaquark would be a baryonic resonance with strangeness -3 and electric charge -2 or 0, in proton charge units. We suggest looking for K ^- Ξ ^- resonances with masses around 2100 and 2240MeV in the sector 1(1/2^-), and for π ^± Ω ^- and K ^- Ξ ^*- resonances with masses around 2260MeV in the sector 1(3/2^-).     

Derivative expansion for the effective action of chiral gauge fermions. The normal parity component

Explicit exact formulas are presented, up to fourth order in a strict chiral covariant derivative expansion, for the normal parity component of the Euclidean effective action of even-dimensional Dirac fermions. The bosonic background fields considered are scalar, pseudo-scalar, vector and axial vector. No assumptions are made on the internal symmetry group and, in particular, the scalar and pseudo-scalar fields need not be on the chiral circle. Received: 31 January 2001 / Published online: 12 April 2001     

LPV identification of a turbocharged diesel engine

This work proposes a methodology of identifying linear parameter varying (LPV) models for nonlinear systems. First, linear local models in some operating points, by applying standard identifications procedures for linear systems in time domain, are obtained. Next, a LPV model with linear fractional dependence (LFR) with respect to measured variables is fitted with the condition of containing all the linear models identified in previous step (differential inclusion). The fit is carried out using nonlinear least squares algorithms. Finally, this identification methodology will then be applied to a nonlinear turbocharged diesel engine.     

Effects of the attractive interactions in the thermodynamic, dynamic, and structural anomalies of a two length scale potential

Using molecular dynamic simulations, we study a system of particles interacting through a continuous core-softened potentials consisting of a hard core, a shoulder at closest distances, and an attractive well at further distance. We obtain the pressure-temperature phase diagram of this system for various depths of the tunable attractive well. Since this is a two length scale potential, density, diffusion, and structural anomalies are expected. We show that the effect of increasing the attractive interaction between the molecules is to shrink the region in pressure in which the density and the diffusion anomalies are present. If the attractive forces are too strong, particle will be predominantly in one of the two length scales and no density of diffusion anomaly is observed. The structural anomalous region is present for all the cases.     

Leading order one-loop CP and P violating effective action in the Standard Model

The fermions of the Standard Model are integrated out to obtain the effective Lagrangian in the sector violating P and CP   at zero temperature. We confirm that no contributions arise for operators of dimension six or less and show that the leading operators are of dimension eight. To assert this we explicitly compute one such non-vanishing contribution, namely, that with three Z⁰$Z^0$, two W⁺$W^{+}$ and two W⁻$W^{-}$. Terms involving just gluons and W?s are also considered, however, they turn out to vanish in the P-odd sector to eighth order. The analogous gluonic term in the CP-odd and P-even (C-odd) sector is non-vanishing and it is also computed. The expressions derived apply directly to massive Dirac neutrinos. All CP-violating results display the infrared enhancement already found at dimension six.