全文获取类型
收费全文 | 246篇 |
免费 | 4篇 |
国内免费 | 5篇 |
专业分类
化学 | 100篇 |
力学 | 13篇 |
数学 | 103篇 |
物理学 | 39篇 |
出版年
2023年 | 2篇 |
2022年 | 2篇 |
2020年 | 5篇 |
2019年 | 4篇 |
2018年 | 6篇 |
2017年 | 3篇 |
2016年 | 9篇 |
2015年 | 3篇 |
2014年 | 4篇 |
2013年 | 14篇 |
2012年 | 15篇 |
2011年 | 9篇 |
2010年 | 11篇 |
2009年 | 11篇 |
2008年 | 14篇 |
2007年 | 13篇 |
2006年 | 11篇 |
2005年 | 12篇 |
2004年 | 11篇 |
2003年 | 7篇 |
2002年 | 6篇 |
2001年 | 7篇 |
2000年 | 2篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1993年 | 3篇 |
1991年 | 4篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 7篇 |
1985年 | 2篇 |
1984年 | 5篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 9篇 |
1978年 | 7篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1961年 | 1篇 |
1957年 | 1篇 |
1956年 | 1篇 |
1938年 | 1篇 |
1937年 | 2篇 |
1936年 | 1篇 |
1932年 | 1篇 |
排序方式: 共有255条查询结果,搜索用时 15 毫秒
1.
B. P. Duggal 《Rendiconti del Circolo Matematico di Palermo》1938,62(2):215-226
If \(T=\left(\begin{array}{clcr}T_1&\quad C\\ 0&\quad T_2\end{array}\right) \in B(\mathcal{X }_1\oplus \mathcal{X }_2)\) is a Banach space upper triangular operator matrix with diagonal \((T_1, T_2)\) such that \(T_2\) is \(k\)-nilpotent for some integer \(k\ge 1\), then \(T\) inherits a number of its spectral properties, such as SVEP, Bishop’s property \((\beta )\) and the equality of Browder and Weyl spectrum, from those of \(T_1\). This paper studies such operators. The conclusions are then applied to provide a general framework for results pertaining (for example) to Browder, Weyl type theorems and supercyclicity for classes of Hilbert space operators, such as \(k\)-quasi hyponormal, \(k\)-quasi isometric and \(k\)-quasi paranormal operators, defined by a positivity condition. 相似文献
2.
Akhilesh K. Verma Rupesh Kumar Amit Saxena Subho Mozumdar 《Tetrahedron letters》2005,46(31):5229-5232
A novel method for effecting the aza-Michael reactions of N-alkyl- and N-arylpiperazines with acrylonitrile using Cu-nanoparticles is described. The method features the use of 10 mol % Cu (14-17 nm) nanoparticles under mild reaction conditions to afford the addition products in good to excellent yields. The Cu-nanoparticles selectively catalysed the aza-Michael reaction of N-alkyl- and N-arylpiperazines in the presence of aromatic amino or aliphatic hydroxy groups. 相似文献
3.
Titanosilicates with complete or partial substitution of Ge or Nb in the framework and having the mineral pharmacosiderite topology were hydrothermally prepared and their ion-exchange properties towards Cs were studied for Ti/Ge/Si, Ti/Si, Nb/Ti/Si and pure Ge phases. The basis for the differences in the ion exchange properties measured as distribution coefficients (Kd) for these materials are detailed via structural characterization using the Rietveld refinement technique on the X-ray powder diffraction data. The differences in affinity towards Cs+ result either from the degree of hydration of the exchanger resulting in different coordination environments or the position of cesium ion in the eight-ring channel. 相似文献
4.
High pressure behavior of alpha-hydroquinone (1,4-dihydroxybenzene) has been studied using Raman spectroscopy up to pressures of 19 GPa. Evolution of Raman spectra suggests two transitions around 3.3 and 12.0 GPa. The first transition appears to be associated with the lowering of crystal symmetry. Above 12.0 GPa, Raman bands in the internal modes region exhibit continuous broadening suggesting that the system is progressively evolving into a disordered state. This disorder is understood as arising due to distortion of the hydrogen-bonded cage across the second transition around 12 GPa. 相似文献
5.
