全文获取类型
收费全文 | 276篇 |
免费 | 10篇 |
国内免费 | 1篇 |
专业分类
化学 | 195篇 |
晶体学 | 4篇 |
力学 | 11篇 |
数学 | 12篇 |
物理学 | 65篇 |
出版年
2022年 | 1篇 |
2021年 | 1篇 |
2020年 | 2篇 |
2019年 | 5篇 |
2018年 | 2篇 |
2017年 | 1篇 |
2016年 | 4篇 |
2015年 | 7篇 |
2014年 | 11篇 |
2013年 | 13篇 |
2012年 | 16篇 |
2011年 | 9篇 |
2010年 | 11篇 |
2009年 | 10篇 |
2008年 | 17篇 |
2007年 | 16篇 |
2006年 | 16篇 |
2005年 | 18篇 |
2004年 | 15篇 |
2003年 | 15篇 |
2002年 | 8篇 |
2001年 | 6篇 |
2000年 | 6篇 |
1999年 | 9篇 |
1998年 | 7篇 |
1997年 | 2篇 |
1996年 | 5篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1987年 | 4篇 |
1986年 | 6篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 7篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1972年 | 1篇 |
1969年 | 1篇 |
1968年 | 1篇 |
排序方式: 共有287条查询结果,搜索用时 203 毫秒
1.
Kiyoshi Mochizuki 《Journal of Mathematical Analysis and Applications》2007,326(1):582-588
We show that the energy of solutions to the initial boundary value problem for the wave equation in exterior domains with a dissipation which is localized only near infinity tends to zero as the time goes to infinity. We do not make any geometrical condition like star-shapedness on the boundary. 相似文献
2.
Nishida H Miyazaki Y Kitamura Y Ohashi M Matsusue T Okamoto A Hosaka Y Ohnishi S Mochizuki H 《Chemical & pharmaceutical bulletin》2001,49(10):1237-1244
Intravascular clot formation is an important factor in a number of cardiovascular diseases. Therefore, the prevention of blood coagulation has become a major target for new therapeutic agents. One attractive approach is the inhibition of factor Xa (FXa), which is a key enzyme in coagulation cascade responsible for the generation of thrombin by limited proteolysis of its zymogen, prothrombin. We have investigated 1-arylsulfonyl-3-piperazinone derivatives, containing a 4-(piperidino)pyridine group in place of guanidino and/or amidino groups, and discovered compound M55113 (30a: 4-[(6-Chloro-2-naphthalenyl)sulfonyl]-1-[[1-(4-pyridinyl)-4-piperidinyl]methyl]piperazinone), as a potent inhibitor of FXa (IC50=0.06 microM) with high selectivity for FXa over trypsin and thrombin. 相似文献
3.
Nakanishi I Miyazaki K Shimada T Iizuka Y Inami K Mochizuki M Urano S Okuda H Ozawa T Fukuzumi S Ikota N Fukuhara K 《Organic & biomolecular chemistry》2003,1(22):4085-4088
Electron-transfer reduction of molecular oxygen (O2) by the phenolate anion (1-) of a vitamin E model, 2,2,5,7,8-pentamethylchroman-6-ol (1H), occurred to produce superoxide anion, which could be directly detected by a low-temperature EPR measurement. The rate of electron transfer from 1- to O2 was relatively slow, since this process is energetically unfavourable. The one-electron oxidation potential of 1- determined by cyclic voltammetric measurements is sufficiently negative to reduce 2,2-bis(4-tert-octylphenyl)-1-picrylhydrazyl radical (DOPPH*) to the corresponding one-electron reduced anion, DOPPH-, suggesting that 1- can also act as an efficient radical scavenger. 相似文献
4.
Dialkoxydichlorosilanes ((RO)2SiCl2, R = alkyl) react almost completely with interlayer silanol groups in a layered silicate octosilicate to create a new crystalline silicate structure consisting of new five-membered rings arranged regularly on both sides of the silicate layers. The introduction of dialkoxysilyl groups to the interlamellar region of layered silicates with regular reaction sites provides a new methodology for the design and construction of novel crystalline silicate frameworks by a soft chemical route. 相似文献
5.
