Dynamics and spectra of excited states of water-micellar suspensions of single-walled carbon nanotubes

The dynamics of the photoinduced differential absorption and excited-state bleaching spectra of single-walled carbon nanotubes suspended in a micellar solution were studied in the spectral range from 40 to 1000 nm within a time interval from 70 fs to 150 ps under excitation by 50-fs pulses with photon energies 2 and 4 eV. The bleaching and absorption bands were observed in the spectra; the positions of the bleaching peaks were independent of the photon energy of the exciting femtosecond pulse in the range 2–4 eV. It was established that, for delay times shorter than 1 ps, the shape of the differential spectrum of excited nanotubes coincided with the shape of the second derivative of the absorption spectrum of unexcited nanotubes in the frequency range of exciting pulse above 18000 cm^?1 (the range of absorption bands of metallic nanotubes). In the frequency range below 16000 cm^?1 (the range of absorption peaks of semiconducting nanotubes), the bleaching peaks in the differential spectrum of excited nanotubes undergo a high-frequency shift of 200–300 cm^?1 with respect to the second-derivative spectrum of unexcited nanotubes. The excited-state relaxation rate constants were measured. They are well approximated by the exponential dependences and depend on the probe-pulse wavelength. An assumption was made about the nature of the observed spectra of excited nanotubes and about the excitation relaxation.     

Comparative study of holographic recording in cholesteric and nematic azo-containing side-chain polymers

For the first time a comparative study of holographic recording in planarly oriented films of nematic and cholesteric azobenzene-containing polymers was performed. The influence of temperature and light intensity on the values of diffraction efficiencies of holographic gratings was investigated. The kinetics of grating relaxation at different temperatures was studied. It was shown that the helical supramolecular structure of cholesteric copolymer causes a significant decrease of the diffraction efficiency in comparison with the one observed for the nematic state of the homopolymer.     

High-frequency magnetoimpedance in nanocomposites

The transmission of millimeter-range electromagnetic waves (30–50 GHz) through a magnetic nanocomposite thin film exhibiting tunnel magnetoresistance (TMR) is calculated. The relative change of transmission coefficient in an applied magnetic field due to the magnetorefractive effect is approximately linear with TMR and strongly depends on nanocomposite resistivity and film thickness. The obtained results are in a good agreement with experiment.     

Illumination of the shadow zone in a two-channel oceanic waveguide with a fine structure of sound speed inhomogeneities

The experimental data on the sound field structure, which were obtained by emitting a continuous pseudonoise signal (a midfrequency of 3.2 kHz) in a two-channel oceanic waveguide, are compared with the calculations performed by the wave program with allowance for the fine structure of the sound speed inhomogeneities. A considerable increase in the intensity of the sound field with a definite angular spectrum is observed in the upper channel in the first shadow zone, and, in the experiment, the increase begins nearer to the sound source than predicted by the wave and ray calculations for a smooth sound speed profile. These features of the field structure are explained by the illumination of the shadow zone by the regular scattering of signals from highly anisotropic fine-structure inhomogeneities of the sound speed profile, which are clearly pronounced in the region of the given oceanic experiment.     

Crystallographic report: Crystal structure of 1‐bromo‐1′‐[(2S)‐N‐(1‐hydroxy‐3‐methylbutane‐2‐yl)]‐ferroceneamide

For the unsymmetrical title compound, 1‐bromo‐1′‐[(2S)‐N‐(1‐hydroxy‐3‐methylbutane‐2‐yl)]‐ferroceneamide, two independent molecules were found in the asymmetric unit. Copyright © 2003 John Wiley & Sons, Ltd.     

Theory of the singular quantum oscillator

We propose a number of arguments in favor of reevaluating the theory of a quantum oscillator described by the Hamiltonian H=–d²/dx² + 2²x² + x^–2(=2m=1). We propose that functions ₊(x) which continuously reduce to even harmonic oscillator solutions in the 0 limit be taken as the even solutions of the Hamiltonian in the –1/4 < < 3/4 range. In this scheme the problem becomes truly one-dimensional such that even and odd parity energy levels alternate, whereas the usual approach leads to parity degeneracy.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 85–89, October, 1989.