Synthesis,characterization and DFT calculations of a Re(V)-thiazolidine-2,4-dione complex

This article presents a combined experimental and computational study of a new oxorhenium(V) complex of thiazolidine-2,4-dione (HTDO). The complex has been synthesized by direct reaction of NH₄ReO₄ with thiazolidine-2,4-dione in the presence of Na₂S₂O₆ as a reducing agent. The complex [ReO(TDO)(H₂O)₃](S₂O₈) has been characterized by spectroscopy (FT-IR, NMR, UV-vis, mass), thermogravimetry, microanalysis, and HPL chromatography. The complex was geometrically optimized by DFT with B3LYP level of theory and satisfactory theoretical–experimental agreement was achieved for analysis of IR and NMR data of the complex. Additional information about binding between rhenium and oxo ligand in the complex has been obtained by NBO analysis. The antibacterial activity of the investigated complex has been tested and evaluated.     

新开花粉蛋白的盐酸胍去折叠过程

本文利用荧光光谱和园二色光谱了新开花粉蛋白的盐酸胍去折叠过程。结果显示：新开花粉蛋白的盐酸胍去折叠是一个只包含天然蛋白和变性终态的二态过程,与已经报道的天花粉蛋白的盐酸胍去折叠的过程不同。     

Review of nanofluids for heat transfer applications

Research on nanofluids has progressed rapidly since its enhanced thermal conductivity was first repotted about a decade ago,though much controversy and inconsistency have been reported,and insufficient understanding of the formulation and mechanism of nanofluids further limits their applications.This work presents a critical review of research on heat transfer applications of nanofluids with the aim of identifying the limiting factors so as to push forward their further development.     

CD40mAb adjuvant induces a rapid antibody response that may be beneficial in post-exposure prophylaxis

Active vaccination can be effective as a post-exposure prophylaxis, but the rapidity of the immune response induced, relative to the incubation time of the pathogen, is critical. We show here that CD40mAb conjugated to antigen induces a more rapid specific antibody response than currently used immunological adjuvants, alum and monophosphoryl lipid A™.     

CeO<Subscript>2</Subscript> nanoparticle-modified electrode as a novel electrochemical interface in the quantification of Zn<Superscript>2+ </Superscript>ions at trace level: application to real sample analysis

A simple strategy has been proposed to quantify Zn²⁺ ions using CeO₂ nanoparticle-modified glassy carbon electrode. The CeO₂ nanoparticles were prepared by sucrose-nitrate decomposition method, and it was characterized by X-ray diffraction (XRD), FT-IR, TEM, and surface area analyzer. The synthesized CeO₂ nanoparticles were used as modifier molecules as a thin film on glassy carbon electrode (GCE) in the trace level quantification of Zn²⁺ by using cyclic voltammetry (CV) and differential pulse anodic stripping voltammetry (DPASV) techniques. The fabricated sensor exhibited a good analytical response towards Zn²⁺ ions. The modified electrode showed a wide linearity in the concentration range 20–380 μg L^?1 with a limit of detection 0.36 μg L^?1. The proposed electrochemical sensor was successfully applied to trace level Zn²⁺ quantification from real sample matrices.     

FTIR光谱法研究天花粉蛋白的热去折叠过程

本文利用ＦＴＩＲ光谱技术和计算机辅助解析技术（二阶导数、去卷积和曲线拟合）研究了天花粉蛋白的热诱导去折叠过程。结果表明：在２５～８５℃温度范围内,天花粉蛋白的热去折叠是一个不可逆的分子间聚集的过程;二级结构随温度的变化暗示了折叠中间体的存在。     

Organocatalysis in synthesis: L-proline as an enantioselective catalyst in the synthesis of pyrans and thiopyrans

The multicomponent reaction (MCR) of aromatic aldehydes 1 and malononitrile (2) with active methylenes 5a-h in the presence of L-proline produced pyrans and thiopyrans 6a-h stereospecifically and in good yields. Moreover a novel MCR of ethyl propiolate (8) with 1 and 2 in the presence of L-proline to afford (R)-polysubstituted pyran is also reported. X-ray structures, e.e. and optical activity of the synthesized compounds indicated that L-proline as a catalyst is responsible for the observed enantioselectivity in the studied reactions.