全文获取类型
收费全文 | 1092篇 |
免费 | 39篇 |
国内免费 | 3篇 |
专业分类
化学 | 583篇 |
晶体学 | 12篇 |
力学 | 25篇 |
数学 | 348篇 |
物理学 | 166篇 |
出版年
2023年 | 8篇 |
2022年 | 24篇 |
2021年 | 23篇 |
2020年 | 20篇 |
2019年 | 31篇 |
2018年 | 31篇 |
2017年 | 31篇 |
2016年 | 53篇 |
2015年 | 32篇 |
2014年 | 56篇 |
2013年 | 91篇 |
2012年 | 95篇 |
2011年 | 76篇 |
2010年 | 48篇 |
2009年 | 40篇 |
2008年 | 59篇 |
2007年 | 65篇 |
2006年 | 60篇 |
2005年 | 39篇 |
2004年 | 33篇 |
2003年 | 23篇 |
2002年 | 23篇 |
2001年 | 8篇 |
2000年 | 15篇 |
1999年 | 11篇 |
1998年 | 16篇 |
1997年 | 10篇 |
1996年 | 11篇 |
1995年 | 9篇 |
1994年 | 9篇 |
1993年 | 5篇 |
1992年 | 4篇 |
1991年 | 6篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1987年 | 4篇 |
1986年 | 2篇 |
1985年 | 6篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 4篇 |
1981年 | 5篇 |
1980年 | 5篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1976年 | 5篇 |
1975年 | 2篇 |
1963年 | 1篇 |
1930年 | 1篇 |
排序方式: 共有1134条查询结果,搜索用时 15 毫秒
1.
Peralta Cecilia Mariana Acosta Gimena Henestrosa Cecilia Gil Raúl Andrés Fernández Liliana Patricia 《Journal of Analytical Chemistry》2022,77(3):308-317
Journal of Analytical Chemistry - The present development involved a flow injection strategy using a mini-column of multiwalled carbon nanotubes and fluorescent detection (λex of 283 nm,... 相似文献
2.
Verdecho María-José Alarcón-Valero Faustino Pérez-Perales David Alfaro-Saiz Juan-José Rodríguez-Rodríguez Raúl 《Central European Journal of Operations Research》2021,29(4):1231-1251
Central European Journal of Operations Research - Sustainability practice within supply chains remains in an early development phase. Enterprises still need tools that support the integration of... 相似文献
3.
Dr. Antonio M. Rodríguez Dr. Pilar Prieto Prof. Antonio de la Hoz Prof. Ángel Díaz-Ortiz D. Raúl Martín Prof. José I. García 《ChemistryOpen》2015,4(3):308-317
The aim of this work was to determine the parameters that have decisive roles in microwave-assisted reactions and to develop a model, using computational chemistry, to predict a priori the type of reactions that can be improved under microwaves. For this purpose, a computational study was carried out on a variety of reactions, which have been reported to be improved under microwave irradiation. This comprises six types of reactions. The outcomes obtained in this study indicate that the most influential parameters are activation energy, enthalpy, and the polarity of all the species that participate. In addition to this, in most cases, slower reacting systems observe a much greater improvement under microwave irradiation. Furthermore, for these reactions, the presence of a polar component in the reaction (solvent, reagent, susceptor, etc.) is necessary for strong coupling with the electromagnetic radiation. We also quantified that an activation energy of 20–30 kcal mol−1 and a polarity (μ) between 7–20 D of the species involved in the process is required to obtain significant improvements under microwave irradiation. 相似文献
4.
Mejía Hugo Fernando Giraldo Jiménez-Piqué Emilio Valdés Matías Procaccini Raúl Pellice Sergio 《Journal of Solid State Electrochemistry》2020,24(10):2451-2460
Journal of Solid State Electrochemistry - A novel material was developed using sol-gel chemistry and an environmental-friendly grafting process of clay nanoparticles. In a previous work of our... 相似文献
5.
6.
We continue the studies on the so–called genuine Bernstein–Durrmeyer operators U
n
by establishing a recurrence formula for the moments and by investigating the semigroup T(t) approximated by U
n
. Moreover, for sufficiently smooth functions the degree of this convergence is estimated. We also determine the eigenstructure
of U
n
, compute the moments of T(t) and establish asymptotic formulas.
Received: January 26, 2007. 相似文献
7.
In this work we study semifield planes of orderq
n(q=p
r
,p prime) with a collineation whose order is ap-primitive divisor ofq
n–1.Research supported in part by NSF Grant No. DMS-9107372Research supported in part by NSF grants RII-9014056, component IV of the EPSCoR of Puerto Rico grant and ARO grant for Cornell MSI. 相似文献
8.
In this paper we prove that all positive eigenvalues of the Laplacian of an arbitrary simple graph have some positive lower bounds. For a fixed integer k 1 we call a graph without isolated vertices k-minimal if its kth greatest Laplacian eigenvalue reaches this lower bound. We describe all 1-minimal and 2-minimal graphs and we prove that for every k 3 the path Pk+1 on k + 1 vertices is the unique k-minimal graph. 相似文献
9.
Leibniz agebras are a generalization of Lie algebras, where no symmetry properties of the bracket are required. In this Letter we introduce a notion of R-matrices for this structure and the related Yang–Baxter equations, and discuss some of their basic properties. 相似文献
10.
Dragan DJURCIC Aleksandar TORGASEV 《数学学报(英文版)》2006,22(3):689-692
In this paper, we prove some properties of the Seneta sequences and functions, and in particular we prove a representation theorem in the Karamata sense for the sequences from the Seneta class SOc. 相似文献