Computational design of new organic (D–π–A) dyes based on benzothiadiazole for photovoltaic applications,especially dye-sensitized solar cells

Research on Chemical Intermediates - A theoretical study on four organic dyes based on bis(4-hexyloxy)triphenylamine as donor and electron acceptor cyanoacrylic acid with a...     

Thermal management of modern electric vehicle battery systems (MEVBS)

Journal of Thermal Analysis and Calorimetry - The operating temperature of Li-ion batteries used in modern electric vehicles should be maintained within an allowable range to avoid thermal runaway...     

On the efficacy of charging a battery using a chaotic energy harvester

Nonlinear Dynamics - Introduction of stiffness nonlinearities to broaden the frequency bandwidth of vibratory energy harvesters has the adverse influence of complicating the response behavior of...     

Designing spirobifullerene core based three-dimensional cross shape acceptor materials with promising photovoltaic properties for high-efficiency organic solar cells

The development of organic electron acceptor materials is one of the key factors for realizing high-performance organic solar cells (OSCs). Nonfullerene electron acceptors, compared to traditional fullerene acceptor materials, have gained much impetus owing to their better optoelectronic tunabilities and lower cost, as well as higher stability. Therefore, 5 three-dimensional (3D) cross-shaped acceptor materials having a spirobifullerene core flanked with 2,1,3-benzothiadiazole are designed from a recently synthesized highly efficient acceptor molecule SF(BR) ₄ and are investigated in detail with regard to their use as acceptor molecules in OSCs. The density functional theory (DFT) and time-dependent DFT (TDDFT) calculations have been performed for the estimation of frontier molecular orbital (FMO) analysis, density of states analysis, reorganization energies of electron and hole, dipole moment, open-circuit voltage, photo-physical characteristics, and transition density matrix analysis. In addition, the structure-property relationship is studied, and the influence of end-capped acceptor modifications on photovoltaic, photo-physical, and electronic properties of newly selected molecules ( H1-H5 ) is calculated and compared with reference ( R ) acceptor molecule SF(BR) ₄ . The structural tailoring at terminals was found to effectively tune the FMO band gap, energy levels, absorption spectra, open-circuit voltage, reorganization energy, and binding energy value in selected molecules H1 to H5 . The 3D cross-shaped molecules H1 to H5 suppress the intermolecular aggregation in PTB7-Th blend, which leads to high efficiency of acceptor material H1 to H5 in OSCs. Consequently, better optoelectronic properties are achieved from designed molecules H1 to H5 . It is proposed that the conceptualized molecules are superior than highly efficient spirobifullerene core-based SF(BR) ₄ acceptor molecules and, thus, are recommended to experiments for future developments of highly efficient solar cells.     

Non existence de solutions globales de certaines équations d'ondes non linéairesNonexistence of global solutions to some nonlinear wave equations

We study the semilinear wave equation u_tt?Δu=p^?k|u|^m in $\text{R}\text{×}\text{R}{}^{\mathrm{n}}$, where p is a conformal factor approaching 0 at infinity. We prove that the solutions blow-up in finite time for small powers m, while having an arbitrarily long life-span for large m. Furthermore, we study the finite time blow-up of solutions for the class of quasilinear wave equations u_tt?Δu=p^?k|Lu|^m in $\text{R}\text{×}\text{R}{}^{\mathrm{n}}$. To cite this article: M. Aassila, C. R. Acad. Sci. Paris, Ser. I 334 (2002) 961–966.     

Nonexistence Results of Minimal Immersions

Let M be a Riemannian m-dimensional manifold with m ≥ 3, endowed with non zero parallel p-form. We prove that there is no minimal isometric immersions of M in a Riemannian manifold N with constant strictly negative sectional curvature. Next we show that, under the conform flatness of the manifold N and some assumptions on the Ricci curvature of N, there is no α-pluriharmonic isometric immersion.