A Novel Dimeric Eremophilane from Ligularia virgaurea spp. oligocephala

A novel dimeric eremophilane, ligulolide B, was isolated from the alcoholic extract of the whole plant of Ligularia virgaurea spp. oligocephala. The structure was elucidated by various spectroscopic methods including intensive 2D NMR techniques （^1H-^1H COSY, gHMQC, gHMBC and ^1H-^1H NOESY） and HR-ESI-MS.     

一类齐次对称多项式上的切比雪夫不等式

本文借助于控制不等式及数学归纳法，将著名的切比雪夫不等式推广到m次一般齐次对称多项式上(如文中定理及引理7)，并将此结果用于对称平均等．旨在展示证明解析不等式的一些有效的方法和技巧，同时为数学研究特别是高维几何研究提供一些新的有趣而有用的解析不等式．     

用ZEMAX软件辅助迈克耳孙干涉仪实验教学

利用ZEMAX软件设计了迈克耳孙干涉仪实验光路.软件绘制的不同显示方式的实验光路外形图,使学生对实验光路建立起了清晰的图像.通过编写ZPL程序实现了对实验现象的动态模拟,使学生对理想情况下的实验现象有一个准确的把握.通过在软件中改变光路主要参数分析了不同方面和不同程度的误差对干涉条纹的影响,其结论对学生在实验中进行有效而准确的调节起到了指导作用.     

Investigation of the quantitative properties of the quadrupole orthogonal acceleration time-of-flight mass spectrometer with electrospray ionisation using 3,4-methylenedioxymethamphetamine

This paper describes the investigation of the potential of a quadrupole orthogonal acceleration time-of-flight mass spectrometer (Q-TOF) equipped with an atmospheric pressure ionisation interface for quantitative measurements of small molecules separated by reversed phase liquid chromatography. To this end, the detection limits and linear dynamic range in particular were studied in an LC/MS/MS experiment using 3,4-methylenedioxymethamphetamine standards and 3,4-methylenedioxyethylamphetamine for internal standardisation. In a second phase, the experiment was repeated with real biological extracts (whole blood, serum, and vitreous humour). A calibration for 3,4-methylenedioxymethamphetamine and its metabolite 3,4-methylenedioxyamphetamine was prepared in each of these matrices again using 3,4-methylenedioxyethylamphetamine as internal standard. The resulting quantitative data were compared with those obtained by liquid chromatography with fluorescence detection for the same extracts. The Q-TOF results revealed excellent sensitivity and a linear dynamic range of nearly four decades (2-10 000 pg on-column, r(2) = 0.9998, 1/x weighting). Furthermore, all the calibration curves prepared in biological material were superimposable, LC/MS/MS and LC-fluorescence, and the quantitative results for actual samples compared very favourably. It was concluded that the Q-TOF achieves a linear dynamic range for quantitative LC/MS/MS work exceeding that of fluorescence detection and at much better absolute sensitivity. Copyright 1999 John Wiley & Sons, Ltd.     

Noncommutative Differential Calculus Approach to Discrete Symplectic Schemes on Regular Lattice

By means of a noncommutative differential calculus on function space of discrete Abelian groups and that of the regular lattice with equal spacing as well as the discrete symplectic geometry and a kind of classical mechanical systems with separable Hamiltonian of the type H(p, q) = T(p) + V(q) on regular lattice, we introduce the discrete symplectic algorithm, i.e., the phase-space discrete counterpart of the symplectic algorithm including original symplectic schemes and the jet-symplectic schemes in terms of the discrete time jet bundle formalism, on the regular lattice. We show some numerical calculation examples and compare the results of different schemes.     

以香豆素为基用以识别氟离子的新型比色化学传感器

以香豆素作为发色团,胺基为氢键供体,以—C=N键桥连设计合成了可裸眼识别氟离子的化学传感器1,吸收光谱结果表明在乙腈中它可以高选择性识别氟离子,光谱红移70 nm,溶液颜色由橙色变为蓝紫色,而其它离子如Cl~-、Br~-、I~-、H_2PO_4~-、NO_3~-、HSO_4~-、AcO~-等均不影响其对氟离子的识别.通过核磁共振氢谱考察其识别机制,表明传感分子通过与F~-间的质子转移反应,使整个体系电子离域,分子内电荷转移更加显著,从而导致吸收光谱大幅红移.     

Calculation of Electronic Structure of Zinc-Blende CdS

The linear-muffin-tin orbital method is used to study the electronic-energy-band structure of zinc-blende CdS. Incorporating the 4d states of Cd into the valence band gives substantially the main-valenceband width, and yields valenceband features in agreement with the experiment. The calculated equilibrium lattice constant is in accord with the measured result. The fundamental band gap is found to be direct at T point and the value is about 1.21 eV. The band structure calculation shows that the present results are in good agreement with experiments and other calculations.     

无机物离子对CuS微晶形态结构的有效调控

以CuCl2·3H2O,Cu（CH3COO）2·H2O和CuSO4·5H2O作为铜源,并向反应体系中引入少量NaCl或NaNO3,通过乙二醇溶剂中的溶剂热反应,合成了形貌各异的CuS微晶．结合XRD和SEM表征,初步探讨了阴离子Cl-、CH3COO-、SO4^2-和阳离子Na’对CuS微晶生长过程的影响．结果表明,Na＋对CuS微晶的生长过程没有显著影响,而Cl、CH3COO-、SO4^2-由于在{1012}晶面上选择性吸附能力的差异,显著影响CuS微晶的形貌．本研究为进一步有效调控CuS微晶的形貌及性能奠定了基础．     

二层供应链网络均衡模型的研究

利用均衡理论和二层规划理论来研究供应链网络均衡问题。针对供应链网络中上下层成员之间具有的Stackelberg博弈特征以及同层成员之间具有的非合作博弈特征,构建了二层供应链网络的均衡模型,该模型实际上一个均衡约束的二层规划问题。此外,为了使得供应链网络在整体上实现最优,本文还在模型中引入回收契约以协调供应链网络。最后,利用罚函数法对模型进行了求解,算例分析说明了模型的合理性和有效性。