全文获取类型
收费全文 | 1840篇 |
免费 | 81篇 |
国内免费 | 11篇 |
专业分类
化学 | 1555篇 |
晶体学 | 14篇 |
力学 | 13篇 |
数学 | 85篇 |
物理学 | 265篇 |
出版年
2023年 | 11篇 |
2022年 | 12篇 |
2021年 | 17篇 |
2020年 | 35篇 |
2019年 | 38篇 |
2018年 | 22篇 |
2017年 | 18篇 |
2016年 | 45篇 |
2015年 | 47篇 |
2014年 | 57篇 |
2013年 | 91篇 |
2012年 | 121篇 |
2011年 | 140篇 |
2010年 | 81篇 |
2009年 | 69篇 |
2008年 | 84篇 |
2007年 | 114篇 |
2006年 | 127篇 |
2005年 | 94篇 |
2004年 | 82篇 |
2003年 | 85篇 |
2002年 | 78篇 |
2001年 | 41篇 |
2000年 | 38篇 |
1999年 | 30篇 |
1998年 | 13篇 |
1997年 | 23篇 |
1996年 | 15篇 |
1995年 | 21篇 |
1994年 | 21篇 |
1993年 | 12篇 |
1992年 | 18篇 |
1991年 | 18篇 |
1990年 | 15篇 |
1989年 | 14篇 |
1988年 | 17篇 |
1987年 | 15篇 |
1986年 | 9篇 |
1985年 | 21篇 |
1984年 | 25篇 |
1983年 | 10篇 |
1982年 | 20篇 |
1981年 | 10篇 |
1980年 | 10篇 |
1979年 | 6篇 |
1977年 | 6篇 |
1976年 | 5篇 |
1974年 | 6篇 |
1973年 | 5篇 |
1968年 | 5篇 |
排序方式: 共有1932条查询结果,搜索用时 15 毫秒
1.
Three new cytotoxic polyacetylenes, PQ-1 (1), PQ-2 (2) and PQ-3 (3), have been isolated from Panax quinquefolium. The structures of these acetylenes were determined by analyses of their 1H-1H and 1H-13C COSY spectra. All these compounds exhibited strong cytotoxic activities against leukemia cells (L 1210) in tissue culture. 相似文献
2.
3.
XPS measurement revealed that the original state of TiO2 was changed to Ti2O3 and TiO by ion bombardment. TiO2 decreased and Ti2O3 increased at the initial stage. TiO increased at a later stage than Ti2O3. Each of them saturated after enough sputtering time.A formulation was proposed in order to explain the change of XPS spectra for oxides as a function of ion sputtering time. This formulation was based on reaction equations that contain two reduction processes (from TiO2 to Ti2O3 and from Ti2O3 to TiO), and sputtering effects. Using four fitting parameters (two reduction coefficients, sputtering yield and information depth), the present formula was fitted to the experimental results. The fitting results agree satisfactorily with the experimental results. The calculation shows that the reduction coefficient from TiO2 to Ti2O3 is about ten times larger than that from Ti2O3 to TiO. This calculation predicts that surface composition of an oxide that is changed by ion bombardment will reach a different value depending on its bulk composition. Moreover, the present formulation can determine the chemical states of compounds changed by ion bombardment. 相似文献
4.
H. Sunaoshi Y. Fukashiro M. Furukawa M. Yamauchi S. Hayashibe T. Shinozuka M. Fujioka I. Satoh M. Wada S. Matsuki 《Hyperfine Interactions》1993,78(1-4):241-245
The ground state hyperfine splitting of87Sr+ was measured with a precision of 1×10–8. The experiments were performed with an RF ion trap connected to an ISOL (isotope separator on-line), where all the possible transitions between Zeeman sublevels were observed by a laser-microwave double resonance method. The magnetic dipole hyperfine constant was determined to beA=–1 000 473.673 (11) kHz. 相似文献
5.
6.
Masayuki Kuzuya Akihiro Noguchi Hideki Ito Shin-Ichi Kondo Nahoko Noda 《Journal of polymer science. Part A, Polymer chemistry》1991,29(1):1-7
Plasma-induced polystyrene radicals were first studied by electron spin resonance (ESR). The room temperature ESR spectrum was compared with those obtained by γ-irradiation, UV-irradiation, and mechanical fracture. It was found that even less than a few seconds of plasma-irradiation gave rise to a large amount of polystyrene radicals and the ESR spectrum consisted of two types of spectra, a triplet and a single broad line. The spectral feature of the triplet was nearly identical with that of γ-irradiated polystyrene. Thus, it was assigned to the structure of a cyclohexadienyl-type radical formed by a nearly random addition of a hydrogen atom to the aromatic ring. The single broad line, thought to be an outline of multicomponent spectrum, was assigned to an immobilized dangling-bond sites at the plasma-induced crosslinked portion of the polystyrene surface. 相似文献
7.
Tomomi Kawasaki Miyuki Nagaoka Tomoko Satoh Ayako Okamoto Rie Ukon Atsuyo Ogawa 《Tetrahedron》2004,60(15):3493-3503
Claisen rearrangement triggered by enolization of 2-allyloxyindolin-3-ones with DBU was performed in order to prepare 3-allyl-3-hydroxyindolin-2-ones. Total synthesis of 3-hydroxyindolin-2-one alkaloids, (±)-donaxaridine, as well as (±)-convolutamydines A and E, was achieved by transformation of the allyl moiety of 3-allyl-3-hydroxyindolin-2-ones. 相似文献
8.
A new hydrophilic copolymer having three kinds of hydroxyl groups, i.e. primary OH on -hydroxy allyl alcohol component, secondary OH on cyclic hemiacetal component and tertiary OH on -hydroxy acrylate component, was prepared by reducing a ‘polylactone’, poly(1-oxa-2-oxobutane-1,4:3,3-tetrayl), with NaBH4 in mixed solvents containing an alcohol. The structural analyses were performed by the solution 1H NMR and the solid state 13C NMR spectroscopies of the reduced samples. The composition of the three components turned out to be variable to the alcohol species used for the mixed solvent. 相似文献
9.
Abdelhak BelaissaouiSatoru Shimada Akihiro OhishiNobuyuki Tamaoki 《Tetrahedron letters》2003,44(11):2307-2310
A bifunctional [2]rotaxane, bearing two free functional groups each in the ring and axial parts, was synthesized, followed by its polycondensation with methylene diphenyl diisocyanate leading to a mechanically linked oligo[2]rotaxane. 相似文献
10.