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The synthesis of several new polyfunctionally substituted fused pyrazoles via reaction of 5‐amino‐3‐methylthio‐1H‐pyrazole‐4‐carboxylate ( 2 ) with different reagents is described. 相似文献
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M. G. Syed Basheer Ahamed V. S. Nagarethinam A. R. Balu A. Thayumanavan K. R. Murali C. Sanjeeviraja M. Jayachandran 《Crystal Research and Technology》2010,45(4):421-426
ZnSe films were deposited on glass substrates keeping the substrate temperatures, at room temperature (RT), 75, 150 and 250 °C. The films have exhibited cubic structure oriented along the (111) direction. Both the crystallinity and the grain size increased with increasing deposition temperature. A very high value of absorption co‐efficient (104 cm‐1) is observed. The band gap values decrease from a value of 2.94 eV to 2.69 eV with increasing substrate temperature. The average refractive index value is in the range of 2.39 – 2.41 for the films deposited at different substrate temperatures. The conductivity values increases continuously with temperature. Laser Raman spectra showed peaks at 140.8 cm‐1, 246.7 cm‐1and 204.5 cm‐1which are attributable to 2TA LO phonon and TO phonon respectively. (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
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A new iminocoumarin based receptor L (C(27)H(26)N(4)OS) is synthesized with pyridyl and benzothiazolyl functionality. Synthesis of L is easy and it is isolated in good yield. L shows a selective and distinct color change from yellow to orange with Cu(2+) over Li(+), Na(+), Ca(2+), Mg(2+), Cr(2+), Mn(2+), Fe(2+), Co(2+), Ni(2+), Cu(2+), Zn(2+), Cd(2+), Pb(2+), and Ag(+) whereas a slight change in color is also observed in the case of Hg(2+) but L shows selective fluorescent quenching only in the presence of Cu(2+) in aqueous HEPES buffer (pH 7.0). The naked eye detection limit of Cu(2+) is determined at 2 μM whereas an emission experiment shows a lower detection limit at 200 nM. Selectivity studies of L in presence of 50 equivalents of other ion(s) by emission experiment show no interference toward the detection of 1 equivalent of Cu(2+). Both UV-Vis and fluorescence studies in the presence of Cu(2+)-salts of different counter anions with various sizes and shapes (Cl(-), ClO(4)(-), NO(3)(-), CF(3)SO(3)(-), SO(4)(2-) and BF(4)(-)) show almost similar spectral output in buffer media irrespective of the nature of the counter anions. The detailed UV-Vis and fluorescence titration experiments suggest the existence of both 1:1 and 2:1 (L:Cu(2+)) complexation stoichiometry and EPR study shows d(x(2)-y(2)) ground state of the Cu(II) centre in the complex. Furthermore the formation of a mononuclear [Cu(L)(CH(3)CN)].2ClO(4) complex and the flexible conformation of L in the solid state are confirmed by the single-crystal X-ray structural study. 相似文献
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Kumar KS Kumar PM Kumar KA Sreenivasulu M Jafar AA Rambabu D Krishna GR Reddy CM Kapavarapu R Shivakumar K Priya KK Parsa KV Pal M 《Chemical communications (Cambridge, England)》2011,47(17):5010-5012
Concurrent construction of five and six membered fused N-heretocyclic ring was achieved via a conceptually new three-component reaction affording 6,6a-dihydroisoindolo[2,1-a]quinazoline-5,11-diones as novel inhibitors of TNF-αin vitro. This represents one of the few examples of direct TNF-α inhibition by small molecules. 相似文献
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Ghalib RM Hashim R Sulaiman O Mehdi SH Anis Z Rahman SZ Ahamed BM Abdul Majid AM 《Natural product research》2012,26(22):2155-2158
The leaves of Cinnamomum iners (Reinw. ex Blume-Lauraceae) have been refluxed successively with chloroform and alcohol to get chloroform extract and alcoholic extract. Both the extracts have been assayed for cytotoxicity against human colorectal tumour cells. The chloroform extract exhibited significant cytotoxicity with IC(50) 31?μg mL(-1) (p?0.01). However, ethanol extract was found to be much less cytotoxic with IC(50)?>?200?μg mL(-1). The chloroform extract has been further proceeded for chemical analysis by GC-TOFMS and 178 components were identified including acids, amines, amides, aldehydes, alcohols, esters, benzene derivatives, bicyclic compounds, terpenes, hydrocarbons, naphthalene derivatives, furan derivatives, azulenes, etc. Nine components representing 51.73% of the total chloroform extract were detected as major components. Caryophyllene (14.41%) and Eicosanoic acid ethyl ester (12.17%) are the most prominent components of the chloroform extract. β-Caryophyllene (14.41%) as most abundant compound supports potent cytotoxicity as shown by chloroform extract. 相似文献
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Using pyronin B and crystal violet dye mixture, the characteristics of energy transfer distributed feedback dye laser (ETDFDL) pumped by 532 nm Nd:YAG laser were investigated. The characteristics of donor DFDL and acceptor DFDL as well as the dependence of their pulse widths and output powers on pump power and acceptor concentrations were studied. The output energy of DFDL was measured at the emission peaks of donor and acceptor dyes for different pump powers and acceptor concentrations, and tunability was observed from 570 to 645 nm using prism dye cell arrangement. 相似文献
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Adam Khatir Sam M. M. O. Ahamed F. El Khangi P. Roos 《Journal of Radioanalytical and Nuclear Chemistry》2000,245(2):411-414
This paper presents the activity concentrations of Pu isotopes in surface marine sediments collected from the Sudanese coast of the Red Sea. The following concentration ranges were determined: 238Pu, 4.7–28.6 mBq/kg; 239+240Pu, 53–343 mBq/kg dry weight. The average activity ratios of 238Pu/239+240Pu (0.075±0.045 mBqk/kg) and 239+240Pu/137Cs (0.026±0.025 mBq/kg) are appropriately comparable to the literature values that are characteristic of the global fallout from the atmospheric nuclear weapon tests. However, 239+240Pu/137Cs ratio in sediments collected from the biologically rich fringing reef is an order of magnitude higher compared to other sampling locations. 相似文献
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Syntheses of three tris-(2-aminoethyl)amine, tren based tripodal fluoroionophores (L2, L3, and L5), are reported. These fluoroionophores are designed based on the fluorophore–spacer–receptor format (choice of fluorophore in all three cases is anthryl unit). In L2, three anthracene moieties are attached to the three arms of tren via –CH2-spacer whereas L3 and L5 have p-nitro benzyl and p-methoxy benzyl substitutions, respectively, on L2, which are in close proximity to the photoinduced electron transfer (PET) center. All three fluoroionophores show appreciably lower fluorescence compared to anthracene due to effective PET process in these systems but the quantum yield varies depending upon the nature of substitution at the PET center. In the cases of L2 and L5 different amounts of fluorescence recovery are observed in the presence of different cation inputs whereas L3 is almost inactive toward cation sensing. Detailed fluorescence emission studies on L2 and L5 in the presence of different cation inputs showed that L5 having N4 donor sets bearing three p-methoxy benzyl units attached to the three nitrogen centers involving photoinduced electron transfer process is a viable candidate for enhancement of fluorescence with Cu(II) input. In the absence of p-methoxy benzyl units at the nitrogen centers' resulting system, L2 shows quenching of fluorescence with the Cu(II) under same experimental conditions. 相似文献
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