Lattices contained in planar orders are planar

The covering graph of a lattice which is contained in an ordered set with a planar covering graph is itself planar.Presented by R. W. Quackenbush.     

Convergent stereocontrolled synthesis of substituted exo-glycals by Stille cross-coupling of halo-exo-glycals and stannanes

(Z)-exo-Glycals can be conveniently prepared in a convergent manner by Stille cross-coupling of (Z)-halo(Br,I)-exo-glycals and aryl or alkenyl stannanes, the latter are readily obtained by addition of tributylstannyl radicals to terminal alkynes.     

Site-specific C content by quantitative isotopic C Nuclear Magnetic Resonance spectrometry: A pilot inter-laboratory study

Isotopic ¹³C NMR spectrometry, which is able to measure intra-molecular ¹³C composition, is of emerging demand because of the new information provided by the ¹³C site-specific content of a given molecule. A systematic evaluation of instrumental behaviour is of importance to envisage isotopic ¹³C NMR as a routine tool. This paper describes the first collaborative study of intra-molecular ¹³C composition by NMR. The main goals of the ring test were to establish intra- and inter-variability of the spectrometer response. Eight instruments with different configuration were retained for the exercise on the basis of a qualification test. Reproducibility at the natural abundance of isotopic ¹³C NMR was then assessed on vanillin from three different origins associated with specific δ¹³C_i profiles. The standard deviation was, on average, between 0.9 and 1.2‰ for intra-variability. The highest standard deviation for inter-variability was 2.1‰. This is significantly higher than the internal precision but could be considered good in respect of a first ring test on a new analytical method. The standard deviation of δ¹³C_i in vanillin was not homogeneous over the eight carbons, with no trend either for the carbon position or for the configuration of the spectrometer. However, since the repeatability for each instrument was satisfactory, correction factors for each carbon in vanillin could be calculated to harmonize the results.     

Theoretical prediction of the damping of a railway wheel with sandwich-type dampers

This paper presents a procedure for predicting the damping added to a railway wheel when sandwich-type dampers are installed. Although there are different ways to reduce the noise generated by a railway wheel, most devices are based on the mechanism of increasing wheel damping. This is why modal damping ratios are a clear indicator of the efficiency of the damping device and essential when a vibro-acoustic study of a railway wheel is carried out. Based on a number of output variables extracted from the wheel and damper models, the strategy explained herein provides the final damping ratios of the damped wheel. Several different configurations are designed and experimentally tested. Theoretical and experimental results agree adequately, and it is demonstrated that this procedure is a good tool for qualitative comparison between different solutions in the design stages.     

Whistler instability in an electron-magnetohydrodynamic spheromak

A three-dimensional magnetic vortex, propagating in the whistler mode, has been produced in a laboratory plasma. Its magnetic energy is converted into electron kinetic energy. Non-Maxwellian electron distributions are formed which give rise to kinetic whistler instabilities. The propagating vortex radiates whistler modes along the ambient magnetic field. A new instability mechanism is proposed.     

Chemical reactions of water molecules on Ru(0 0 0 1) induced by selective excitation of vibrational modes

Tunneling electrons in a scanning tunneling microscope were used to excite specific vibrational quantum states of adsorbed water and hydroxyl molecules on a Ru(0 0 0 1) surface. The excited molecules relaxed by transfer of energy to lower energy modes, resulting in diffusion, dissociation, desorption, and surface-tip transfer processes. Diffusion of H₂O molecules could be induced by excitation of the O-H stretch vibration mode at 445 meV. Isolated molecules required excitation of one single quantum while molecules bonded to a C atom required at least two quanta. Dissociation of single H₂O molecules into H and OH required electron energies of 1 eV or higher while dissociation of OH required at least 2 eV electrons. In contrast, water molecules forming part of a cluster could be dissociated with electron energies of 0.5 eV.     

Illuminating high-dimensional convex sets

A setL of points in thed-spaceE ^d is said toilluminate a familyF={S ₁, ...,S _n } ofn disjoint compact sets inE ^d if for every setS _i inF and every pointx in the boundary ofS _i there is a pointv inL such thatv illuminatesx, i.e. the line segment joiningv tox intersects the union of the elements ofF in exactly {x}.The problem we treat is the size of a setS needed to illuminate a familyF={S ₁, ...,S _n } ofn disjoint compact sets inE ^d . We also treat the problem of putting these convex sets in mutually disjoint convex polytopes, each one having at most a certain number of facets.     

Scheduling tasks with communication delays on parallel processors

LetP={v ₁,...,v _n } be a set ofn jobs to be executed on a set ofm identical machines. In many instances of scheduling problems, if a jobv _i has to be executed before the jobv _j and both jobs are to be executed on different machines, some sort of information exchange has to take place between the machines executing them. The time it takes for this exchange of information is called a communication delay.In this paper we give anO(n) algorithm to find an optimal scheduling with communication delays when the number of machines is not limited and the precedence constraints on the jobs form a tree.