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2.
Shaobo Cheng Vidushi Sharma Altug S. Poyraz Lijun Wu Xing Li Amy C. Marschilok Esther S. Takeuchi Kenneth J. Takeuchi Marivi Fernndez-Serra Yimei Zhu 《Chemical science》2020,11(19):4991
Tunneled metal oxides such as α-Mn8O16 (hollandite) have proven to be compelling candidates for charge-storage materials in high-density batteries. In particular, the tunnels can support one-dimensional chains of K+ ions (which act as structure-stabilizing dopants) and H2O molecules, as these chains are favored by strong H-bonds and electrostatic interactions. In this work, we examine the role of water molecules in enhancing the stability of K+-doped α-Mn8O16 (cryptomelane). The combined experimental and theoretical analyses show that for high enough concentrations of water and tunnel-ions, H2O displaces K+ ions from their natural binding sites. This displacement becomes energetically favorable due to the formation of K2+ dimers, thereby modifying the stoichiometric charge of the system. These findings have potentially significant technological implications for the consideration of cryptomelane as a Li+/Na+ battery electrode. Our work establishes the functional role of water in altering the energetics and structural properties of cryptomelane, an observation that has frequently been overlooked in previous studies.Water displaces potassium ions and initiates the formation of a homonuclear dimer ion (K2+) in the tunnels of hollandite. 相似文献
3.
Benjamin E. Blass Anil Srivastava Amy L. Faulkner James M. Ridgeway 《Tetrahedron letters》2004,45(6):1275-1277
The solid-phase synthesis of a series of imidazo[1,2-b]pyrazol-2-ones, an interesting 5,5-fused ring system, based on diverse set of hydrazine acids and malanonitriles is described. The method involves formation of 5-aminopyrazoles on solid support and subsequent cyclizative cleavage off the resin. Compounds were obtained in acceptable to excellent yields and are suitable for biological evaluation without further purification. 相似文献
4.
Roger H. Newman 《Cellulose (London, England)》2004,11(1):45-52
Solid-state 13C NMR spectroscopy was used to characterize a bleached softwood kraft pulp in the never-dried state and after cycles of drying and remoistening. Changes in NMR signal strengths indicated that growth of crystalline domains involved cocrystallization rather than accretion of cellulose from noncrystalline domains. A cluster of C-4 signals at 89.4 ppm, assigned to the interiors of crystalline domains, grew at the expense of C-4 signals at 84.0 and 84.9 ppm, assigned to the well-ordered surfaces of crystalline domains. Irreversible changes were not detected until the moisture content dropped below 18%. They were enhanced by a second drying/remoistening cycle, but showed little further change on subsequent cycles. The necessary conditions resembled those reported for hornification, suggesting that cocrystallization might provide a mechanism for hornification. 相似文献
5.
Sajewicz Mieczysław Hauck Heinz-E. Drabik Gabriela Namysło Ewa Głód Bronisław Kowalska Teresa 《平面色谱法杂志一现代薄层色谱法》2006,19(4):278-281
JPC – Journal of Planar Chromatography – Modern TLC - We have previously described unexpected two-dimensionality in the thin-layer chromatographic separation of pairs of enantiomers of... 相似文献
6.
The free groups of exponent eight are shown to differ from thoseof sufficiently large exponent in the nature of their finitesubgroups. 相似文献
7.
How Focusing Phenomena in the Instructional Environment Support Individual Students' Generalizations
This article sets forth a way of connecting the classroom instructional environment with individual students' generalizations. To do so, we advance the notion of focusing phenomena, that is, regularities in the ways in which teachers, students, artifacts, and curricular materials act together to direct attention toward certain mathematical properties over others. The construct of focusing phenomena emerged from an empirical study conducted during a 5-week unit on slope and linear functions in a high school classroom using a reform curriculum. Qualitative evidence from interviews with 7 students revealed that students interpreted the m value in y = b + mx as a difference rather than a ratio as a result of counterproductive generalization afforded by focusing phenomena. Classroom analysis revealed 4 focusing phenomena, which regularly directed students' attention to various sets of differences rather than to the coordination of quantities. 相似文献
8.
It was argued by Schramm and Smirnov that the critical site percolation exploration path on the triangular lattice converges
in distribution to the trace of chordal SLE
6. We provide here a detailed proof, which relies on Smirnov’s theorem that crossing probabilities have a conformally invariant
scaling limit (given by Cardy’s formula). The version of convergence to SLE
6 that we prove suffices for the Smirnov–Werner derivation of certain critical percolation crossing exponents and for our analysis
of the critical percolation full scaling limit as a process of continuum nonsimple loops.
Research of Charles M.Newman was partially supported by the US NSF under grants DMS-01-04278 and DMS-06-06696. 相似文献
9.
Cardy's formula for some dependent percolation models 总被引:2,自引:0,他引:2
F. Camia C. M. Newman V. Sidoravicius 《Bulletin of the Brazilian Mathematical Society》2002,33(2):147-156
We prove Cardy's formula for rectangular crossing probabilities in dependent site percolation models that arise from a deterministic cellular automaton with a random initial state. The cellular automaton
corresponds to the zero-temperature case of Domany's stochastic Ising ferromagnet on the hexagonal lattice (with alternating
updates of two sublattices) [7]; it may also be realized on the triangular lattice 𝕋 with flips when a site disagrees with
six, five and sometimes four of its six neighbors.
Received: 24 December 2001 相似文献
10.