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New optically active polyamides were synthesized according to two ways: using a microwave-assisted polycondensation of an optically active isosorbide-derived diacylchloride with different aromatic diamines in NMP and using interfacial polymerization from an isosorbide-derived diamine with different diacylchlorides. The polymers are obtained with inherent viscosities in the range from 0.11 to 1.05 dL/g. The DSC and TGA measurements clearly demonstrate the high thermal stability of these polymers when considering the range of the melting points from 200 °C to 300 °C and the absence of decomposition till 350 °C. 相似文献
2.
Highly Luminescent Colloidal Eu3+‐Doped KZnF3 Nanoparticles for the Selective and Sensitive Detection of CuII Ions
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Shyam Sarkar Manjunath Chatti Dr. Venkataramanan Mahalingam 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(12):3311-3316
This article describes a green synthetic approach to prepare water dispersible perovskite‐type Eu3+‐doped KZnF3 nanoparticles, carried out using environmentally friendly microwave irradiation at low temperature (85 °C) with water as a solvent. Incorporation of Eu3+ ions into the KZnF3 matrix is confirmed by strong red emission upon ultraviolet (UV) excitation of the nanoparticles. The nanoparticles are coated with poly(acrylic acid) (PAA), which enhances the dispersibility of the nanoparticles in hydrophilic solvents. The strong red emission from Eu3+ ions is selectively quenched upon addition of CuII ions, thus making the nanoparticles a potential CuII sensing material. This sensing ability is highly reversible by the addition of ethylenediaminetetraacetic acid (EDTA), with recovery of almost 90 % of the luminescence. If the nanoparticles are strongly attached to a positively charged surface, dipping the surface in a CuII solution leads to the quenching of Eu3+ luminescence, which can be recovered after dipping in an EDTA solution. This process can be repeated for more than five cycles with only a slight decrease in the sensing ability. In addition to sensing, the strong luminescence from Eu3+‐doped KZnF3 nanoparticles could be used as a tool for bioimaging. 相似文献
3.
Anion complexation. A ditriphenylphosphonium calix[4]arene derivative as a novel receptor for anions
A novel anionic receptor 2 consisting of a calix[4]arene bearing two alkytriphenylphosphonium has been prepared by two different procedures. The complexation occurred at the phosphonium sites probably due to electrostatic and/or π-anion forces. 相似文献
4.
Electric and magnetic hybridized plasmonic modes are obtained by stacking two T-shaped resonators. We show that head-to-toe configuration leads to inverse the hybridization. The frequency shift between the resonances is finely controlled by adjusting the gap between the two resonators. A negative refractive index close to -1 is numerically and experimentally demonstrated at 4.3 GHz for TE waves. This left-handed behavior is similar for parallel and normal TE incident wave vectors. The proposed double-T unit cell is well adapted for developing terahertz and IR metamaterials. 相似文献
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Numerous polycondensations of aliphatic diol of isosorbide and 1,8-dimesyloctane or other aliphatic dibromo and disulphonated alkylating agent was performed under phase-transfer catalytic conditions. In order to check the possible specific non-thermal microwave (MW) effects, reactions were comparatively performed inside a thermostated oil bath (Δ) under similar conditions. The reactions conditions were varied to optimize both, the fraction insoluble in methanol (FP MeOH) and the molecular weight of polyethers. In all cases, it was found that microwave-assisted polycondensations proceeded more efficiently compared with conventional heating (the reaction time was reduced from 24 h to 30 min: ratio 1/50). The polycondensation under microwave yields 63% of polyethers precipitating in methanol with relatively high average-weight molecular weights (Mw up to approximately 7000). The polyethers were characterized by NMR (1H, 13C) and FT-IR spectroscopy and SEC measurement and MALDI-TOF mass spectrometry. 相似文献
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Sodium hydrogen telluride opens many epoxides cleanly by an SN2 process to give telluro-alcohols, which by reduction with nickel boride afford alcohols. An intermediate telluro-alcohol was converted to olefin in high yield by treatment with -toluene-sulphonyl chloride in pyridine. Quaternary ammonium salt are also cleaved efficiently by sodium hydrogen telluride. 相似文献
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Sodium hydrogen telluride reduces .-amine -oxides to the corresponding amines in very high yield, but does not reduce sulphoxides. This reagent also reduces nitrones to .-amines at pH6 and to imines at alkaline pH (10–11). 相似文献
9.
Habib?Maagli Abdelwaheb?DhifliEmail author Abdulah?Khamis?Alzahrani 《Mediterranean Journal of Mathematics》2018,15(2):68
In this paper, we study the following fractional Navier boundary value problem where \(\alpha ,\beta \in (0,1]\) such that \(\alpha +\beta >1\), \(D^{\beta }\) and \(D^{\alpha }\) stand for the standard Riemann–Liouville fractional derivatives and a, b are nonnegative constants such that \(a+b>0\). The function g is a nonnegative continuous function in \([0,\infty )\) that is required to satisfy some suitable integrability condition. Using estimates on the Green’s function and a perturbation argument, we prove the existence of a unique positive continuous solution, which behaves like the unique solution of the homogeneous problem.
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$$\begin{aligned} \left\{ \begin{array}{lllc} D^{\beta }(D^{\alpha }u)(x)=u(x)g(u(x)),\quad x\in (0,1), \\ \displaystyle \lim _{x\longrightarrow 0}x^{1-\beta }D^{\alpha }u(x)=-a,\quad \,\,u(1)=b, \end{array} \right. \end{aligned}$$
10.
Bouchra Belhaj Abdallah Ahmed Landoulsi Abdelwaheb Chatti 《Journal of Saudi Chemical Society》2018,22(1):110-118
The instant biosynthesis of silver nanoparticles under static electromagnetic induction, its antibacterial activity and its post exposure monitoring were reported here. A mix of silver nitrate solution and Ruta chalepensis leaf extract was irradiated by a static electromagnetic field (SMF) of 200 mT. The characteristics and stability of the biosynthesized silver nanoparticles (Ag NPs) were determined. Compared to the non-irradiated exposure, the morphology and state of the obtained material change once the exposition to SMF is turned off. Shifting from 453 to 473 nm, the percentage of the needles shaped silver nanoparticles increased and continue to win and dominate the biomixture toward the spherical silver nanoparticles. TEM microscopy showed a wide range of silver materials designed in different nanoscale morphology and beyond where they undergo major changes affecting mainly the size, shape and form (dispersity) of nanosilver. 相似文献