S. K. Aggarwal G. Chourasiya R. K. Duggal R. Rao P. A. Ramasubramanian H. C. Jain 《Journal of Radioanalytical and Nuclear Chemistry》1987,119(1):1-12
A reverse isotope dilution alpha spectrometric /R-IDAS/ method using239Pu as a spike is described for the determination of plutonium concentration in high burn-up fuel samples wth238Pu/(239Pu+240Pu) alpha activity ratio >0.5, without resorting to any purification from241Am and a bulk of other impurities. It involves the addition of a pre-clibrated spike solution to a known aliquot of the plutonium sample solution followed by source preparation using TEG as a spreading agent. The results obtained on a number of plutonium samples containing 20–80% of241Am /alpha activity wise/ using this method are compared with those achieved by R-IDAS using purification with TTA, with respect to precision and accuracy. Precision and accuracy of 0.5% are demonstrated. This method eliminates the need of any separation and purification of plutonium from241Am and a bulk of other impurities like uranium. 相似文献
6.
The 25% niobium substituted crystalline titanosilicate with the composition Na1.5Nb0.5Ti1.5O3SiO4·2H2O (Nb-TS) was synthesized under hydrothermal conditions. Its selectivity for radioactive 137Cs and 89Sr was compared with the TS, Na2Ti2O3SiO4·2H2O, having sitinakite topology. The Nb-TS shows significantly higher uptake value for 137Cs but lower for 89Sr than the TS. To investigate the origin of selectivity, the ion exchanged Cs+ and Sr2+ forms with the composition, CsxNaHyNb0.5Ti1.5O3SiO4·zH2O (x=0.1, 0.2 and 0.3, x+y=0.5 and z=1-2) and Sr0.2Na0.6H0.5Nb0.5Ti1.5O3SiO4·H2O, respectively, were structurally characterized from the X-ray powder diffraction data using the Rietveld refinement technique. Simultaneously the kinetics of 137Cs and 89Sr uptake was investigated for the NbV free and doped samples. While the Cs+ and Sr2+ exchanged form of Nb-TS and the Cs+ exchanged form of TS retain the symmetry of the parent compound, the Sr2+ exchanged form of TS undergoes a symmetry change. The differences in the uptake of Cs+ and Sr2+ result from the different coordination environments of cesium and strontium in the eight-ring channel, that result from various hydration sites in the tunnel. The origin of selectivity appears to arise from the higher coordination number of cesium or strontium. Other effects due to NbV substitution are reflected in the increase of both, the a- and c-dimensions and thus the unit cell volume, and the population of water vs. Na+ in the channel to charge-balance the Nb5+↔Ti4+ substitution. 相似文献
7.
Kapil Mohan Saini Rakesh K. Saunthwal Sushmita Akhilesh K. Verma 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(5):1017-1021
Transition-metal-free regioselective synthesis of functionalized amino-indenones by the reaction of ortho-alkynylaldehydes with a broad range of primary amines by intramolecular cyclization has been described. The designed reaction proceeds through KOH-mediated Prins-type cyclization and DMSO-promoted oxidation of the cyclopent-2-en-1-one system. The proposed mechanism and role of solvent were well supported by control experiments. For the first time, we have disclosed the reverse reactivity of (2-alkynyl)-arylaldimines in a super basic system. 相似文献
8.
Anirban Bhandari Saikat Mishra Dr. Ram Chandra Maji Akhilesh Kumar Prof. Dr. Marilyn M. Olmstead Prof. Dr. Apurba K. Patra 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(23):9262-9270
According to the well-accepted mechanism, methyl-coenzyme M reductase (MCR) involves Ni-mediated thiolate-to-disulfide conversion that sustains its catalytic cycle of methane formation in the energy saving pathways of methanotrophic microbes. Model complexes that illustrate Ni-ion mediated reversible thiolate/disulfide transformation are unknown. In this paper we report the synthesis, crystal structure, spectroscopic properties and redox interconversions of a set of NiII complexes comprising a tridentate N2S donor thiol and its analogous N4S2 donor disulfide ligands. These complexes demonstrate reversible NiII-thiolate/NiII-disulfide (both bound and unbound disulfide-S to NiII) transformations via thiyl and disulfide monoradical anions that resemble a primary step of MCR's catalytic cycle. 相似文献
9.
10.
The electron paramagnetic resonance of Mn2+ doped in single crystals of Zn(ClO4)2·6H2O has been studied at X-band in the temperature range 300–380 K. A phase transition, observed at ~ 346 K, is reported for the first time. 相似文献