全文获取类型
收费全文 | 606篇 |
免费 | 5篇 |
国内免费 | 2篇 |
专业分类
化学 | 359篇 |
晶体学 | 4篇 |
力学 | 30篇 |
数学 | 86篇 |
物理学 | 134篇 |
出版年
2023年 | 1篇 |
2022年 | 10篇 |
2021年 | 13篇 |
2020年 | 11篇 |
2019年 | 9篇 |
2018年 | 12篇 |
2017年 | 24篇 |
2016年 | 27篇 |
2015年 | 8篇 |
2014年 | 14篇 |
2013年 | 34篇 |
2012年 | 33篇 |
2011年 | 43篇 |
2010年 | 27篇 |
2009年 | 28篇 |
2008年 | 26篇 |
2007年 | 32篇 |
2006年 | 36篇 |
2005年 | 21篇 |
2004年 | 30篇 |
2003年 | 22篇 |
2002年 | 29篇 |
2001年 | 29篇 |
2000年 | 14篇 |
1999年 | 9篇 |
1998年 | 8篇 |
1997年 | 6篇 |
1996年 | 4篇 |
1995年 | 5篇 |
1993年 | 2篇 |
1992年 | 4篇 |
1991年 | 6篇 |
1990年 | 3篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 6篇 |
1982年 | 1篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1970年 | 1篇 |
1967年 | 1篇 |
1955年 | 3篇 |
1952年 | 1篇 |
排序方式: 共有613条查询结果,搜索用时 15 毫秒
1.
A. P. Tyutnev R. Sh. Ikhsanov E. L. Grin’ G. P. Safonov A. I. Kononenko A. M. Sorokin I. V. Rudenko 《Polymer Science Series A》2006,48(11):1190-1195
A general theory of the phenomenon of recovered voltage in polymers was considered on the basis of representation of an actual poling process by a discrete set of Debye relaxators. Examples of numerical solution of the direct and inverse problems are given. A correlation expression between intentionally aged polymer specimens and recovered-voltage curves was proposed for use in the assessment of the material state of a polymer under actual service conditions. It was shown that it is sufficient to restrict consideration to three relaxation processes in analysis of the phenomenon. 相似文献
2.
We generalize a method for determination of time scales of nonstationary diffusion in a one-dimensional medium. The time of relaxation to a stationary non-equilibrium density of substance in a system with a source, a sink, and an arbitrary potential profile are obtained and studied in detail. A few specific examples are considered. 相似文献
3.
Two series of tensile relaxation tests are performed on natural rubber filled with high abrasion furnace black. To fit observations, constitutive equations are derived for the nonlinear viscoelastic behavior of a particle-reinforced elastomer. A filled rubber is modeled as a composite medium, where inclusions with low concentrations of junctions are randomly distributed in the host matrix. The inclusions are treated as equivalent networks of macromolecules, where strands can separate from temporary junctions as they are thermally agitated. The bulk medium is thought of as a permanent network of chains. Unlike conventional concepts of transient networks, the concentration of strands in inclusions is assumed to be affected by mechanical factors: under active loading, inter-chain interactions weaken and some strands that were prevented from detachment from their junctions in a stress-free compound become free to separate from the junctions in a deformed medium. Unloading strengthens interactions between macromolecules, which results in an increase in the number of permanent strands. By using the laws of thermodynamics, stress–strain relations for a particle-reinforced rubber are developed. Adjustable parameters in the constitutive equations are found by fitting the experimental data. It is demonstrated that mechanical pre-loading and annealing of specimens at an elevated temperature noticeably affect concentrations of inclusions with various activation energies for rearrangement of strands. 相似文献
4.
Aleksey Zinger 《Topology》2004,43(4):793-829
We give a formula computing the number of one-nodal rational curves that pass through an appropriate collection of constraints in a complex projective space. The formula involves intersections of tautological classes on moduli spaces of stable rational maps. We combine the methods and results from three different papers. 相似文献
5.
B. B. Damaskin O. A. Baturina V. A. Safonov N. V. Safonov 《Russian Journal of Electrochemistry》2003,39(6):685-691
Effect of the electrode potential on the coadsorption of two organic substances is studied using a set of two mixed Frumkin isotherms and a model of three parallel capacitors in conditions where in the absence of an electric field this system has seven solutions. It is shown that only four of these solutions may correspond to realizable adsorption states. Effect of the electrode potential on the number of possible solutions of the isotherm set, the number of realizable adsorption states, as well as on the composition and properties of a surface layer is considered. 相似文献
6.
7.
Within the semimicroscopic approach based on the random-phase approximation that takes exactly into account a single-particle continuum and on a phenomenological inclusion of the fragmentation effect, it is proposed to describe the strength functions for charge-exchange giant dipole resonances and cross sections for photoabsorption and for partial “direct + semidirect” (γ, p) reactions in the vicinity of a giant E1 resonance with allowance for the isospin-splitting effect. The results of the calculations performed for some magic and semimagic nuclei without resort to free parameters are compared with available experimental data. 相似文献
8.
Berezkin Victor G. Mardanov Robert G. Moiseew Aleksey A. Malinowska Irena Różyło Jan K. 《平面色谱法杂志一现代薄层色谱法》2002,15(5):377-379
JPC – Journal of Planar Chromatography – Modern TLC - 相似文献
9.
As an adjunct to the regression analysis of differential capacitance curves, which allows refining the adsorption parameters, a program, which takes into account possible errors in volume concentrations of organic substances, is developed. Using this procedure, the earlier data on the differential capacitance of a mercury electrode in aqueous solutions of normal butanol (1-BuOH) containing either 0.1 M NaF or 0.05 and 0.5 M Na2SO4 as the supporting electrolyte are analyzed. This allows obtaining the most accurate values of adsorption parameters for the systems mentioned above within the framework of the model of two parallel capacitors and the Frumkin isotherm. It is shown that, when a linear dependence of the intermolecular interaction parameter on the electrode potential is taken into account, the standard deviation of experimental capacitance values from those calculated using the mentioned model is 6.8–8.8%, which points to very high accuracy of this phenomenological model. 相似文献
10.
Potential energy curves for the X (1)Sigma(g) (+) ground state and Omega=0(u) (+), 1(u) valence states and dipole moments for the 0(u) (+), 1(u)-X transitions are obtained in an ab initio configuration interaction study of Cl(2) including spin-orbit coupling. In contrast to common assumptions, it is found that the B (3)Pi(0(+)u)-X transition moment strongly depends on internuclear distance, which has an important influence on the Cl(2) photodissociation. Computed energy curves and transition moments are employed to calculate the A, B, C<--X extinction coefficients, the total spectrum for the first absorption band, and the Cl(*)((2)P(1/2))/Cl((2)P(3/2)) branching ratio as a function of excitation wavelength. The calculated data are shown to be in good agreement with available experimental results. 相似文献