全文获取类型
收费全文 | 798篇 |
免费 | 26篇 |
专业分类
化学 | 454篇 |
晶体学 | 17篇 |
力学 | 36篇 |
数学 | 56篇 |
物理学 | 261篇 |
出版年
2023年 | 11篇 |
2022年 | 28篇 |
2021年 | 18篇 |
2020年 | 26篇 |
2019年 | 18篇 |
2018年 | 24篇 |
2017年 | 29篇 |
2016年 | 34篇 |
2015年 | 11篇 |
2014年 | 35篇 |
2013年 | 88篇 |
2012年 | 60篇 |
2011年 | 43篇 |
2010年 | 51篇 |
2009年 | 40篇 |
2008年 | 32篇 |
2007年 | 42篇 |
2006年 | 27篇 |
2005年 | 17篇 |
2004年 | 21篇 |
2003年 | 9篇 |
2002年 | 10篇 |
1999年 | 3篇 |
1998年 | 7篇 |
1997年 | 5篇 |
1995年 | 4篇 |
1994年 | 4篇 |
1993年 | 17篇 |
1992年 | 10篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1987年 | 5篇 |
1986年 | 3篇 |
1985年 | 3篇 |
1984年 | 6篇 |
1983年 | 4篇 |
1982年 | 6篇 |
1981年 | 4篇 |
1980年 | 6篇 |
1979年 | 9篇 |
1978年 | 6篇 |
1976年 | 6篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 4篇 |
1972年 | 2篇 |
1971年 | 2篇 |
1970年 | 2篇 |
1967年 | 3篇 |
1962年 | 2篇 |
排序方式: 共有824条查询结果,搜索用时 0 毫秒
1.
Spectral data during a chelatometric titration were utilized for determining an equivalence point of the titration. Three-dimensional titration data were analyzed by fitting to a theoretical equation that was derived from equilibrium equations among a metal ion, an indicator and EDTA. The equation with optimized parameters successfully explained the three-dimensional titration data. This method was applied to EDTA titration systems of zinc, cadmium and lead with xylenol orange (XO) as an indicator. These systems were analyzed while taking the formation of 1:1 and 2:1 metal-indicator complexes into account. By this method, an accurate equivalence point was determined as well as stability constants and molar absorption spectra of metal-indicator complexes in each titration system. Moreover, the comparability among the concentrations of the metal standard solutions prepared from pure metals (Zn, Pb, and Cd) was also confirmed by the proposed evaluation method. 相似文献
2.
S. C. Tiwari 《Foundations of Physics Letters》2006,19(1):51-62
Advances in gauge theories and unified theories have not thrown light on the meaning of electron. The problem of the origin
of electronic charge is made precise, new insights gained from Weyl space are summarized, and the origin of charge in terms
of fractional spin is suggested. A new perspective on the abelian Chern-Simons theory is presented to explain charge. 相似文献
3.
4.
The analytical potential of water as an eluent in thin layer chromatographic separation of various anions on plain adsorbent layers (silica gel "G" alumina, and cellulose) as well as on beds containing different combinations of silica gel, alumina, or cellulose has been investigated. In addition to some important separation of anions, microgram separation of IO−4 from milligram quantities of IO−3, Bro−3, MoO2−4, and Fe (CN)3−6 has been realized. The effect on pH of the sample in the separation of IO−4 from accompanying ions has also been studied. The limits of detection and dilution limits of anions on alumina thin layers have been determined. NO−2 in artificial seawater has been detected. The effect of CaCl2, MgCl2, and NaHCO3 on some ternary separations of analytical importance has been examined. 相似文献
5.
