全文获取类型
收费全文 | 1308篇 |
免费 | 51篇 |
国内免费 | 3篇 |
专业分类
化学 | 968篇 |
晶体学 | 9篇 |
力学 | 27篇 |
数学 | 145篇 |
物理学 | 213篇 |
出版年
2023年 | 9篇 |
2022年 | 28篇 |
2021年 | 21篇 |
2020年 | 37篇 |
2019年 | 41篇 |
2018年 | 25篇 |
2017年 | 25篇 |
2016年 | 46篇 |
2015年 | 36篇 |
2014年 | 32篇 |
2013年 | 53篇 |
2012年 | 112篇 |
2011年 | 108篇 |
2010年 | 52篇 |
2009年 | 45篇 |
2008年 | 73篇 |
2007年 | 70篇 |
2006年 | 65篇 |
2005年 | 62篇 |
2004年 | 41篇 |
2003年 | 35篇 |
2002年 | 23篇 |
2001年 | 14篇 |
2000年 | 13篇 |
1999年 | 14篇 |
1998年 | 7篇 |
1997年 | 19篇 |
1996年 | 12篇 |
1995年 | 8篇 |
1994年 | 10篇 |
1993年 | 14篇 |
1992年 | 11篇 |
1991年 | 9篇 |
1990年 | 7篇 |
1989年 | 7篇 |
1988年 | 13篇 |
1986年 | 8篇 |
1984年 | 9篇 |
1983年 | 8篇 |
1982年 | 7篇 |
1981年 | 10篇 |
1980年 | 9篇 |
1979年 | 7篇 |
1976年 | 10篇 |
1975年 | 7篇 |
1974年 | 12篇 |
1973年 | 13篇 |
1969年 | 7篇 |
1968年 | 6篇 |
1960年 | 6篇 |
排序方式: 共有1362条查询结果,搜索用时 15 毫秒
1.
2.
Daria E. Lonsdale Geoffrey Johnston‐Hall Amanda Fawcett Craig A. Bell Carl N. Urbani Michael R. Whittaker Michael J. Monteiro 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3620-3625
In this work, we propose that retardation in vinyl acetate polymerization rate in the presence of toluene is due to degradative chain transfer. The transfer constant to toluene (Ctrs) determined using the Mayo method is equal to 3.8 × 10?3, which is remarkably similar to the value calculated from the rate data, assuming degradative chain transfer (2.7 × 10?3). Simulations, including chain‐length‐dependent termination, were carried out to compare our degradative chain transfer model with experimental results. The conversion–time profiles showed excellent agreement between experiment and simulation. Good agreement was found for the Mn data as a function of conversion. The experimental and simulation data strongly support the postulate that degradative chain transfer is the dominant kinetic mechanism. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3620–3625, 2007 相似文献
3.
Amanda J. Ziegler Craig C. McLauchlan Cyndi R. Sosnowski Albert W. Herlinger 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(2):o132-o134
The title compound (H2DTMSP[EBP]), C14H36O6P2Si2, was crystallized by the slow evaporation of a solution in a 20:1 mixture of pentane and acetone. The H2DTMSP[EBP] molecule lies about an inversion center. In the solid state, the molecule exists in an anti configuration, with the molecular backbone C—C bond located on an inversion center. The compound exists in the solid state as hydrogen‐bonded infinite sheets in the ab plane, unlike the methylene analogue, which exists as hydrogen‐bonded infinite chains, demonstrating an `even–odd' effect of the length of the backbone alkyl chain. 相似文献
4.
Haes AJ Zhao J Zou S Own CS Marks LD Schatz GC Van Duyne RP 《The journal of physical chemistry. B》2005,109(22):11158-11162
A novel method to produce solution-phase triangular silver nanoparticles is presented. Ag nanoparticles are prepared by nanosphere lithography and are subsequently released into solution. The resulting nanoparticles are asymmetrically functionalized to produce either single isolated nanoparticles or dimer pairs. The structural and optical properties of Ag nanoparticles have been characterized. Mie theory and the Discrete Dipole Approximation method (DDA) have been used to model and interpret the optical properties of the released Ag nanoparticles. 相似文献
5.
E. M. Araújo Renata Barbosa Amanda D. Oliveira Crislene R. S. Morais T. J. A. deMélo A. G. Souza 《Journal of Thermal Analysis and Calorimetry》2007,87(3):811-814
Polyethylene/montmorillonite clay nanocomposites were obtained via direct
melt intercalation. The clay was organically modified with four different
types of quaternary ammonium salts. The objective of this work is to study
the use of montmorillonite clay in the production of nanocomposites by means
on rheological, mechanical and crystallization properties of nanocomposites
and to compare to the properties of the matrix and PE/unmodified clay nanocomposites.
In general, the tensile test showed that the yield strength and modulus of
the nanocomposites are close to the pure PE. Apparently, the mixture with
Dodigen salt seems to be more stable than the pure PE and PE/unmodified clay. 相似文献
6.
D. Gardner 《Analytica chimica acta》1980,119(1):167-169
The method developed earlier was found to suffer a loss in sensitivity when the magnesium perchlorate desiccant became damp. The most sensitive and consistent results were obtained when the magnesium perchlorate was removed from the sample injection manifold. Under most circumstances a desiccant is not required. 相似文献
7.
8.
Frabetti PL Cheung HW Cumalat JP Dallapiccola C Ginkel JF Greene SV Johns WE Nehring MS Butler JN Cihangir S Gaines I Garbincius PH Garren L Gourlay SA Harding DJ Kasper P Kreymer A Lebrun P Shukla S Bianco S Fabbri FL Sarwar S Zallo A Culbertson R Gardner RW Greene R Wiss J Alimonti G Bellini G Caccianiga B Cinquini L Di Corato M Giammarchi M Inzani P Leveraro F Malvezzi S Menasce D Meroni E Moroni L Pedrini D Perasso L Sala A Sala S Torretta D Vittone M Buchholz D Claes D Gobbi B O'Reilly B 《Physical review letters》1993,71(6):827-830
9.
Frabetti PL Cheung HW Cumalat JP Dallapiccola C Ginkel JF Greene SV Johns WE Nehring MS Butler JN Cihangir S Gaines I Garren L Garbincius PH Gourlay SA Harding DJ Kasper P Kreymer A Lebrun P Shukla S Bianco S Fabbri FL Sarwar S Zallo A Culbertson R Gardner RW Greene R Wiss J Alimonti G Bellini G Caccianiga B Cinquini L Di Corato M Giammarchi M Inzani P Leveraro F Malvezzi S Menasce D Meroni E Moroni L Pedrini D Perasso L Sala A Sala S Torreta D Vittone M Buchholz D Claes D Gobbi B O'Reilly B 《Physical review letters》1993,70(14):2058-2061
10.
Frabetti PL Cheung HW Cumalat JP Dallapiccola C Ginkel JF Greene SV Johns WE Nehring MS Butler JN Cihangir S Gaines I Garren L Garbincius PH Gourlay SA Harding DJ Kasper P Kreymer A Lebrun P Shukla S Bianco S Fabbri FL Sarwar S Zallo A Culbertson R Gardner RW Greene R Wiss J Alimonti G Bellini G Caccianiga B Cinquini L Di Corato M Giammarchi M Inzani P Leveraro F Malvezzi S Menasce D Meroni E Moroni L Pedrini D Perasso L Sala A Sala S Torretta D Vittone M Buchholz D Claes D Gobbi B O'Reilly B 《Physical review letters》1993,70(10):1381-1384