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Lavilla R Kumar R Coll O Masdeu C Spada A Bosch J Espinosa E Molins E 《Chemistry (Weinheim an der Bergstrasse, Germany)》2000,6(10):1763-1772
The natural tendency of 1,4-dihydropyridines to undergo "biomimetic" oxidation to afford pyridinium salts can be switched off and, through the use of reagents that interact electrophilically with the enamine moiety present in the heterocyclic system, it is possible to promote alternative oxidations. In this way, efficient regio- and stereocontrolled synthetic methods have been developed that lead to diversely substituted di- and tetrahydropyridines. These include iodoazidation, diamination, bis-sulfonamidation, sulfonylation, sulfinylation, thiocyanation, sulfanylation, bis-sulfanylation, and halo-phosphonylation processes. 相似文献
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This paper presents a method for the energy analysis of alpha-particles emitted by transuranic elements via a novel technique
using Nuclear Tracks. The method is based on the relationship between the energy deposited in the detection material and the
diameter of the track, that is formed by chemical etching. The method involves CR-39 polycarbonate as the detector material,
one-step chemical etching after irradiation, and a digital image analysis system for automatic reading of the track diameters.
The experimental study included alpha-particles in the energy range 5.1 MeV to 5.8 MeV emitted by239Pu,241Am and244Cm. The quantitative results provide a clear signature to identify each one of the emitters based on a characteristic track
diameter. 相似文献
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Conejo-García A Campos JM Entrena A Sánchez-Martín RM Gallo MA Espinosa A 《The Journal of organic chemistry》2003,68(22):8697-8699
A complete study of the conformational behavior of 4,8-diaza-3(1,4),9(4,1)-dipyridina-1,6(1,4)-dibenzenacyclodecaphan-3(1),9(1)-bis(ilium) bishexafluorophosphate is described. This study allows us to conclude that the process observed by which the different chemical shifts of the pyridinium protons show coalescence at a high-temperature 1H NMR is the rotation around the C-N bond, whereas the conformational equilibrium between the four conformers is produced at low temperature. 相似文献
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Peña-Alvarez A Díaz L Medina A Labastida C Capella S Vera LE 《Journal of chromatography. A》2004,1027(1-2):131-136
Steam distillation (SD) extraction-solid-phase microextraction coupled to GC-MS was developed for the determination of terpenes and Bligh-Dyer extraction-derivatization coupled with GC for the determination of fatty acids such as ethyl esters were used. It was found that the three different Agave species have the same profile of fatty acids; the quantity of these compounds is different in each Agave variety. On the other hand, different terpenes were identified in the three Agave plants studied: nine in A. salmiana, eight in A. angustifolia and 32 in A. tequilana Weber var. azul. 相似文献
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Nuclear Track Detectors (NTD's) are a useful option forin situ measurements of the distribution of alpha contamination as a function of soil depth. The contamination profile of alpha emitting elements, e.g. Pu, Am and U, can be determined by detecting their alpha emission at varying depths. This paper discusses a stake type device, containing strips of CR-39 (allyl diglycol carbonate) that can be inserted into the soil up to ten centimeters or more, depending on the firmness of the soil. The CR-39 is exposed directly to the contaminated soil for a few hours. The stake is then withdrawn from the soil, the plastic detectors recovered and the alpha tracks developed by chemical etching with KOH. The distribution of tracks can be used to determine the alpha contamination depth profile as well as for detecting hot spots. It has a sensitivity of less than a pCi/g of soil.Work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under contract W-7405-ENG-48. 相似文献
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