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1.
Self‐Assembly and Gelation of Poly(aryl ether) Dendrons Containing Hydrazide Units: Factors Controlling the Formation of Helical Structures 下载免费PDF全文
Partha Malakar Prof. Dr. Edamana Prasad 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(13):5093-5100
Self‐assembly of AB2 and AB3 type low molecular weight poly(aryl ether) dendrons that contain hydrazide units were used to investigate mechanistic aspects of helical structure formation during self‐assembly. The results suggest that there are three important aspects that control helical structure formation in such systems with acyl hydrazide/hydrazone linkage: i) J‐type aggregation, ii) the hydrogen‐bond donor/acceptor ability of the solvent, and iii) the dielectric constant of the solvent. The monomer units self‐assemble to form dimer structures through hydrogen‐bonding and further assembly of the hydrogen‐bonded dimers leads to macroscopic chirality in the present case. Dimer formation was confirmed by NMR spectroscopy and by mass spectrometry. The self‐assembly in the system was driven by hydrogen‐bonding and π–π stacking interactions. The morphology of the aggregates formed was examined by scanning electron microscopy, and the analysis suggests that aprotic solvent systems facilitate helical fibre formation, whereas introduction of protic solvents results in the formation of flat ribbons. This detailed mechanistic study suggests that the self‐assembly follows a nucleation–elongation model to form helical structures, rather than the isodesmic model. 相似文献
2.
K. Batra V. Prasad M. Mohan 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,20(2):191-198
The scattering of heavy ion with a multilevel Rydberg atom in the presence of an electromagnetic field is studied. The interaction
of Rydberg atom and the e.m field is explored using non-perturbative quasi-energy technique. Although the results are presented
for selected excitations but in actual calculations we have included many levels of the atom. The effect of various parameters
are shown on collisional excitation process. As an illustration detailed calculations are performed for the inelastic proton-Na
Rydberg atom collision accompanied by the transfer of photons and the effects of dressing due to the field are considered.
The emphasis of the present work is on collision induced transitions especially the case that involves change of orbital as
well as principal quantum number.
Received 26 December 2001 / Received in final form 8 April 2002 Published online 19 July 2002 相似文献
3.
Beeranahally H Doreswamy Madegowda Mahendra Hirihally C Devarajegowda Venkatesh B Devaru Sridhar M Anandalwar Javaregowda S Prasad 《Analytical sciences》2004,20(2):407-408
The title compound was extracted from a natural product and its structure was characterized by an X-ray diffraction method. It crystallizes in the tetragonal space group P41 with cell parameters a = 15.832(10)A, c = 11.622(10)A, Z = 4; the final residual factor is R1 = 0.0769. The structure has both intra and intermolecular hydrogen bonds. 相似文献
4.
P Rabindra Reddy P R Prasad Reddy M Harilatha Reddy 《Journal of Chemical Sciences》1987,99(5-6):297-303
Studies on interaction of La(III), Pr(III), Nd(III), Sm(III), Gd(III), Dy(III) and Er(III) with inosine and xanthosine in
a 1:1 ratio have been carried out by potentiometric equilibrium measurements at 35±0·1°C and 0·1 M (KNO3) ionic strength. Investigations were also made for the interaction of these metal ions and nucleosides with the biologically
important secondary ligands glycine and histidine. These investigations were undertaken with a view to assess the influence
of charge on the structure and stability of 1:1 metal-inosine/xanthosine systems.
DBT/India overseas Fellow at Harvard University (1986–88). 相似文献
5.
Andrew Bach Xinglong Jiang Joseph Mckenna Kapa Prasad Oljan Repic Wen‐Chung Shieh 《Journal of heterocyclic chemistry》2004,41(4):637-640
An efficient approach has been developed for the synthesis of an isofervenulin analogue 1 employing a one‐pot condensation‐substitution reaction of a chlorocarboethoxytriazine (electrophile) with a urea (nucleophile). The resulting cyclization reaction resulted in the synthesis of a pyrimido‐heterocycle in good yield in either acidic or basic media. The former was assisted by utilizing trimethylsilyl chloride. 相似文献
6.
C. V. Yelamaggad Manoj Mathews Uma Hiremath Geetha Nair D. S. Shankar Rao S. Krishna Prasad 《Liquid crystals》2003,30(8):899-908
A series of symmetrical dimers consisting of salicylaldimine moieties connected by flexible alkylene central spacer via ether linkages has been synthesized. In order to validate the empirical rule suggested by Date et al. to account for the smectic behaviour of such dimers, the chain length of the terminal alkoxy chain has been kept constant (C8) while the number of methylene units in the central spacer was varied from C3 to C11. Another aim of the present investigation was to understand structure-property relationship in these dimers in which the salicylaldimine mesogenic segment has been used for the first time in dimers. The mesomorphic behaviour of these dimers was evaluated using optical microscopy and differential scanning calorimetry and the structure of some of the mesophases has been further investigated with the help of X-ray diffraction. Our studies reveal that the dimers consisting of 3 to 8 methylene units in the flexible spacer show only smectic (smectic C and smectic A) phases. For the dimers containing 4, 6 and 8 methylene units in the central spacer, a unique filament growth pattern has been observed in the smectic A phase while cooling from the isotropic phase. The dimers containing of C9 to C11 methylene groups exhibit the nematic phase in addition to smectic modifications. This observation indicates that when the terminal chains are shorter than the spacer, the tendency to form smectic phases is not fully extinguished but is perhaps reduced. 相似文献
7.
B. Sahoo W. Keune E. Schuster W. Sturhahn T. S. Toellner E. E. Alp 《Hyperfine Interactions》2006,168(1-3):1185-1190
Amorphous (a-) Fe x Mg1?x alloys are interesting materials for the investigation of non-Debye-like low-energy vibrational excitations. We have prepared a-Fe x Mg1?x alloy thin films (0.3 ≤ × ≤0.7) by vapour quenching. The amorphous state was confirmed by conversion electron Mössbauer spectroscopy between 4.2–300 K, and the x- and temperature-dependence of the isomer shift and hyperfine magnetic field was measured. For x= 0.6 and 0.7, magnetic ordering occurs below ~150 K. The atomic vibrational density of states, g(E), was determined by nuclear resonant inelastic scattering, providing clear evidence for the non-Debye-like low-energy vibrational excitations. 相似文献
8.
9.
The object of the paper is to study the absolute matrix summability problem of Fourier series, conjugate series and some associated
series under a new set of conditions on matrix methods, generalising many known results in the literature. 相似文献
10.
Aditya M. Vora 《Journal of Non》2008,354(45-46):5022-5032
A well recognized model potential is used to study the superconducting state parameters (SSP) viz. electron–phonon coupling strength λ, Coulomb pseudopotential μ1, transition temperature TC, isotope effect exponent α and effective interaction strength N0V of some binary metallic glasses of simple, non-simple and transition metals. Five local field correction functions proposed by Hartree (H), Taylor (T), Ichimaru–Utsumi (IU), Farid et al. (F) and Sarkar et al. (S) are used in the present investigation to study the screening influence on the aforesaid properties. Instead of using Vegard’s law, pseudo-alloy-atom model (PAA) in the present investigation is proposed and found successful. The present results of the SSP are found in qualitative agreement with other such earlier reported data wherever exist, which confirms the superconducting phase in the metallic glasses. 相似文献