Kishore K Tiwari Girdhar L Mundhara Manish K Rai Vinay K Gupta 《Analytical sciences》2006,22(2):259-262
The results of a study and application of leucocrystal violet for the determination of antimony in parts per million levels is described here. The proposed method is based on the reaction of antimony(III) with acidified potassium iodate to liberate iodine. The liberated iodine selectively oxidizes leucocrystal violet to crystal violet dye. The formed dye shows maximum absorbance at 590 nm. The color system obeys Beer's law in the concentration range from 0.4 - 3.6 microg antimony per 25 ml of final solution. The molar absorptivity and Sandell's sensitivity were found to be 7.32 x 10(5) l mol(-1) cm(-1) and 0.0016 microg cm(-2), respectively. All variables were studied in order to optimize the reaction. The proposed method is satisfactorily applicable for the analysis of antimony in various environmental and biological samples. The method is simple, highly sensitive, accurate and reliable. 相似文献
6.
Trituration and capillary solid-state spot-tests for 25 anions with a number of organic and inorganic reagents have been examined. A comparative study of the corresponding reactions in solution has also been made. Incorporation of a glass-wool plug in the capillary improves the selectivity. Schemes are presented for possible use of the technique. 相似文献
7.
JPC – Journal of Planar Chromatography – Modern TLC - Optimization of the separation and identification of heavy metals present in cotton material has been performed by... 相似文献
8.
J. S. Shukla R. K. Tiwari 《Journal of polymer science. Part A, Polymer chemistry》1981,19(6):1517-1524
The aqueous polymerization of methacrylamide (I) initiated by KBrO3–thioglycolic acid (TGA) has been studied at 30 ± 0.2°C in nitrogen. The rate is given by K[M]1.19 [thioglycolic acid]1 [KBrO3]0.53 for 10–15% conversion. Activation energy was found to be 53.96 kJ/mole (12.92 kcal/mole) in the investigated range of temperature 30–45°C. The role of addition of a series of aliphatic alcohols and some salts was also determined. The kinetics of polymerization was followed iodometrically. 相似文献
9.
Summary Copper(II) forms a stable colourless complex with thiourea. This property has been utilized to develop a Spectrophotometric method for the determination ofg quantities of thiourea. The complex absorbs in ultraviolet region and the determinations are carried out at 250 nm. The method permits the determination of thiourea from 10–60g with error not exceeding ± 1.0%.
Zusammenfassung Kupfer(II) bildet mit Thioharnstoff eine farblosa Komplexverbindung, die sich auf Grund ihrer Absorption bei 250 nm zur spektrophotometrischen Bestimmung von Mikrogrammengen Thioharnstoff eignet. 10 bis 60g Thioharnstoff lassen sieh mit einem Fehler von höchstens ± 1,0% bestimmen.相似文献
10.
Devendra Kumar Uday Razdan Alka D. Gupta 《Journal of polymer science. Part A, Polymer chemistry》1993,31(3):797-804
Heat-resistant polymers which are processable into void-free components and suitable for composite applications have been synthesized by thermal/chemical polymerization of four newly developed bisimido-bisphthalonitriles containing silicon, ether, carbonyl, and hexafluoroisopropylidene groups. Thermal polymerization involving addition reactions was performed at 200–275°C for 2–10 h and then post-curing at 310°C for 10 h. Polymers VI, VII, VIII , and IX were obtained. The thermal polymerization was monitored using infrared spectroscopy. Thermal polymerization was also carried out in the presence of an aromatic diamine. A polyhexasocyclane ( V ) was synthesized by condensation polymerization of ether containing bisimido-bisphthalonitrile with 4,4′-diaminodiphenyl ether in solvent phenol. The synthesized polymers were evaluated for thermal stability using dynamic thermogravimetric analysis (TGA). Polymers VII, VIII, IX , and X showed thermal decomposition temperature in the range of 475–500°C in nitrogen and air atmosphere. The char yield of the polymers was in the range of 60–69% in nitrogen at 800°C. This study indicated that synthesized thermosetting polymers from ether and keto containing bisimido-bisphthalo-nitrile are potential candidates for development of graphite composites. © 1993 John Wiley & Sons, Inc. 相似文献