A method is described for determination of the steroidal saponin, eruboside B, originating in garlic and garlic products as the p-nitrobenzoyl chloride (PNBC) derivative by reversed-phase liquid chromatography (with ultraviolet detection at 260 nm. Proto-eruboside B was extracted from garlic (Allium sativum L.); subjected to solid-phase extraction (SPE) with a C18 cartridge, Florisil column chromatography, and silica gel column chromatography; and then enzymatically converted to eruboside B, which was applied as an external standard. Steroidal saponins in garlic and commercial garlic products were extracted with methanol and purified by SPE cartridges, followed by enzymatic treatment. A frostanol saponin such as proto-eruboside B is enzymatically transformed to a spirostanol saponin, eruboside B. After the derivatization with PNBC, the saponin derivative was chromatographed on a C8 column with a gradient elution of (A) 80% aqueous acetonitrile and (B) 100% acetonitrile. The detection limit of the developed method was 1 microg/g for the samples. The method was applied to the analysis of garlic and garlic health food products available in Japan. 相似文献
6.
Fukuji Higashi Michihide Ozawa Akihiko Mochizuki 《Journal of polymer science. Part A, Polymer chemistry》1986,24(4):637-643
The reaction promoted by diphenyl chlorophosphate (DPCP) in pyridine was successfully applied to the preparation of soluble aromatic copolyesteramides of high molecular weights directly from aromatic dicarboxylic acids, bisphenols, and a wide range of mol % aromatic diamines. Dropwise addition of a mixture of bisphenols and diamines (more favorably of bisphenols and then diamines) to the mixture of dicarboxylic acids activated by DPCP led the reactions homogeneously even with high mol % of diamines to produce copolymers of good solubility. This improved copolymer solubility was roughly estimated by sequence distribution of polyamide and polyester units in the copolymers, which was studied in a model reaction and in the copolycondensations by simultaneous and stepwise addition of bisphenols and diamines. 相似文献
7.
The photoluminescence (PL) properties of ZrO2 have been measured at different temperatures between 7 and 300 K, using various kinds of ZrO2 specimens: bulk crystal melt-grown by a large solar furnace, thermally oxidized zirconium plate (ZrO2 film crystal on Zr ) and nanocrystals (surface area: 35–45m2/g, diameter: 20–30 nm). The results clarify the deep and shallow energy level structures in the energy gap. Reversible UV-laser-light-induced spectral changes are observed for all of the specimens in different specimen-atmospheres (vacuum and O2 gas). The results elucidate the defect-effects of the PL properties and the PL enhancement mechanism in ZrO2 nanocrystals. 相似文献
8.
The effect of metal ions on the conformation of thymine-containing poly-D-lysine was studied by CD spectra in aqueous solution. Of the metal ions studied, only copper(II) ion affected the conformation of nucleic acid analogs. Copper(II) ion also affected the specifically interacting system made up of thymine-containing poly-D-lysine and polyadenylic acid. 相似文献
9.
Ikuya Tagawa Yosuke UrakamiMaki Maeda Youji MaruyamaKazue Kudo Hiromi ShiinaMasafumi Mochizuki 《Journal of magnetism and magnetic materials》2012,324(3):327-329
To make the write-field much stronger with sharper cross-track field gradient in Shingled perpendicular Magnetic Recording (SMR), we have successfully developed asymmetric SMR heads with one-side shield design. Using these heads, higher track density capability on the shielded-side was demonstrated, which came from narrower erase-band width at shielded side. 相似文献
10.
Yuko Mochizuki Shinsuke Inagaki Mayu Suzuki Jun Zhe Min Koichi Inoue Kenichiro Todoroki Toshimasa Toyo'oka 《Journal of separation science》2013,36(12):1883-1889
A novel bromoquinolinium reagent, i.e. 1‐(3‐aminopropyl)‐3‐bromoquinolinium bromide (APBQ), was synthesized for the analysis of carboxylic acids. A simple and practical precolumn derivatization procedure using the APBQ in RP chromatography and MS (HPLC‐MS) has been developed using bile acids and free fatty acids, as the representative carboxylic acids in biological samples. The APBQ efficiently reacted with carboxylic acids at 60°C for 60 min in the presence of N,N‐dicyclohexylcarbodiimide and pyridine as the activation reagents. Because the APBQ possesses a bromine atom in the structure, the identification of a series of carboxylic acids was easily achieved due to the characteristic bromine isotope pattern in the mass spectra. The APBQ also has a quaternary amine structure, thus the positively charged derivatives are predominate for the highly sensitive detection of carboxylic acids. The APBQ was successfully applied to the selective determination of biological carboxylic acids in human plasma. The bile acids (chenodeoxycholic acid and deoxycholic acid) and several saturated (stearic acid and palmitic acid) and unsaturated free fatty acids (oleic acid and linoleic acid) were reasonably determined by HPLC‐MS under the proposed procedure. Based on the results of analyses of human plasma and saliva, the proposed procedure using APBQ seems to be applicable for the qualitative and quantitative analyses of a series of carboxylic acids in biological samples. 相似文献