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排序方式: 共有1227条查询结果,搜索用时 15 毫秒
1.
Palladium-containing zeolites catalyze the cycloisomerization of diethyl diallylmalonate to dimethylcyclopentenes. When the reaction is carried out in toluene, the performance of the palladium catalyst depends on the pore size of the zeolites. At 60 °C, palladium adsorbed on large pore size Beta zeolite (pore size ∼7.4 Å) is more active than medium pore size ZSM-5 (pore size ∼5.4 Å). This lower activity of ZSM-5 compared to Beta is attributable to the restricted diffusion of reagent and products through the ZSM-5 channels as compared to Beta zeolite. However, due to the gas-like diffusion characteristic of the supercritical state, the activity of ZSM-5 increases and becomes identical to that of Beta zeolite using supercritical CO2 as medium. 相似文献
2.
Alvaro Carrillo Ravi S. Kane 《Journal of polymer science. Part A, Polymer chemistry》2004,42(13):3352-3359
This article describes the formation and characterization of self‐assembled nanoparticles of controlled sizes based on amphiphilic block copolymers synthesized by ring‐opening metathesis polymerization. We synthesized a novel hydrophobic derivative of norbornene; this monomer could be polymerized using Grubbs' catalyst [Cl2Ru(CHPh)(PCy3)2] forming polymers of controlled molecular weight. We synthesized amphiphilic block copolymers of controlled composition and showed that they assemble into nanoparticles of controlled size. The nanoparticles were characterized using dynamic light scattering and transmission electron microscopy. Tuning the composition of the block copolymer enables the tuning of the diameters of the nanoparticles in the 30‐ to 80‐nm range. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3352–3359, 2004 相似文献
3.
The magnetic properties of existing amorphous iron based materials, i.e., Fe--metalloid, Fe--early transition metals and Fe--rare
earth alloys, are briefly discussed for some representative alloys. The spin orientation of amorphous Fe--metalloid alloys
has been determined by the angular dependence of hyperfine interactions. It is shown that in iron--early transition metals
ferromagnetic order is not long-ranged, but determined by magnetic clusters. The magnetic hyperfine field distributions of
Fe-rich iron--early transition metals consist of a high and a low field tail. The magnetic structure has been investigated
for two representative Fe--RE (RE = Er, Ce) amorphous alloys. For the first time, the magnetic coupling phenomenon in amorphous/crystalline
multilayers has been discussed.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
4.
A. Sánchez-Lavega A. Salazar A. Ocariz L. Pottier E. Gomez L.M. Villar E. Macho 《Applied Physics A: Materials Science & Processing》1997,65(1):15-22
Received: 16 September 1996/Accepted: 6 January 1997 相似文献
5.
Alvaro P. Raposo Hans J. Weber David E. Alvarez-Castillo Mariana Kirchbach 《Central European Journal of Physics》2007,5(3):253-284
We briefly review the five possible real polynomial solutions of hypergeometric differential equations. Three of them are
the well known classical orthogonal polynomials, but the other two are different with respect to their orthogonality properties.
We then focus on the family of polynomials which exhibits a finite orthogonality. This family, to be referred to as the Romanovski
polynomials, is required in exact solutions of several physics problems ranging from quantum mechanics and quark physics to
random matrix theory. It appears timely to draw attention to it by the present study. Our survey also includes several new
observations on the orthogonality properties of the Romanovski polynomials and new developments from their Rodrigues formula. 相似文献
6.
This study demonstrates the separation of active ingredients in acne formulations (salicylic acid, cloramphenicol and resorcinol in presence of azulene) by capillary zone electrophoresis. Factors affecting their separations were the buffer pH and concentration, applied voltage, sample preparation, and presence of additives. Optimun results were obtained with a 50 mM sodium tetraborate-50 mM sodium phosphate, pH 9.0. The carrier electrolyte gave baseline separation with good resolution, short migration times (<6 min), great reproducibility and accuracy. Calibration plots were linear over at least three orders of magnitude of analyte concentrations, the lower limits of detection being within the range 0.39-1.25 μg ml−1. The procedure was fast and reliable and commercial pharmaceuticals could be analysed without prior sample clean-up procedure. 相似文献
7.
Summary Measurements on sea surface films were conducted during five separate experimental periods in the following marine areas:
the Sicilian Channel, the Gulf of Maine (spring and fall periods), Bermuda, and the Pacific Ocean West of Southern California.
The measurements consisted in surface elevation sampling using an interferential microwave probe with frequency spectra evaluation.
Wave spectra were performed for both clean and film-covered sea surface conditions to determine the wave attenuation ratio
within the 2–20 Hz spectral range. The method is able to detect, chart and characterize sea surface films. Theoretical analyses
of the results yield several viscoelastic film parameters: the modulus of elasticity, the relaxation frequency and the maximum
of the damping ratio as a function of wave frequency. The analysed data are interpreted to infer film weathering effects,
surface concentration of film-forming constituents, and compactness of the organic sea surface film. 相似文献
8.
Soderstrom E McKenna JA Abrams GS Adolphsen CE Averill D Ballam J Barish BC Barklow T Barnett BA Bartelt J Bethke S Blockus D Bonvicini G Boyarski A Brabson B Breakstone A Bulos F Burchat PR Burke DL Cence RJ Chapman J Chmeissani M Cords D Coupal DP Dauncey P DeStaebler HC Dorfan DE Dorfan JM Drewer DC Elia R Feldman GJ Fernandes D Field RC Ford WT Fordham C Frey R Fujino D Gan KK Gero E Gidal G Glanzman T Goldhaber G Gomez Cadenas JJ Gratta G Grindhammer G Grosse-Wiesmann P Hanson G Harr R 《Physical review letters》1990,64(25):2980-2983
9.
Komamiya S Abrams GS Adolphsen CE Averill D Ballam J Barish BC Barklow T Barnett BA Bartelt J Bethke S Blockus D Bonvicini G Boyarski A Brabson B Breakstone A Bulos F Burchat PR Burke DL Cence RJ Chapman J Chmeissani M Cords D Coupal DP Dauncey P DeStaebler HC Dorfan DE Dorfan JM Drewer DC Elia R Feldman GJ Fernandes D Field RC Ford WT Fordham C Frey R Fujino D Gan KK Gatto C Gero E Gidal G Glanzman T Goldhaber G Gomez Cadenas JJ Gratta G Grindhammer G Grosse-Wiesmann P Hanson G Harr R 《Physical review letters》1990,64(24):2881-2884
10.
Stewart C Zieminski A Blessing S Crittenden R Draper P Dzierba A Heinz R Krider J Marshall T Martin J Sambamurti A Smith P Sulanke T Gomez R Dauwe L Haggerty H Malamud E Nikolic M Hagopian S Abrams R Ares J Goldberg H Halliwell C Margulies S McLeod D Salminen A Solomon J Wu G Ellsworth R Goodman J Gupta S Yodh G Watts T Abramov V Antipov Y Baldin B Denisov S Glebov V Gorin Y Kryshkin V Petrukhin A Polovnikov S Sulyaev R 《Physical review D: Particles and fields》1990,42(5):1385-1395