Chlorination of aromatic substrates catalyzed by the phthalocyanine complexes

The chlorination of benzene, toluene, and o-xylene with molecular chlorine in the presence of the phthalocyanine complexes of different structures was studied. The transformations of the catalysts during the reaction were investigated. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1644–1647, August, 2008.     

Prognostication of aging of polymeric composite materials

Experimental data demonstrate that a study of accelerated aging can enable prognostication of the working capacity and storage life of polymeric formulations used in aircraft components on the basis of changes in thermogravimetric constants of these polymeric formulations.     

Attracting cycles of maps of an interval generating periodic solutions of a differential-difference equation

Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 41, No. 8, pp. 1054–1058, August, 1989.     

Modification of multiwalled carbon nanotubes by carboxy groups and determination of the degree of functionalization

Multiwalled carbon nanotubes were modified by carboxy groups. Four independent methods for the determination of the degree of functionalization of the surface were proposed: ¹³C NMR spectroscopy, thermogravimetry, titrimetry, and fluorimetry. The first two methods show the total content of carboxy groups in the sample, and the latter two methods give information about the content of the surface groups only. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 291–295, February, 2008.     

Optical Magnus effect in metamaterials fabricated from ferromagnetic microwires

In homogeneous negative phase velocity media, the Doppler and Cherenkov-Vavilov effects and the refraction and pressure of light are anomalous: they are inverse with respect to the corresponding effects in conventional media. Using the geometrical optics approximation, it is shown that the optical Magnus effect in inhomogeneous negative phase velocity media is also anomalous. The effect is demonstrated by considering a metamaterial consisting of parallel amorphous ferromagnetic microwires in a magnetic field. The metamaterial proves to be a left-handed one in the realistic region of the electromagnetic spectrum. The optical properties of such a left-handed medium can be controlled by the external magnetic field.     

Diffractive vector meson production at HERA: From soft to hard QCD

Experimental results from HERA on diffractive vector meson production and their theoretical interpretation within microscopic QCD are reviewed with an emphasis on the BFKL color dipole and k _T -factorization approaches. The text was submitted by the authors in English.     

Generation of H− ions in a low-pressure xenon-hydrogen discharge. I

A theory of a low-pressure discharge in a xenon-molecular hydrogen mixture is developed. It is shown that, in such a discharge, at an interelectrode distance of L = 1 cm and a total plasma pressure of p ₀ ～ 1 Torr, the density of negative hydrogen ions produced via the dissociative attachment of thermal electrons to vibrationally excited molecules H₂ can reach a value as high as N_H ^? ≥ 10¹² cm^?3. According to calculations, the electron temperature in discharge operating regimes under study attains T _e ≈ 1?2 eV, which corresponds to the maximum of the e-v exchange rate constant of H₂ molecules. This ensures a relatively high rate of vibrational pumping of H₂ molecules in the discharge.