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排序方式: 共有298条查询结果,搜索用时 15 毫秒
1.
Alwin Schleicher 《Fresenius' Journal of Analytical Chemistry》1956,151(6):413-415
Zusammenfassung Es wird gezeigt, daß die Erscheinung der Polarisation bei elektroanalytischen Fällungen, sei es durch äußere oder durch innere Stromzufuhr, als eine Selbstinduktion angesehen werden kann. Sie ist auf Verzögerungen, Hemmungen oder innere Widerstände der primären gegenseitigen Induktion zurückzuführen. 相似文献
2.
Shoeib T Cunje A Hopkinson AC Siu KW 《Journal of the American Society for Mass Spectrometry》2002,13(4):408-416
Collision-induced dissociation experiments on the Ag+-phenylalanine complex using several collision energies were shown to yield ten different fragment ions. Unambiguous assignment of these fragment ions were made by careful analysis of deuterium labeling experiments. The losses of H2O, CO, CO2, and AgH were commonly observed; also encountered were the losses of H2, Ag, and H. Deuterium labeling experiments and density functional calculations have been employed to probe fragmentation mechanisms that account for all experimental results. 相似文献
3.
A. Schleicher 《Fresenius' Journal of Analytical Chemistry》1955,146(5):375
Ohne Zusammenfassung 相似文献
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Surup F Wagner O von Frieling J Schleicher M Oess S Müller P Grond S 《The Journal of organic chemistry》2007,72(14):5085-5090
The iromycins A-D are members of a new family of rare alpha-pyridone metabolites. The isolation and structure elucidation of these microbial secondary metabolites from Streptomyces sp. Dra 17 revealed a N-heterocyclic core structure with two unusual side chains. Iromycins act as inhibitors of nitric oxide synthases (NOS), a protein family, which produces the crucial second messenger nitric oxide (NO). Importantly, these compounds inhibit selectively endothelial NOS rather than neuronal NOS and thus set prospects for both medical therapy and basic research. Feeding experiments with 13C- and 15N -labeled precursors indicated an uncommon type of polyketide biosynthesis and clearly ruled out an isoprenoid origin. A detoxification pathway of a particular secondary metabolite in the host strain is a rare observation and here we demonstrate it with the iromycin family. 相似文献
7.
Alwin Walther 《Monatshefte für Mathematik》1933,40(1):444-457
Ohne Zusammenfassung 相似文献
8.
Lehmann R Huber M Beck A Schindera T Rinkler T Houdali B Weigert C Häring HU Voelter W Schleicher ED 《Electrophoresis》2000,21(14):3010-3015
The aim of this study was to develop and evaluate a capillary zone electrophoretic (CE) procedure for the accurate quantification of the UDP-hexosamines as well as for the corresponding UDP-hexoses in samples from various biological origins. Testing different buffer conditions, voltages, capillary dimensions and temperatures, optimal results were achieved with a 90 mM borate buffer, pH 9.0, at 18 degrees C and 15.5 kV in an uncoated fused-silica capillary of 50 cm x 50 microm and a detection wavelength of lambda = 262 nm. The total procedure, i.e., including variations of the sample preparation, showed coefficients of variation for the peak areas between 4. 1% and 10.4% in mesangial cells (n = 7) and between 7.8 and 10.3% (n = 6) in leukocytes for the components of interest. To improve precision, an internal standard was used for calibration. The limit of detection for all compounds is an absolute amount of 180 fmol, sufficient for the precise analysis of UDP-sugars in a limited amount of biological samples, such as human leukocytes (obtained from a 10 mL blood sample), muscle biopsies (< or = 100 mg), and mesangial kidney cells (ca. 2.5 x 10(5) cells). This reproducible, quantitative analysis of all four UDP-sugars from various biomedically relevant origins by CZE is a definite improvement over the generally used high performance liquid chromatography (HPLC) procedures. The CZE method allows the study of the flux through the hexosamine pathway in diabetes mellitus and other diseases in a simple, quantitative and accurate way. 相似文献
9.
Alwin S. Wheeler 《Fresenius' Journal of Analytical Chemistry》1909,48(11):712
Ohne Zusammenfassung 相似文献
10.
Solid state N.M.R. relaxation study of liquid crystal polymers employing a two dimensional technique
Molecular motions of liquid crystal polymers in the solid state cover a broad dynamic range, extending from the fast rotational to the ultra slow motional regime. Two dimensional N.M.R. relaxation spectroscopy is designed to follow these motions and to differentiate the various motional modes. In addition, different types of molecular order, modulated by these regions, are also discriminated. The solid state dynamics of the polyesters studied depends sensitively upon their thermal history. Annealed samples show a typical semicrystalline behaviour, manifested by two different motional components. The molecular order is characterized by a high degree of conformational and orientational order of the polymer chains, which is strongly correlated with the exceptional mechanical properties of these systems. 相似文献